Hostname: page-component-cd9895bd7-7cvxr Total loading time: 0 Render date: 2024-12-18T09:58:13.592Z Has data issue: false hasContentIssue false
  • English
  • Français

Structures and Optical Properties of Nanoforest-Like Carbon Nanotubes Decorated with Nanoparticles of Strontium Aluminate Doped with Rare-Earth Elements

Published online by Cambridge University Press:  14 March 2018

Patsy Y. Arquieta Guillén ,
Alena Borisovna Kharissova ,
Beatriz Ortega García  and
Oxana V. Kharissova
Patsy Y. Arquieta Guillén
Affiliation:
Universidad Autónoma de Nuevo León, Av. Universidad S/N, Ciudad Universitaria, San Nicolás de los Garza, N.L., C.P.66455, México.
Alena Borisovna Kharissova
Affiliation:
Universidad Autónoma de Nuevo León, Av. Universidad S/N, Ciudad Universitaria, San Nicolás de los Garza, N.L., C.P.66455, México.
Beatriz Ortega García
Affiliation:
Universidad Autónoma de Nuevo León, Av. Universidad S/N, Ciudad Universitaria, San Nicolás de los Garza, N.L., C.P.66455, México.
Oxana V. Kharissova*
Affiliation:
Universidad Autónoma de Nuevo León, Av. Universidad S/N, Ciudad Universitaria, San Nicolás de los Garza, N.L., C.P.66455, México.
*
*(Email: [email protected])
Get access

Abstract

Nowadays, carbon nanotubes have a lot of applications in daily life, being applied in the fabrication of cellphones, computers, nanotransistors, among many others. Currently, their new applications in biotechnology area are in research, in particular in order to find new biosensors with fluorescent properties applying on the basis of multi-wall carbon nanotubes (MWCNTs). In this work, the obtaining of carbon nanoparticles having fluorescent properties via spray pyrolysis is presented. Synthesis, properties, structural peculiarities, and applications of nanobuds and related nanostructures are discussed. MWCNTs, decorated with strontium aluminate SrAl12O19 and doped with rare-earth elements, were synthetized from distinct organic precursors and the corresponding metal oxides. The metal oxides used were Samarium (Sm), Europium (Eu), Neodymium (Nd), Lanthanum (La), Cerium (Ce) and some their combinations.

The synthesis was carried out on the surface of optical fibres to obtain a uniform growth of forest-like MWCNTs, adding to metal oxide nanoparticles to their surface. The preparation of composites was carried out by spray pyrolysis techniques in dry nitrogen atmosphere in the temperature range from 780 to 850°C. The formed products were characterized by Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), FTIR spectroscopy, Raman spectroscopy and UV/visible spectroscopies. The analysis of the obtained data shows that the deposited nanoparticles are in the range of size 20-60 nm being uniformly distributed on the surface of MWCNTs. The samples, obtained at different temperatures and with doping metal oxides added to SrAl12O19, show different fluorescence behavior. The best results were observed with lanthanum oxide as a dopant. Possible applications as persistently luminescent phosphors for the formed MWCNTs-supported luminescent materials are proposed.

Keywords

Cspray pyrolysisfiber
Type
Articles
Information
MRS Advances , Volume 3 , Issue 1-2: Nanomaterials , 2018 , pp. 121 - 126
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Iverson, N.M., Barone, P.W., Shandell, M., Trudel, L.J., Sen, S., Sen, F., Reuel, F., N.. In vivo biosensing via tissue-localizable near-infrared-fluorescent single-walled carbon nanotubes. Nature Nanotechnology, 8(11), 873–880 (2013).Google Scholar
Rezende, M.V.D.S., Amaral, J.B., Valerio, M.E., Jackson, R.A.. Optical properties of Pr and Eu-doped SrAl12O19: A theoretical study. Optical Mater., 48, 105–109 (2015).CrossRefGoogle Scholar
Kharisov, B.I., Kharissova, O.V., García Ortega, B., Méndez, Y.P., de la Fuente, I.G.. State of the art of nanoforest structures and their applications. RSC Advances, 5(128), 105507–105523 (2015).CrossRefGoogle Scholar
Kharissova, O.V., Kharisov, B.I.. Solubilization and Dispersion of Carbon Nanotubes. Springer-Nature, 250 pp. (2017)Google Scholar
Rojas-Hernandez, R.E., Rodriguez, M.A., Rubio-Marcos, F., Serrano, A., Fernandez, J.F.. Designing nanostructured strontium aluminate particles with high luminescence properties. Journal of Materials Chemistry C, 3(6), 1268–1276 (2015).Google Scholar
Marzahl, D.T., Metz, P.W., Calmano, T., Reichert, F., Kränkel, C., Huber, G.. Rare Earth Doped Oxides for Visible Laser Operation. In: The European Conference on Lasers and Electro-Optics (p. CA_8_2). Optical Society of America (2015).Google Scholar
Han, C.Y., Xiao, Z.L., Wang, H.H., Lin, X.M., Trasobares, S., Cook, R.E.. Facile synthesis of highly aligned multiwalled carbon nanotubes from polymer precursors. Journal of Nanomaterials, 2009, 15 (2009).CrossRefGoogle Scholar