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Sensing properties of pellets based on mesoporous structures of ZnO

Published online by Cambridge University Press:  19 April 2016

R. Herrera-Rivera ,
A. M. Pineda ,
M. de la L. Olvera  and
A. Maldonado
R. Herrera-Rivera*
Affiliation:
Programa de Doctorado en Nanociencias y Nanotecnología, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional. México, D.F., MEXICO
A. M. Pineda
Affiliation:
Programa de Doctorado en Nanociencias y Nanotecnología, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional. México, D.F., MEXICO
M. de la L. Olvera
Affiliation:
Programa de Doctorado en Nanociencias y Nanotecnología, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional. México, D.F., MEXICO Departamento de Ingeniería Eléctrica, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional. México, D.F., MEXICO
A. Maldonado
Affiliation:
Programa de Doctorado en Nanociencias y Nanotecnología, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional. México, D.F., MEXICO Departamento de Ingeniería Eléctrica, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional. México, D.F., MEXICO
*
*(Email: [email protected])
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Abstract

Mesoporous zinc oxide nanopowders were synthesized by the homogenous precipitation method. Zinc acetate dissolved in water, at different molar concentrations, was used as Zn precursor, whereas ammonium carbonate ((NH4)2CO3) and ammonium hydroxide (NH4OH) were used to prepare the precipitant solutions. The precipitated powders were dried in a conventional drying chamber at 100°C for 1 h, and then calcined at 400°C during 2 h. Crystal structure of powders was determined by X-ray Diffraction (XRD), and the crystallite sizes were calculated from Scherrer’s formula. Morphological characteristics (size and shape) were analyzed from Scanning Electron Microscopy (SEM). The surface area and the pore volume were obtained from BET analysis. The hexagonal wurtzite phase was corroborated in all synthesized powders, irrespective of the synthesis conditions. From SEM micrographs different structures, depending on the experimental routes, were observed. In order to test the sensing properties of the ZnO nanopowders, 10 mm diameter pellets were manufactured and then measured in a propane (C3H8) atmosphere at different gas concentrations and temperatures. Pellets processed from ZnO powders at 0.05, 0.35, and 0.5 M presented the highest sensitivity, 413, 532, at 300°C and 500 ppm of C3H8.

Keywords

nanostructuremorphologyscanning electron microscopy (SEM)
Type
Articles
Information
MRS Advances , Volume 1 , Issue 21: Nanomaterials and Synthesis , 2016 , pp. 1545 - 1551
Copyright
Copyright © Materials Research Society 2016 

