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Cobalt Metal ion Doped Cerium Oxide (Co-CeO2) Nanoparticles Effect Enhanced Photocatalytic Activity

Published online by Cambridge University Press:  08 July 2020

G. Killivalavan ,
B. Sathyaseelan ,
G. Kavitha ,
I. Baskarann ,
K. Senthilnathan ,
D. Sivakumar ,
N. Karthikeyan ,
E. Manikandan Open the ORCID record for E. Manikandan [Opens in a new window]  and
M. Maaza
G. Killivalavan
Affiliation:
Research & Development Centre, Department of Physics, Bharathiar University, Coimbatore-641046, Tamil Nadu (TN), India
B. Sathyaseelan*
Affiliation:
Research & Development Centre, Department of Physics, Bharathiar University, Coimbatore-641046, Tamil Nadu (TN), India Department of Physics, University College of Engineering Arni, Anna University Chennai, Arni-632326, TN, India
G. Kavitha
Affiliation:
P.G. & Research Department of Physics, A. M. Jain College, Meenambakkam-600114, Chennai, India
I. Baskarann
Affiliation:
Department of Physics, Arignar Anna Government Arts College, Cheyyar-604407, TN, India
K. Senthilnathan
Affiliation:
Photonics Division, School of Advanced Sciences, VIT University, Vellore-632014, TN, India
D. Sivakumar
Affiliation:
Dept. of Physics, Sree Krishna College of Engineering, Unai, Anaicut-632101, TN, India
N. Karthikeyan
Affiliation:
Department of Physics, Anna University, Chennai-600025, Tamil Nadu, India
E. Manikandan*
Affiliation:
Department of Physics, Government Arts and Science College, Thennangur-604408, Thiruvalluvar University, Vellore, TN, India UNESCO-UNISA Africa Chair in Nanosciences-Nanotechnology, College of Graduate Studies, University of South Africa, Muckleneuk Ridge, PO Box 392, Pretoria, South Africa Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, 1 Old Faure Road, Somerset West 7129, PO Box 722, Somerset West, Western Cape Province, South Africa
M. Maaza
Affiliation:
UNESCO-UNISA Africa Chair in Nanosciences-Nanotechnology, College of Graduate Studies, University of South Africa, Muckleneuk Ridge, PO Box 392, Pretoria, South Africa Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, 1 Old Faure Road, Somerset West 7129, PO Box 722, Somerset West, Western Cape Province, South Africa
*
(*Corresponding Author: [email protected]; [email protected])
(*Corresponding Author: [email protected]; [email protected])
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Abstract

The REE (rare-earth-elements) cerium (Ce) is the most abundant earth-crust element and their oxides have great attention in the form of nanocrystalline nature with superior physical and chemical properties. Pure and Co (1%, 3% and 5%) doped CeO2 nanoparticles (NPs) synthesized by co-precipitation technique were characterized through X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), UV-visible spectroscopy. XRD shows face-centred-cubic (FCC) crystal symmetry with average crystallite size 6–12 nm. HRTEM exhibits almost identical cubical shaped particles with average size 4–10 nm. Tuned band-gap may be observed from UV-visible spectrum of CeO2-NPs upon Co (1%, 3% & 5%) incorporation. Enhancement of the photocatalytic activity observed for Co-doped (1%, 3% & 5%) to the degradation of methylene-blue (MB) dye under visible-light absorption.

Type
Articles
Information
MRS Advances , Volume 5 , Issue 48-49: Energy, Storage and Conversion , 2020 , pp. 2503 - 2515
Copyright
Copyright © Materials Research Society 2020

