Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-24T23:04:37.892Z Has data issue: false hasContentIssue false
  • English
  • Français

Hydrothermal Synthesis and Characterization of Mn-Doped VO2 Nanowires

Published online by Cambridge University Press:  24 January 2019

G. Long ,
David Matatov ,
Acher Suissa ,
Elmustapha Feddi ,
M. EL Yadri ,
Kawtar Feddi  and
M. Sadoqi
G. Long*
Affiliation:
Department of Physics, St. John’s University, Queens, 11439, USA
David Matatov
Affiliation:
Department of Physics, St. John’s University, Queens, 11439, USA
Acher Suissa
Affiliation:
Department of Physics, St. John’s University, Queens, 11439, USA
Elmustapha Feddi
Affiliation:
LaMCScI, Group of Optoelectronic of Semiconductors and Nanomaterials, ENSET, Mohammed V University in Rabat, 10000, Morocco
M. EL Yadri
Affiliation:
LaMCScI, Group of Optoelectronic of Semiconductors and Nanomaterials, ENSET, Mohammed V University in Rabat, 10000, Morocco
Kawtar Feddi
Affiliation:
REAM Laboratory, International University of Rabat, 10000, Morocco
M. Sadoqi
Affiliation:
Department of Physics, St. John’s University, Queens, 11439, USA Department of Pharmaceutical Sciences, St. John’s University, Queens, 11439, USA
*
*(Email: [email protected])
Get access

Abstract

Monoclinic VO2 is a known polymorph of vanadium dioxide that has received much attention due to its oxidative capabilities, geometric configuration, and promising applications in functional windows. VO2 can usually be obtained through a hydrothermal method under high pressure. In this work we report a synthesis of VO2 doped with Manganese using a rapid single-step hydrothermal process with V2O5, manganese (II) acetate and citric acid as precursors. Different syntheses were carried out in which the concentration of V2O5 and citric acid remained constant whereas the concentration of manganese (II) acetate was varied. The reactants underwent a stirring phase for 30 minutes before being loaded into a hydrothermal reactor for 2.5 hours at 200°C. The resultant was washed three times to remove the residual precursors. Imaging and spectroscopy characterizations such as TEM, SEM and UV-VIS-NIR have been performed on different doping concentration and the results display a dependence on doping concentrations.

Keywords

hydrothermalnanostructuremetal-insulator transition
Type
Articles
Information
MRS Advances , Volume 4 , Issue 14: Energy-Transfer, Storage and Conversion , 2019 , pp. 829 - 836
Copyright
Copyright © Materials Research Society 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Rao, C.N.R., Annu. Rev. Phys. Chem. 1989, 40, 291-326.CrossRefGoogle Scholar
Anderson, T., Ren, F., Pearton, S., Kang, B.S., Wang, H.T., Chang, C.Y., and Lin, J., Sensors 2009, 9 (4), 4669-4694.CrossRefGoogle Scholar
Shen, T.Z., Hong, S.H., and Song, J.K., Nature Materials 2014, 13, 394-399.CrossRefGoogle Scholar
Murdoch, M., Waterhouse, G.I.N., Nadeem, M.A., Metson, J.B., Keane, M.A., Howe, R.F., Llorca, J., and Idriss, H., Nature Chemistry 2011, 3, 489-492.CrossRefGoogle Scholar
Morin, F. J., Phys. Rev. Lett. 1959, 3, 34.CrossRefGoogle Scholar
Eyert, V., Ann. Physic. 2002, 11, 9.Google Scholar
Andersson, G., Acta Chemica Scandinavica 1954, 8, 1599-1606.CrossRefGoogle Scholar
Mamedov, E.A. and Cortés Corberán, V., Applied Catalysis A: General 1995, 1-2, 1-40.CrossRefGoogle Scholar
Liu, P., Zhu, K., Gao, Y., Luo, H., and Lu, L., Advanced Energy Materials 2017, 23, 1700547.CrossRefGoogle Scholar
Yan, Y., Li, B., Guo, W., Pang, H., and Xue, H., Journal of Power Sources 2016, 148-169.CrossRefGoogle Scholar
Baudrin, E., Sudant, G., Larcher, D., Dunn, B., and Tarascon, J.M., Chem. Mater. 2006, 18, 4369-4374.CrossRefGoogle Scholar
Ganganagappa, N. and Siddaramanna, A., Materials Characterization 2012, 58-62.CrossRefGoogle Scholar
Zhou, J., Gao, Y., Zhang, Z., Luo, H., Cao, C., Chen, Z., Dai, L., Liu, X., Scientific Reports 2013, 3, 3029.CrossRefGoogle Scholar
Mai, L., Wei, Q., An, Q., Tian, X. Zhao, Y., Xu, X., Xu, L., Chang, L., Zhang, Q., Advanced Materials 2013, 21, 2969-2973.CrossRefGoogle Scholar
Armstrong, G., Canales, J., Armstrong, A.R., and Bruce, P.G., Journal of Power Sources 2008, 2, 723-728.CrossRefGoogle Scholar
Guiton, B.S., Gu, Q., Prieto, A.L., Gudiksen, M.S., and Park, H., J. Am. Chem. Soc. 2005, 127, 498-499.CrossRefGoogle Scholar
Shichang, H., Zhengguang, Z., and Shuailei, H., IOP Conf. Ser.: Mater. Sci. Eng. 2018, 382, 022059.Google Scholar
Chen, X., Wang, X., Wang, Z., Wan, J., Liu, J. and Qian, Y., Nanotechnology 2004, 15, 1685-1687.CrossRefGoogle Scholar
Popuri, S.R., Miclau, M., Artemenko, A., Labrugere, C., Villesuzanne, A., and Pollet, M., Inorganic Chemistry 2013, 52, 4780-4785.CrossRefGoogle Scholar
Ni, J., Jiang, W., Yu, K., Gao, Y., and Zhu, Z., Electrochimica Acta, 2011, 5, 2122-2126CrossRefGoogle Scholar