Hostname: page-component-78c5997874-8bhkd Total loading time: 0 Render date: 2024-11-04T18:05:46.819Z Has data issue: false hasContentIssue false
  • English
  • Français

Deposition routes of Cs2AgBiBr6 double perovskites for photovoltaic applications

Published online by Cambridge University Press:  05 February 2018

Martina Pantaler ,
Christian Fettkenhauer ,
Hoang L. Nguyen ,
Irina Anusca  and
Doru C. Lupascu
Martina Pantaler
Affiliation:
Institute for Materials Science and Center of Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Universitätsstraße 15, 45141Essen, Germany
Christian Fettkenhauer
Affiliation:
Institute for Materials Science and Center of Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Universitätsstraße 15, 45141Essen, Germany
Hoang L. Nguyen
Affiliation:
Institute for Materials Science and Center of Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Universitätsstraße 15, 45141Essen, Germany
Irina Anusca
Affiliation:
Institute for Materials Science and Center of Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Universitätsstraße 15, 45141Essen, Germany
Doru C. Lupascu*
Affiliation:
Institute for Materials Science and Center of Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Universitätsstraße 15, 45141Essen, Germany
*
*(Email: [email protected])

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The lead free double perovskite Cs2AgBiBr6 is an upcoming alternative to lead based perovskites as absorber material in perovskite solar cells. So far, the majority of investigations on this interesting material have focused on polycrystalline powders and single crystals. We present vapor and solution based approaches for the preparation of Cs2AgBiBr6 thin films. Sequential vapor deposition processes starting from different precursors are shown and their weaknesses are discussed. Single source evaporation of Cs2AgBiBr6 and sequential deposition of Cs3Bi2Br9 and AgBr result in the formation of the double perovskite phase. Additionally, we show the possibility of the preparation of planar Cs2AgBiBr6 thin films by spin coating.

Keywords

energy generationchemical vapor deposition (CVD) (deposition)optical
Type
Articles
Information
MRS Advances , Volume 3 , Issue 32: Energy and Sustainability , 2018 , pp. 1819 - 1823
Copyright
Copyright © Materials Research Society 2018 

References

REFERENCES

Kojima, A., Teshima, K., Shirai, Y., and Miyasaka, T., J. Am. Chem. Soc. 131 6050–6051 (2009).CrossRefGoogle Scholar
National Renewable Energy Laboratory (NREL) Efficiency Chart. Available at: https://www.nrel.gov/pv/assets/images/efficiency-chart.png (accessed 30 October 2017).Google Scholar
Brenner, T.M., Egger, D.A., Kronik, L., Hodes, G., and Cahen, D., Nat. Rev. Mater. 1 15007 (2016).CrossRefGoogle Scholar
Noh, J.H., Im, S.H., Heo, J.H., Mandal, T.N., and Seok, S.I., Nano. Lett. 13, 1764 (2013).CrossRefGoogle Scholar
Stranks, S.D., Eperon, G.E., Grancini, G., Menelaou, C., Alcocer, M.J.P., Leijtens, T., Herz, L.M., Petrozza, A., Snaith, H.J., Science 342, 341–344 (2013).CrossRefGoogle Scholar
Brandt, R.E., Stevanovic, V., Ginley, D.S., and Buonassisi, T., MRS Commun. 5, 265−275 (2015).CrossRefGoogle Scholar
Anusca, I., Balciunas, S., Gemeiner, P., Svirskas, S., Sanlialp, M., Lackner, G., Fettkenhauer, C., Belovickis, J., Samulionis, V., Ivanov, M., Dkhil, B., Banys, J., Shvartsman, V.V., and Lupascu, D.C., Adv. Energy Mater. 7, 1700600 (2017).CrossRefGoogle Scholar
Wehrenfennig, C., Eperon, G.E., Johnston, M.B., Snaith, H.J., and Herz, L.M., Adv. Mater. 26, 1584−1589 (2014).CrossRefGoogle Scholar
Aristidou, N., Sanchez-Molina, I., Chotchuangchutchaval, T., Brown, M., Martinez, L., Rath, T., and Haque, S.A., Angew. Chem., Int. Ed. 54, 8208−8212 (2015).CrossRefGoogle Scholar
Babayigit, A., Ethirajan, A., Muller, M., and Conings, B., Nat. Mater. 15, 247− 251 (2016).CrossRefGoogle Scholar
Zhang, Zheng, Li, Xiaowei, Xia, Xiaohong, Wang, Zhuo, Huang, Zhongbing, Lei, Binglong, and Gao, Yun, J. Phys. Chem. Lett. 8(17), 4300–4307 (2017).CrossRefGoogle Scholar
Slavney, A.H., Hu, Te, Lindenberg, A.M., and Karunadasa, H.I., J. Am. Chem. Soc. 138(7), 2138–2141 (2016).CrossRefGoogle Scholar
Mcclure, E.T., Ball, M.R., Windl, W., and Woodward, P.M., Chem. Mater. 28, 1348−1354 (2016).CrossRefGoogle Scholar
Volonakis, G., Filip, M.R., Haghighirad, A.A., Sakai, N., Wenger, B., Snaith, H. J., and Giustino, F., J. Phys. Chem. Lett. 7, 1254–1259 (2016).CrossRefGoogle Scholar
Greul, E., Petrus, M.L., Binek, A., Docampo, P., and Bein, T., J. Mater. Chem. A. 5, 19972 (2017).CrossRefGoogle Scholar
Xiao, Z., Meng, W., Wang, J., Yan, Y., ChemSusChem 9, 2628–2633 (2016)CrossRefGoogle Scholar
Smallwood, I.M., Handbook of organic solvent properties (Arnold, London, 1996) p. 253.CrossRefGoogle Scholar