Article contents
Aqueous leaching of high burnup UO2 fuel under hydrogen conditions
Published online by Cambridge University Press: 06 March 2018
Abstract
Leaching results on fragments of high burnup (65 MWd/kgU) UO2 fuel from a commercial pressurized water reactor are presented. The experiment was performed in simplified granitic groundwater under a hydrogen pressure of up to 5 MPa, representing conditions in a water intrusion scenario for a Swedish KBS-3 design spent nuclear fuel repository. The freshly crushed fragments were pre-washed for 6 days to remove pre-oxidized matrix and part of the instant release fraction of the radionuclide inventory, and then transferred to an autoclave for leaching under hydrogen conditions. Following an initial release of U attributed to dissolution of a pre-oxidized fuel layer caused by the aerated handling mainly during the transfer from pre-washing to autoclave, the U concentration decreased with time to levels of 2-5x10-9 M, which corresponds, approximately, to the solubility of amorphous UO2. The release of radionuclides such as Cs and Sr gradually declined indicating a transition to inhibition of the fuel matrix dissolution.
Keywords
- Type
- Articles
- Information
- MRS Advances , Volume 3 , Issue 19: Scientific Basis for Nuclear Waste Management XLI , 2018 , pp. 1013 - 1018
- Copyright
- Copyright © Materials Research Society 2018
References
- 5
- Cited by