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Role of the Shuttleworth effect in adhesion on elasticsurfaces

Published online by Cambridge University Press:  22 March 2016

Shayandev Sinha  and
Siddhartha Das
Shayandev Sinha
Affiliation:
Department of Mechanical Engineering, University of Maryland, College Park, Maryland 20742, United States
Siddhartha Das*
Affiliation:
Department of Mechanical Engineering, University of Maryland, College Park, Maryland 20742, United States
*
*E-mail: [email protected]
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Abstract

The Shuttleworth effect ensures that at an interface, where one of the phases isan elastic solid, surface stress is not equal to the surface energy. In thispaper, we provide a free energy based approach to quantify the impact of theShuttleworth effect in the adhesion of a rigid, spherical particle on an elasticsolid. Our paper has four key findings. Firstly, we demonstrate that thedifference in the elastic-solid-particle surface stress and surface energies islinearly proportional to the adhesion energy. Secondly, we establish that thesurface stresses being larger than the surface energies provide the sufficientcondition for an energetically favorable adhesion. Thirdly, we show that for agiven adhesion energy and solid-vapor surface energy increase in particle-vaporsurface energy makes the adhesion, in presence of the Shuttleworth effect, morefavorable. Finally, and most importantly, we identify the necessary parameterspace corresponding to which the Shuttleworth effect may or may not enhance theadhesion as compared to the case that does not account for the Shuttlewortheffect. We anticipate that our findings will significantly impact ourunderstanding of a plethora of problems involving adhesion and indentation onsoft surfaces, such as nanoparticle adhesion on cells, nanoindentation basedcharacterization of soft solids, applications of adhesion-based soft lithographytechniques, etc.

Keywords

adhesionelastic propertiesnano-indentation
Type
Articles
Information
MRS Advances , Volume 1 , Issue 10: Biomaterials and Soft Materials , 2016 , pp. 621 - 630
Copyright
Copyright © Materials Research Society 2016 

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