Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-24T10:43:26.657Z Has data issue: false hasContentIssue false
  • English
  • Français

Impact of Divalent Metal Additives on the Structural and Optoelectronic Properties of CH3NH3PbI3 Perovskite Prepared by the Two-Step Solution Process

Published online by Cambridge University Press:  16 January 2017

Suneth C. Watthage ,
Zhaoning Song ,
Niraj Shrestha ,
Adam B. Phillips ,
Geethika K. Liyanage ,
Paul J. Roland ,
Randy J. Ellingson  and
Michael J. Heben
Suneth C. Watthage*
Affiliation:
Wright Center for Photovoltaics Innovation and Commercialization, School for Solar and Advanced Renewable Energy, Department of Physics and Astronomy, University of Toledo, Toledo, OH, USA 43606
Zhaoning Song
Affiliation:
Wright Center for Photovoltaics Innovation and Commercialization, School for Solar and Advanced Renewable Energy, Department of Physics and Astronomy, University of Toledo, Toledo, OH, USA 43606
Niraj Shrestha
Affiliation:
Wright Center for Photovoltaics Innovation and Commercialization, School for Solar and Advanced Renewable Energy, Department of Physics and Astronomy, University of Toledo, Toledo, OH, USA 43606
Adam B. Phillips
Affiliation:
Wright Center for Photovoltaics Innovation and Commercialization, School for Solar and Advanced Renewable Energy, Department of Physics and Astronomy, University of Toledo, Toledo, OH, USA 43606
Geethika K. Liyanage
Affiliation:
Wright Center for Photovoltaics Innovation and Commercialization, School for Solar and Advanced Renewable Energy, Department of Physics and Astronomy, University of Toledo, Toledo, OH, USA 43606
Paul J. Roland
Affiliation:
Wright Center for Photovoltaics Innovation and Commercialization, School for Solar and Advanced Renewable Energy, Department of Physics and Astronomy, University of Toledo, Toledo, OH, USA 43606
Randy J. Ellingson
Affiliation:
Wright Center for Photovoltaics Innovation and Commercialization, School for Solar and Advanced Renewable Energy, Department of Physics and Astronomy, University of Toledo, Toledo, OH, USA 43606
Michael J. Heben
Affiliation:
Wright Center for Photovoltaics Innovation and Commercialization, School for Solar and Advanced Renewable Energy, Department of Physics and Astronomy, University of Toledo, Toledo, OH, USA 43606
*
*(Email: [email protected])
Get access

Abstract

Here, we investigate the effect of divalent metal (Zn2+, Cd2+ and Hg2+) on the structural and optoelectronic properties of methylammonium lead iodide perovskite materials prepared by the two-step deposition process. The incorporation of Cd2+ significantly improved the grain size, crystallinity, and charge carrier lifetime of CH3NH3PbI3. The inclusion of Hg2+ and Zn2+ improved the grain size compare to the control sample but adversely affected the optoelectronic properties of perovskite films. The Hg- and Zn-based impurities were formed on the surface of the films, which increased the charge trap density and lead to high non-radiative recombination rate. Time resolved photoluminescence measurements indicated that the Cd and Zn point defects do not create deep-level trap states, but the Zn-modified film showed a low lifetime due to morphology changes in the film and particle segregation on the surface.

Keywords

organometallicphotovoltaicdefects
Type
Articles
Information
MRS Advances , Volume 2 , Issue 21-22: Energy and Sustainability , 2017 , pp. 1183 - 1188
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

NREL Solar Efficiency Chart . Available at: http://www.nrel.gov/ncpv/images/efficiency_chart.jpg. (accessed November 2016)Google Scholar
Song, Z., Watthage, S. C., Phillips, A. B., and Heben, M. J., J. Photon. Energy. 6, 022001, (2016).Google Scholar
Green, M. A., Ho-Baillie, A., and Snaith, H. J., Nat Photon. 8, 506–514, (2014).Google Scholar
Im, J.-H., Jang, I.-H., Pellet, N., Grätzel, M., and Park, N.-G., Nat. Nano. 9, 927–932, (2014).Google Scholar
Nie, W., Tsai, H., Asadpour, R., Blancon, J.-C., Neukirch, A. J., Gupta, G., Crochet, J. J., Chhowalla, M., Tretiak, S., Alam, M. A., Wang, H.-L., and Mohite, A. D., Science. 347, 522–525, (2015).Google Scholar
Bi, C., Wang, Q., Shao, Y., Yuan, Y., Xiao, Z., and Huang, J., Nat Commun. 6, (2015).Google Scholar
Marinova, N., Tress, W., Humphry-Baker, R., Dar, M. I., Bojinov, V., Zakeeruddin, S. M., Nazeeruddin, M. K., and Grätzel, M., ACS Nano. 9, 4200–4209, (2015).Google Scholar
Fu, K., Nelson, C. T., Scott, M. C., Minor, A., Mathews, N., and Wong, L. H., Nanoscale. 8, 4181–4193, (2016).Google Scholar
Watthage, S. C., Song, Z., Shrestha, N., Phillips, A. B., Liyanage, G. K., Roland, P. J., Ellingson, R. J., and Heben, M. J., ACS Appl. Mater. Interfaces, DOI: 10.1021/acsami.6b12627 (2016).Google Scholar
Song, Z., Watthage, S. C., Phillips, A. B., Tompkins, B. L., Ellingson, R. J., and Heben, M. J., Chem. Mater. 27, 4612–4619, (2015).Google Scholar
Terao, H. and Okuda, T., Z. Naturforsch. 45, 343–348, (1990).Google Scholar
Körfer, M., Fuess, H., Bats, J. W., and Klebe, G., Z. Anorg. Allg. Chem. 525, 23–28, (1985).Google Scholar
Shi, T., Yin, W.-J., and Yan, Y., J. Phys. Chem. C. 118, 25350–25354, (2014).CrossRefGoogle Scholar
Yang, Y., Yang, M., Zhu, K., Johnson, J. C., Berry, J. J., van de Lagemaat, J., and Beard, M. C., Nature Communications. 7, 12613, (2016).Google Scholar
Wu, B., Nguyen, H. T., Ku, Z., Han, G., Giovanni, D., Mathews, N., Fan, H. J., and Sum, T. C., Adv. Energy Mater. 6, 1600551, (2016).Google Scholar