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Heterogeneous photo–Fenton treatment for degradation of indigo carmine dye

Published online by Cambridge University Press:  29 November 2019

Ismael Cosme-Torres ,
María Guadalupe Macedo-Miranda ,
Sonia Mireya Martinez-Gallegos ,
Julio Cesar González-Juárez ,
Gabriela Roa-Morales ,
Francisco Javier Illescas-Martínez  and
Pedro Ibarra-Escutia
Ismael Cosme-Torres
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, Av. Tecnológico s/n, Colonia Agrícola Bellavista, C.P. 52149, Metepec, México
María Guadalupe Macedo-Miranda*
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, Av. Tecnológico s/n, Colonia Agrícola Bellavista, C.P. 52149, Metepec, México
Sonia Mireya Martinez-Gallegos
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, Av. Tecnológico s/n, Colonia Agrícola Bellavista, C.P. 52149, Metepec, México
Julio Cesar González-Juárez
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, Av. Tecnológico s/n, Colonia Agrícola Bellavista, C.P. 52149, Metepec, México
Gabriela Roa-Morales
Affiliation:
Universidad Autónoma del Estado de México, Facultad de Química, Paseo Colón intersección Paseo Tollocan s/n, C.P. 50120, Toluca, México
Francisco Javier Illescas-Martínez
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, Av. Tecnológico s/n, Colonia Agrícola Bellavista, C.P. 52149, Metepec, México
Pedro Ibarra-Escutia
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, Av. Tecnológico s/n, Colonia Agrícola Bellavista, C.P. 52149, Metepec, México
*
*(Email: [email protected])
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Abstract

The catalyst ZeoSonFe(M1), mixed with hydrogen peroxide and UV light, presented the highest degradation percent within 120 minutes of treatment respect to ZeoSonFe(M2), ZeoSonFe(M3) and ZeoSonFe(M4) which accounted for 72.92, 84.27, and 72.30 %, respectively. The spectrum of UV-Vis degradation showed that the absorption main bands of IC (612 and 286 nm) decrease due to the rupture of C=C bond that belong to the chromophorous group IC. The catalyst ZeoSonFe(M1) was characterized with infrared (FTIR), Scanning Electron Microscopy (SEM) and pore diameter analysis with the BET method. To describe the kinetics of the oxidative reaction the pseudo first order model was applied.

Keywords

compositezeoliteheterogenousoxidation
Type
Articles
Information
MRS Advances , Volume 4 , Issue 59-60: International Materials Research Congress XXVIII , 2019 , pp. 3281 - 3289
Copyright
Copyright © Materials Research Society 2019 

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