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Synthesis and Characterization of 2D-Graphene Oxide-Metal Hybrid Systems with Increased Solubility

Published online by Cambridge University Press:  10 June 2019

Hadi Kelani ,
Shelby Weatherbee ,
Stephen Blama  and
Mary Sajini Devadas Open the ORCID record for Mary Sajini Devadas [Opens in a new window]
Hadi Kelani
Affiliation:
Department of Chemistry, Towson University 8000 York Road, Towson, MD21252, U.S.A.
Shelby Weatherbee
Affiliation:
Department of Chemistry, Towson University 8000 York Road, Towson, MD21252, U.S.A.
Stephen Blama
Affiliation:
Department of Chemistry, Towson University 8000 York Road, Towson, MD21252, U.S.A.
Mary Sajini Devadas*
Affiliation:
Department of Chemistry, Towson University 8000 York Road, Towson, MD21252, U.S.A.
*
*Corresponding Author Email: [email protected]
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Abstract

Graphene oxide serves as a precursor to various technologies, which include batteries, biosensors, solar cells, and supercapacitors. Gold nanoparticles exhibit excellent electrochemical and photophysical properties, allowing for electronic absorption and the ability to absorb light energy at the plasmonic wavelength. Palladium nanoparticles are highly sensitive and functional in room temperature, making it an ideal metal for catalytic applications. We report the synthesis of functional graphene oxide from graphite flakes followed by the insertion of gold and palladium nanoparticles through an oleylamine ligand. In this report, the fermi level of graphene oxide (GOx), gold-graphene oxide (Au-GOx), and palladium-graphene oxide (Pd-GOx) was shown to be effectively controlled. Additionally, each system showed complete solubility in ethanol and in the case of Au-GOx, enhanced solubility was seen in tetrahydrofuran as well.

Keywords

2D materialsnanoscalegrapheneplasmonic
Type
Articles
Information
MRS Advances , Volume 4 , Issue 38-39: Quantum and Nanomaterials , 2019 , pp. 2119 - 2126
Copyright
Copyright © Materials Research Society 2019 

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References

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