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Adsorptive removal of V(V) ions using clinoptilolite modified with polypyrrole and iron oxide nanoparticles in column studies

Published online by Cambridge University Press:  01 March 2018

NOMCEBO H. MTHOMBENI ,
SANDRINE MBAKOP ,
AOYI OCHIENG  and
MAURICE S. ONYANGO
NOMCEBO H. MTHOMBENI*
Affiliation:
Department of Civil and Chemical Engineering, University of South Africa (UNISA), Roodeport, South Africa,
SANDRINE MBAKOP
Affiliation:
Department of Chemical, Metallurgical and Materials Engineering, Tshwane University of Technology, Pretoria, South Africa
AOYI OCHIENG
Affiliation:
Department of Chemical Engineering, Vaal University of Technology, Vanderbiljpark, South Africa
MAURICE S. ONYANGO
Affiliation:
Department of Chemical, Metallurgical and Materials Engineering, Tshwane University of Technology, Pretoria, South Africa
*
*Corresponding Author: Dr Nomcebo Mthombeni [email protected] ; [email protected]
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Abstract

Clinoptilolite modified with polypyrrole and iron oxide nanoparticles (Cln-PPy-Fe3O4) nanocomposite as a potential adsorbent for V (V) ions was prepared via polymerization of pyrrole monomer using FeCl3 oxidant in aqueous medium in which clinoptilolite-Fe3O4 nanoparticles were suspended. The structure and morphology of the prepared adsorbent was analysed with the Fourier transform infrared (FTIR) spectrometer, field-emission scanning electron microscope (FE-SEM), energy dispersive X-ray spectroscopy (EDX) and high-resolution transmission electron microscope (HR-TEM). Column fixed bed studies were performed to test the ability of the adsorbent to remove V (V) ions from aqueous solution. Low values of adsorbent exhaustion rate (AER) and large bed volumes were observed at lower metal ion concentration, higher bed mass and lower flow rate for V(V) removal indicating good performance. The volume of treated water processed at breakthrough point were found to be 0.09; 0.63 and 1.26 L for bed mass of 1, 2.5; and 5 g, respectively. The Yoon–Nelson and Thomas models appropriately described the breakthrough curves.

Keywords

adsorptionV
Type
Articles
Information
MRS Advances , Volume 3 , Issue 36: African Materials Research Society 2017 , 2018 , pp. 2119 - 2127
Copyright
Copyright © Materials Research Society 2018 

