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Hydrothermal Synthesis of MoO2 Nanoparticles Directly onto a Copper Substrate

Published online by Cambridge University Press:  05 April 2016

Michael McCrory ,
Ashok Kumar  and
Manoj K. Ram
Michael McCrory*
Affiliation:
Department of Mechanical Engineering, University of South Florida, Tampa, Florida 33620, USA
Ashok Kumar
Affiliation:
Department of Mechanical Engineering, University of South Florida, Tampa, Florida 33620, USA Clean Energy Research Center, College of Engineering, University of South Florida, Tampa, FL 33620, USA
Manoj K. Ram
Affiliation:
Clean Energy Research Center, College of Engineering, University of South Florida, Tampa, FL 33620, USA
*
*(Email: [email protected])
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Abstract

Recently, molybdenum oxide (MoO2) has been found to be a chemically stable and relatively inexpensive material for the application as the anode in a lithium ion battery [1-5]. We believe the use of MoO2 in battery applications has been hindered due to a long, complicated, and multistep synthesis process. We present a simple one-pot hydrothermal technique to synthesize MoO2 nanoparticles directly onto a copper (Cu) substrate.

We believe this is a first report of the synthesis of MoO2 directly onto a Cu substrate, and could lead to the ability to both fabricate other materials in a similar manner as well as depositing MoO2 onto other substrates. This technique can reduce anode production time by eliminating the coating process, and also decrease the total amount of chemicals used when compared to a typical powder synthesis and coating processes. The MoO2 coated Cu electrode was characterized using Raman Spectroscopy, Grazing Incident X-ray Diffraction (GIXRD) and scanning electron microscopy (SEM) techniques to confirm the composition, crystallinity and structure of the synthesized MoO2 nanomaterial.

Keywords

energy storagehydrothermalchemical synthesis
Type
Articles
Information
MRS Advances , Volume 1 , Issue 15: Energy and Sustainability , 2016 , pp. 1051 - 1054
Copyright
Copyright © Materials Research Society 2016 

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References

REFERENCES

Chen, X., Zhang, Z., Li, X., Shi, C., and Li, X., Chem. Phys. Lett. 418, 105–108 (2006).CrossRefGoogle Scholar
Tang, Q., Shan, Z., Wang, L., and Qin, X., Electrochimica Acta 79, 148–153 (2012).CrossRefGoogle Scholar
Bhaskar, A., Deepa, M., Rao, T. N., and Varadaraju, U. V., J. Power Sources 216, 169–178 (2012).Google Scholar
Ihsan, M., Wang, H., Majidm, S. R.Yang, J., Kennedy, S. J., Guo, Z., Liu, H. K., Carbon 96, 1200–1207 (2016)CrossRefGoogle Scholar
Yang, L.C., Sun, W., Zhong, Z.W., Liu, J.W., Gao, Q.S., Hu, R.Z., Zhu, M., J. Power Sources 306, 78–84 (2016).Google Scholar
Liu, Y., Zhang, H., Ouyang, P. and Li, Z., Electrochimica Acta 102, 429–435 (2013).Google Scholar
Liang, Y., Yi, Z., Yang, S., Zhou, L., Sun, J. and Zhou, Y., Solid State Ionics 177, 501–505 (2006).CrossRefGoogle Scholar
Gao, H., Liu, C., Liu, Y., Liu, Z., Dong, W., Materials Chem. and Phys. 147, 218–224 (2014).CrossRefGoogle Scholar
International Centre for Diffraction Data (ICDD) Powder Diffraction File Release 2002 PDF-2, last accessed on Dec. 11, 2015.Google Scholar