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Development of a hybrid metal-oxides (Li2O-Al2O3-Al3Fe-Al3Fe5O12) reinforced polycaprolactone composite

Published online by Cambridge University Press:  21 January 2020

N.N. Zurita-Méndez ,
J. Beltran-González ,
G. Carbajal-De la Torre  and
M.A. Espinosa-Medina Open the ORCID record for M.A. Espinosa-Medina [Opens in a new window]
N.N. Zurita-Méndez
Affiliation:
Facultad de Ingeniería Mecánica, Universidad Michoacana de San Nicolás de Hidalgo, C.P. 58000; Morelia, Michoacán, México.
J. Beltran-González
Affiliation:
Facultad de Ingeniería Mecánica, Universidad Michoacana de San Nicolás de Hidalgo, C.P. 58000; Morelia, Michoacán, México.
G. Carbajal-De la Torre
Affiliation:
Facultad de Ingeniería Mecánica, Universidad Michoacana de San Nicolás de Hidalgo, C.P. 58000; Morelia, Michoacán, México.
M.A. Espinosa-Medina*
Affiliation:
Facultad de Ingeniería Mecánica, Universidad Michoacana de San Nicolás de Hidalgo, C.P. 58000; Morelia, Michoacán, México.
*
*Corresponding author: [email protected]
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Abstract

This paper addresses the chemical synthesis and characterization of a composite formed by Li2O-Al2O3-Al3Fe-Al3Fe5O12/PCL which were obtained by the process of reduction of ferric chloride (FeCl3) with lithium aluminum hydride (LiAlH4) in an open atmosphere. The goal of the development of this hybrid material was to perform a superparamagnetic material with several potential applications. The results of the characterizations by scanning electron microscopy (SEM) and vibrating sample magnetometer showed a Li2O-Al2O3-Al3Fe-Al3Fe5O12 “desert rose stone”-like morphology 3D hierarchical powders formation when particles were sintered at 850 °C. Homogeneous nanometric particles after calcination at 1100 °C were observed. X-ray diffraction analysis were performed to determine their composition. Subsequently, the superparamagnetic powders were added by dispersion in a polycaprolactone (PCL) matrix, and then, were evaluated by SEM for the observation of their morphologies. The composite material presented a polymer network with an opened structure, a well dispersion of the oxides particles into the interstices with irregular topography and reliefs.

Keywords

compositebiomaterialpolymermagnetic properties
Type
Articles
Information
MRS Advances , Volume 4 , Issue 63: International Materials Research Congress XXVIII , 2019 , pp. 3485 - 3493
Copyright
Copyright © Materials Research Society 2020 

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