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Zincorietveldite, Zn(UO2)(SO4)2(H2O)5, the zinc analogue of rietveldite from the Blue Lizard mine, San Juan County, Utah, USA

Published online by Cambridge University Press:  03 March 2023

Anthony R. Kampf Open the ORCID record for Anthony R. Kampf [Opens in a new window] ,
Travis A. Olds ,
Jakub Plášil Open the ORCID record for Jakub Plášil [Opens in a new window]  and
Joe Marty
Anthony R. Kampf*
Affiliation:
Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA, USA
Travis A. Olds
Affiliation:
Section of Minerals and Earth Sciences, Carnegie Museum of Natural History, 4400 Forbes Avenue, Pittsburgh, PA, USA
Jakub Plášil
Affiliation:
Institute of Physics of the CAS, Na Slovance 1999/2, 18200 Prague 8, Czech Republic
Joe Marty
Affiliation:
Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA, USA
*
Corresponding author: Anthony R. Kampf; Email: [email protected]
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Abstract

The new mineral zincorietveldite (IMA2022-070), Zn(UO2)(SO4)2(H2O)5, was found in the Blue Lizard mine, San Juan County, Utah, USA, where it occurs as yellow to orange–yellow blades in a secondary assemblage with bobcookite, coquimbite, halotrichite, libbyite, metavoltine, rhomboclase, römerite, tamarugite and voltaite. The streak is very pale yellow. Crystals are transparent with vitreous lustre. The tenacity is brittle, the Mohs hardness is ~2½ and the fracture is curved. Cleavage is excellent on {010}, good on {100} and fair on {001}. The mineral is easily soluble in H2O and has a calculated density of 3.376 g⋅cm–3. The mineral is optically biaxial (+) with α = 1.568(2), β = 1.577(2) and γ = 1.595(2); 2V = 70(1)°. Electron microprobe analyses provided (Zn0.720Mg0.109Fe0.091Mn0.046Co0.035)Σ1.00(UO2)(SO4)2(H2O)5. Zincorietveldite is orthorhombic, Pmn21, a = 12.8712(9), b = 8.3148(4), c = 11.2959(4) Å, V = 1208.90(11) Å3 and Z = 4. Zincorietveldite is the Zn analogue of rietveldite. The structural unit is a uranyl-sulfate chain that is also found in the structures of bobcookite, oldsite, oppenheimerite and svornostite.

Keywords

zincorietvelditerietvelditenew mineraluranyl sulfatecrystal structureRaman spectroscopyBlue Lizard mineRed CanyonUtahUSA
Type
Article
Information
Mineralogical Magazine , Volume 87 , Issue 4 , August 2023 , pp. 528 - 533
Copyright
Copyright © The Author(s), 2023. Published by Cambridge University Press on behalf of The Mineralogical Society of the United Kingdom and Ireland.

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Footnotes

Associate Editor: Daniel Atencio

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