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References

Filik, H., Yanaz, Z., A sensitive method for determining total vanadium in water samples using colorimetric-solid-phase extraction-fiber optic reflectance spectroscopy, Journal of Hazardous Materials, 172 (2009) 1297–1302.CrossRefGoogle ScholarPubMed
Patel, B., Henderson, G.E., Haswell, S.J., Grzeskowiak, R., Speciation of vanadium present in a model yeast system, Analyst, 115 (1990) 1063–1066.CrossRefGoogle Scholar
Zhang, B., Feng, C., Ni, J., Zhang, J., Huang, W., Simultaneous reduction of vanadium (V) and chromium (VI) with enhanced energy recovery based on microbial fuel cell technology, Journal of Power Sources, 204 (2012) 34–39.CrossRefGoogle Scholar
Sturini, M., Rivagli, E., Maraschi, F., Speltini, A., Profumo, A., Albini, A., Photocatalytic reduction of vanadium(V) in TiO2 suspension: Chemometric optimization and application to wastewaters, Journal of Hazardous Materials, 254–255 (2013) 179–184.CrossRefGoogle Scholar
Li, W., Zhang, Y., Liu, T., Huang, J., Wang, Y., Comparison of ion exchange and solvent extraction in recovering vanadium from sulfuric acid leach solutions of stone coal, Hydrometallurgy, 131–132 (2013) 1–7.CrossRefGoogle Scholar
Hu, Q., Paudyal, H., Zhao, J., Huo, F., Inoue, K., Liu, H., Adsorptive recovery of vanadium(V) from chromium(VI)-containing effluent by Zr(IV)-loaded orange juice residue, Chemical Engineering Journal, 248 (2014) 79–88.CrossRefGoogle Scholar
Kaczala, F., Marques, M., Hogland, W., Lead and vanadium removal from a real industrial wastewater by gravitational settling/sedimentation and sorption onto Pinus sylvestris sawdust, Bioresource Technology, 100 (2009) 235–243.CrossRefGoogle ScholarPubMed
Ngomsik, A.-F., Bee, A., Siaugue, J.-M., Cabuil, V., Cote, G., Nickel adsorption by magnetic alginate microcapsules containing an extractant, Water Research, 40 (2006) 1848–1856.CrossRefGoogle ScholarPubMed
Hristovski, K., Baumgardner, A., Westerhoff, P., Selecting metal oxide nanomaterials for arsenic removal in fixed bed columns: From nanopowders to aggregated nanoparticle media Journal of Hazardous Materials, 147 (2007) 265–274.Google Scholar
Bhaumik, M., Choi, H.J., Seopela, M.P., McCrindle, R.I., Maity, A., Highly Effective Removal of Toxic Cr(VI) from Wastewater Using Sulfuric Acid-Modified Avocado Seed, Industrial & Engineering Chemistry Research, 53 (2014) 1214–1224.CrossRefGoogle Scholar
Setshedi, K.Z., Bhaumik, M., Onyango, M.S., Maity, A., Breakthrough studies for Cr(VI) sorption from aqueous solution using exfoliated polypyrrole-organically modified montmorillonite clay nanocomposite, Journal of Industrial and Engineering Chemistry, 20 (2014) 2208–2216.CrossRefGoogle Scholar
Setshedi, K.Z., Bhaumik, M., Onyango, M.S., Maity, A., High-performance towards Cr(VI) removal using multi-active sites of polypyrrole–graphene oxide nanocomposites: Batch and column studies, Chemical Engineering Journal, 262 (2015) 921–931.CrossRefGoogle Scholar
Yu, K., Kumar, N., Roine, J., Pesonen, M., Ivaska, A., Synthesis and characterization of polypyrrole/H-Beta zeolite nanocomposites, RSC Advances, 4 (2014) 33120–33126.CrossRefGoogle Scholar
Bhaumik, M., Maity, A., Srinivasu, V.V., Onyango, M.S., Enhanced removal of Cr(VI) from aqueous solution using polypyrrole/Fe3O4 magnetic nanocomposite, Journal of Hazardous Materials, 190 (2011) 381–390.CrossRefGoogle ScholarPubMed
Karimi, M., Shojaei, A., Nematollahzadeh, A., Abdekhodaie, M.J., Column study of Cr (VI) adsorption onto modified silica–polyacrylamide microspheres composite, Chemical Engineering Journal, 210 (2012) 280–288.CrossRefGoogle Scholar
Mthombeni, N.H., Mbakop, S., Ochieng, A., Onyango, M.S., Vanadium (V) adsorption isotherms and kinetics using polypyrrole coated magnetized natural zeolite, Journal of the Taiwan Institute of Chemical Engineers, 66 (2016) 172–180.CrossRefGoogle Scholar
Mthombeni, N.H., Mbakop, S., Onyango, M.S., Magnetic zeolite-polymer composite as an adsorbent for the remediation of wastewaters containing vanadium, International Journal of Environmental Science and Development, 6 (2015) 602.CrossRefGoogle Scholar
Bhaumik, M., Setshedi, K., Maity, A., Onyango, M.S., Chromium(VI) removal from water using fixed bed column of polypyrrole/Fe3O4 nanocomposite, Separation and Purification Technology, 110 (2013) 11–19.CrossRefGoogle Scholar
Mthombeni, N.H., Mpenyana-Monyatsi, L., Onyango, M.S., Momba, M.N.B., Breakthrough analysis for water disinfection using silver nanoparticles coated resin beads in fixed-bed column, Journal of Hazardous Materials, 217–218 (2012) 133–140.CrossRefGoogle ScholarPubMed
Frost, R.L., Crane, M., Williams, P.A., Theo Kloprogge, J., Isomorphic substitution in vanadinite [Pb5(VO4)3Cl]—a Raman spectroscopic study, Journal of Raman Spectroscopy, 34 (2003) 214–220.CrossRefGoogle Scholar
Frost, R.L., Henry, D.A., Weier, M.L., Martens, W., Raman spectroscopy of three polymorphs of BiVO4: clinobisvanite, dreyerite and pucherite, with comparisons to (VO4)3-bearing minerals: namibite, pottsite and schumacherite, Journal of Raman Spectroscopy, 37 (2006) 722–732.CrossRefGoogle Scholar
Palmer, S.J., Nguyen, T., Frost, R.L., Synthesis and Raman spectroscopic characterisation of hydrotalcite with CO32− and VO3− anions in the interlayer, Journal of Raman Spectroscopy, 38 (2007) 1602–1608.CrossRefGoogle Scholar
Boukerma, K., Piquemal, J.-Y., Chehimi, M.M., Mravčáková, M., Omastová, M., Beaunier, P., Synthesis and interfacial properties of montmorillonite/polypyrrole nanocomposites, Polymer, 47 (2006) 569–576.CrossRefGoogle Scholar
Singha, S., Sarkar, U., Mondal, S., Saha, S., Transient behavior of a packed column of Eichhornia crassipes stem for the removal of hexavalent chromium, Desalination, 297 (2012) 48–58.CrossRefGoogle Scholar
Chen, S., Yue, Q., Gao, B., Li, Q., Xu, X., Fu, K., Adsorption of hexavalent chromium from aqueous solution by modified corn stalk: A fixed-bed column study, Bioresource Technology, 113 (2012) 114–120.CrossRefGoogle Scholar
Wang, W., Li, M., Zeng, Q., Adsorption of chromium (VI) by strong alkaline anion exchange fiber in a fixed-bed column: Experiments and models fitting and evaluating, Separation and Purification Technology, 149 (2015) 16–23.CrossRefGoogle Scholar
Chu, K.H., Fixed bed sorption: Setting the record straight on the Bohart–Adams and Thomas models, Journal of Hazardous Materials, 177 (2010) 1006–101CrossRefGoogle ScholarPubMed