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Theoretical pulse charge for the optimal inhibition of growing dendrites

Published online by Cambridge University Press:  23 January 2018

Asghar Aryanfar ,
Daniel J. Brooks  and
William A. Goddard III
Asghar Aryanfar*
Affiliation:
Engineering Faculty, Bahçeşehir University, Istanbul, Turkey34349, Email: [email protected] Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA91125, USA
Daniel J. Brooks
Affiliation:
Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA91125, USA
William A. Goddard III
Affiliation:
Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA91125, USA
*
‡(Email: [email protected])
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Abstract

Dendritic growth during charging period is one of the main barriers for the rechargeablity of conventional batteries. Additionally this phenomenon hinders the utilization of high energy density metal candidates by limiting the safety and allowable operating condition for these devices. We address the role of square wave pulse on the growth dynamics of dendrites in the continuum scale and large time periods by formulating an analytical criterion. Our dimension-free analysis permits the application our results to a variety of electrochemical systems in diverse scales.

Keywords

electrodepositionLiamorphous
Type
Articles
Information
MRS Advances , Volume 3 , Issue 22: Energy and Sustainability , 2018 , pp. 1201 - 1207
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Copyright
Copyright © Materials Research Society 2018 

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