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References

Laberty-Robert, C.; Long, J. W.; Pettigrew, K. A.; Stroud, R. M.; Rolison, D. R. Ionic Nanowires at 600 °C: Using Nanoarchitecture to Optimize Electrical Transport in Nanocrystalline Gadolinium-Doped Ceria. Adv. Mater. 2007, 19, 1734–1739.10.1002/adma.200601840CrossRefGoogle Scholar
Li, H.; Wang, G.; Zhang, F.; Cai, Y.; Li, He, Wang, G.; Zhang, F.; Cai, Y.; Wang, Y.; Djerdj, I. Surfactant-assisted synthesis of CeO2 nanoparticles and their application in wastewater treatment. RSC Adv. 2012, 2, 12413–12423.10.1039/c2ra21590jCrossRefGoogle Scholar
Zhang, H. X.; He, Z.; Zhang, P.; Li, Y.; Ma, Y.; Kuang, Y.; Zhao, Y.; Chai, Z. Nano-CeO2 Exhibits Adverse Effects at Environmental Relevant Concentrations. Environ. Sci. Technol. 2011, 45, 3725–3730.10.1021/es103309nCrossRefGoogle ScholarPubMed
Asati, A.; Santra, S.; Kaittanis, C.; Nath, S.; Perez, J.M. Oxidase-Like Activity of Polymer-Coated Cerium Oxide Nanoparticles. Angew. Chem. Int. Ed. 2009, 48, 2308–2312.Google Scholar
Chen, F.; Cao, Y.; Jia, D. Preparation and photocatalytic property of CeO2 lamellar. Appl. Surf. Sci. 2011, 257, 9226–9231.10.1016/j.apsusc.2011.06.009CrossRefGoogle Scholar
Gao, F.; Lu, Q.; Komarneni, S. J. Fast Synthesis of Cerium Oxide Nanoparticles and Nanorods. Nanosci. Nanotechnol. 2006, 6, 3812–3819.Google ScholarPubMed
Gu, F.; Wang, Z.; Han, D.;, Shi, C.; Guo, G. Reverse micelles directed synthesis of mesoporous ceria nanostructures. Mater. Sci. Eng. B. 2007, 139, 62–64.10.1016/j.mseb.2007.01.051CrossRefGoogle Scholar
Tsunekawa, S.; Fukuda, T.; Kasuya, A. Blue shift in ultraviolet absorption spectra of monodisperse CeO2−x nanoparticles. J. Appl. Phys. 2000, 87, 1318–1321.10.1063/1.372016CrossRefGoogle Scholar
Mai, H. X.; Sun, L. D.; Zhang, Y. W.; Si, R.; Feng, W.; Zhang, H.P.; Liu, H.C.; Yan, C.H. Shape-Selective Synthesis and Oxygen Storage Behavior of Ceria Nanopolyhedra, Nanorods and Nanocubes. J. Phys. Chem. B 2005, 109, 24380–24385.10.1021/jp055584bCrossRefGoogle ScholarPubMed
Martono, E.; Hyman, M. P.; Vohs, J. M. Reaction Pathways for Ethanol on Model Co/ZnO(0001) Catalysts. Phys. Chem. Chem. Phys. 2011, 13, 9880–9886.10.1039/c1cp20132hCrossRefGoogle ScholarPubMed
Batista, M. S.; Santos, R. K. S.; Assaf, E. M.; Assaf, J. M.; Ticianelli, E. A. Characterization of the Activity and Stability of Supported Cobalt Catalysts for the Steam Reforming of Ethanol. J. Power Sources. 2003, 124, 99–103.10.1016/S0378-7753(03)00599-8CrossRefGoogle Scholar
Huang, L.; Nishinari, K.; Interaction between poly (ethyleneglycol) and water as studied by differential scanning calorimetry. Journal of Polymer Science, Part B: Polymer Physics. 2001,39, 496–506.10.1002/1099-0488(20010301)39:5<496::AID-POLB1023>3.0.CO;2-H3.0.CO;2-H>CrossRefGoogle Scholar
Pastoriza-Santos, I.; Liz-Marzan, L.M.; Synthesis of silver nanoprisms in DMF. Nano Lett. 2 (2002) 903.10.1021/nl025638iCrossRefGoogle Scholar
Zhang, T. M.; Li, J.; Li, H.; Li, Y.; Shen, W. Morphology-dependent redox and catalytic properties of CeO2 nanostructures: Nanowires, nanorods and nanoparticles. Catal. Today. 2009, 148, 179–183.Google Scholar
Wang, Z.; Quan, Z.; Lin, J. Remarkable Changes in the Optical Properties of CeO2 Nanocrystals Induced by Lanthanide Ions Doping. J. Lin, Inorg. Chem. 2007, 46, 5237–5242.10.1021/ic0701256CrossRefGoogle Scholar
American Society for Testing and Material. Powder Diffraction Files; Joint Committee on Powder Diffraction Standards: Swarthmore, PA, 1999, pp 3–888.Google Scholar
Sathyaseelan, B.; Sambasivam, S.; Alagesan, T.; Sivakumar, K. Ex-situ studies on calcinations of structural, optical and morphological properties of post-growth nanoparticles CeO2 by HRTEM and SAED. Int. J. Nano Dimens. 2014, 341–349.Google Scholar
Zhang, F.; Chan, S-W.; Spanier, J.E.; Apak, E.; Jin, Q.; Robinson, R. D.; Irving Herman, P. Cerium oxide nanoparticles: Size-selective formation and structure analysis. Appl Phys Lett 2002, 80,127–129.CrossRefGoogle Scholar