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References

REFERENCES

Hijiri, M., El Mir, L., Leonardi, S.G., Pistone, A., Mavilia, L., and Neri, G.. Al-doped ZnO for highly sensitive CO gas sensors . Sensors and Actuators B, 196, (2014), pp. 413–420.Google Scholar
Chang, Shoou-Jinn, Hsueh, Ting-Jen, Chen, I-Cgerng, and Huang, Bohr-Ran. Highly sensitive ZnO nanowire Co sensors with the adsorption of Au nanoparticles . IOP Publishing Nanotechnology 19 (2008) 175502.Google Scholar
Wei, Shaohong, Wang, Shaomei, Zhang, Yan, and Zhou, Meihua. Different morphologies of ZnO and their ethanol sensing property . Sensors and Actuators B, 192, (2014), pp. 480–487.Google Scholar
Kluth, O, Rech, B, Houben, L, Wieder, S, Schöpe, G, Beneking, C, Wagner, H, Löffl, A, and Schock, H.W. Texture etched ZnO: Al coated glass substrates for silicon based thin film solar cells . Thin Solid Films, 351, (1999), pp. 247–253.Google Scholar
Bao, Jiming, Zimmler, Mariano A., Capasso, Federico, Wang, Xiaowei, and Ren, Z. F.. Broadband ZnO Single-Nanowire Light-Emitting Diode . Nano Letters, 6, (2006), pp. 1719–1722.Google Scholar
Lin Wang, Zhong. Zinc oxide nanostructures: growth, properties and applications . Journal of Physics: Condensed Matter. (2004), pp. 829–831.Google Scholar
Oh, Byeong-Yun, Jeong, Min-Chang, Moon, Tae-Hyoung, Lee, Woong, Myoung, Jae-Min, Hwang, Jeoung-Yeon, and Seo, Dae-Shik. Transparent conductive Al-doped ZnO films for liquid crystal displays . J. Appl. Phys. 99, (2006), 124505.Google Scholar
Tian, Hailin, Fan, Huiqing, Guo, Hui, and Song, Na. Solution-based synthesis of ZnO/carbon nanostructures by chemical coupling for high performance gas sensors . Sensors and Actuators B: Chemical, 195, (2014), pp. 132–139.Google Scholar
Darroudi, Majid, Sabouri, Zahra, Oskuee, Reza Kazemi, Zak, Ali Khorsand, Kargar, Hadi, and Abd Hamid, Mohamad Hasnul Naim. Green chemistry approach for the synthesis of ZnO nanopowders and their cytotoxic effects . Ceramics International, 40, (2014), pp. 4827–4831.Google Scholar
Zeng, Haibo, Cai, Weiping, Li, Yue, Hu, Jinlian, and Liu, Peisheng. Composition/Structural Evolution and Optical Properties of ZnO/Zn Nanoparticles by Laser Ablation in Liquid Media . J. Phys. Chem. B, 109, (2005), pp. 18260–18266.Google Scholar
Carcia, P. F., McLean, R. S., Reilly, M. H., and Nunes, G. Jr. Transparent ZnO thin-film transistor fabricated by RF magnetron sputtering . Appl. Phys. Lett. 82, (2003), 1117.Google Scholar
Sun, X. W., and Kwok, H. S.. Optical properties of epitaxially grown zinc oxide films on sapphire by pulsed laser deposition . J. Appl. Phys. 86, (1999), 408.Google Scholar
Schuler, T, and Aegerter, M.A. Optical, electrical and structural properties of sol gel ZnO: Al coatings . Thin Solid Films, 351, (1999), pp. 125–131.Google Scholar
Hong, Ruoyu, Pan, Tingting, Qian, Jianzhong, and Li, Hongzhong. Synthesis and surface modification of ZnO nanoparticles . Chemical Engineering Journal, 119, (2006), pp. 71–81.Google Scholar
Hjiri, M., El Mir, L., Leonardi, S.G., Pistone, A., Mavilia, L., and Neri, G.. Al-doped ZnO for highly sensitive CO gas sensors . Sensor and Actuators B 196 (2014), pp. 413–420.Google Scholar
Li, X.B., Zhang, Q.Q., Ma, S.Y., Wan, G.X., Li, F.M., and Xu, X.L.. Microstructure optimization and gas sensing improvement of ZnO spherical structure through yttrium doping . Sensor and Actuators B 195 (2014), pp. 256–533.Google Scholar
Chen, Chang Chun, Liu, Ping, and Lu, Chun Hua. Synthesis and characterization of nano-size ZnO powders by direct precipitation method . Chemical Engineering Journal, 144, (2006), pp. 509–513.Google Scholar
Pineda, A. M., Herrera-Rivera, R. and, de la L. Olvera, M.. Synthesis and Characterization of ZnO Powders by Homogeneous Precipitation from Different Precursors. 2014 11th International Conference on Electrical Engineering, Computing Science and Automatic Control (CCE). 978-1-4799-6230-3/14/$31.00 ©2014 IEEEGoogle Scholar
Wang, Jiaheng, Qi, Yang, Zhi, Zhuangzhi, Guo, Jing, Li, Maolin, and Zhang, Ying. A self-assembly mechanism for sol-gel derived ZnO thin films . Smart Materials and Structures IOP Publishing, 16, (2007) pp. 2673–2679.Google Scholar