May, G. J. Ionic conductivity and crystal structure of magnesium- and cobalt-doped sodium-beta-alumina. J Mater Sci. 1978,13, 261–267.10.1007/BF00647769CrossRefGoogle Scholar
Li, L.; Sasaki, T.; Shimizu, Y.; Koshizaki, N. Controlled Cobalt Oxide from Two-Dimensional Films to One-Dimensional Nanorods and Zero-Dimensional Nanoparticles: Morphology Dependent Optical Carbon Monoxide Gas-Sensing Properties. J. Phys. Chem. C 2009,113, 15948–15954.10.1021/jp905715gCrossRefGoogle Scholar
Kumar, A.; Kumar, D.; Pandey, G. Characterisation of hydrothermally synthesised CuO nanoparticles at different pH. J. Technological Advances and Scientific Res. 2016, 2(4), 166–169.Google Scholar
Zhang, H.; He, X.; Zhang, Z.; Zhang, P.; Li, Y.; Ma, Y.; Kuang, Y.; Zhao, Y.; Chai, Z. Nano-CeO2 Exhibits Adverse Effects at Environmental Relevant Concentrations. Environ. Sci. Technol. 2011, 45, 3725–3730.CrossRefGoogle ScholarPubMed
Zhang, Q. C.; Yu, Z. H.; Li, G.; Ye, Q. M.; Lin, J. H. Synthesis of quantum-size cerium oxide nanocrystallites by a novel homogeneous precipitation method. J. Alloys Compd. 2009, 477, 81– 84.10.1016/j.jallcom.2008.10.059CrossRefGoogle Scholar
Saravanakumar, K.; Ramjan, M. M.; Suresh, P.; Muthuraj, V. Fabrication of highly efficient visible light driven Ag/CeO2 photocatalyst for degradation of organic pollutants. Alloys and Comp. 2016, 664, 149–160.10.1016/j.jallcom.2015.12.245CrossRefGoogle Scholar
Zhang, L.; Zhang, Q.; Xie, H.; Guo, J.; Lyu, H.; Li, Y.; Sun, Z.; Wang, H.; Guo, Z. Electrospun titania nanofibers segregated by graphene oxide for improved visible light photocatalysis. Appl. Catal. B: Environ. 2017, 201, 470–478.10.1016/j.apcatb.2016.08.056CrossRefGoogle Scholar
Kaviyarasu, K.; Manikandan, E.; Nuru, ZY.; Maaza, M. Investigation on the structural properties of CeO2 nanofibers via CTAB surfactant. Materials Letters. 2015, 160, 61–63.10.1016/j.matlet.2015.07.099CrossRefGoogle Scholar
Xue, Li.; He, Hong.; Liu, Chang.; Zhang, Changbin.; and Zhang, Bo.; Promotion Effects and Mechanism of Alkali Metals and Alkaline Earth Metals on Cobalt–Cerium Composite Oxide Catalysts for N2O Decomposition. Environmental Science & Technology 2009, 43 (3), 890–895.CrossRefGoogle ScholarPubMed
Mwakikunga, BW.; Forbes, A.; Sideras-Haddad, E.; Scriba, M.; Manikandan, E. Self-Assembly and Properties of C:WO3 Nano-Platelets and C:VO2/V2O5 Triangular Capsules Produced by Laser Solution Photolysis. Nanoscale Research Letters. 2010, 5 (2), 389.10.1007/s11671-009-9494-4CrossRefGoogle Scholar
Ranjith, K. S.; Saravanan, P.; Chen, Shih-Hsien.; Dong, Chung-Li.; Chen, Chih Liang.; Chen, Shih-Yun.; Asokan, K.; and Thangavelu, R.; Kumar, R.; Enhanced room-temperature ferromagnetism on Co-doped CeO2 nanoparticles: mechanism and electronic and optical properties. The Journal of Physical Chemistry C 2014, 118 (46), 27039–27047.10.1021/jp505175tCrossRefGoogle Scholar
Becker, J.; Raghupathi, K. R.; Pierre, J. St.; Zhao, D;. Koodali, R.T. Tuning of the Crystallite and Particle Sizes of ZnO Nanocrystalline Materials in Solvothermal Synthesis and Their Photocatalytic Activity for Dye Degradation. J. Phys. Chem. C 2011, 115, 13844–13850.CrossRefGoogle Scholar
Gomathisankar, P.; Hachisuka, K.; Katsumata, H.; Suzuki, T.; Funasaka, K.; Kaneco, S. Photocatalytic Hydrogen Production from Aqueous Na2S + Na2SO3 Solution with B-Doped ZnO. ACS Sustain. Chem. Eng. 2013, 1, 982–988.CrossRefGoogle Scholar
Qin, H.; Li, W.; Xia, Y.; He, T. Photocatalytic Activity of Heterostructures Based on ZnO and N-Doped ZnO. ACS Appl. Mater. Interfaces 2011, 3, 3152–3156.10.1021/am200655hCrossRefGoogle ScholarPubMed
Zhang, L.; Yin, L.; Wang, C.; Lun, N.; Qi, Y. Sol–Gel Growth of Hexagonal Faceted ZnO Prism Quantum Dots with Polar Surfaces for Enhanced Photocatalytic Activity. ACS Appl. Mater. Interfaces 2010, 2, 1769–1773.10.1021/am100274dCrossRefGoogle ScholarPubMed
Lu, X.; Zhai, T.; Cui, H.; Shi, J.; Shi, J.; Xie, S.; Huang, Y.; Liang, C.; Tong, Y. Redox cycles promoting photocatalytic hydrogen evolution of CeO2 nanorods. J. Mater. Chem. 2011, 21, 5569–5572.CrossRefGoogle Scholar
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