Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-24T14:23:08.877Z Has data issue: false hasContentIssue false

The use of zeolites for the treatment of radioactive waste

Published online by Cambridge University Press:  05 July 2018

A. Dyer
Affiliation:
Department of Chemistry and Applied Chemistry, University of Salford, Salford M5 4WT, UK
K. Y. Mikhail
Affiliation:
Department of Chemistry and Applied Chemistry, University of Salford, Salford M5 4WT, UK

Abstract

The uptake of 137-Cs and 90-Sr on to synthetic zeolite A has been studied. The use of a combined barium exchange followed by a relatively mild heat treatment has been shown to fix the isotopes within a collapsed zeolite structure. Leaching experiments using deionized and simulated sea and pond waters were carried out on zeolite compacts and zeolite/cement composites. They demonstrated the effectiveness of the calcination and cement containment. Some comments on the interpretation of leach test data are made.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1985

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Collins, E. D., Campbell, D. O., King, L. J., and Knaues, J. B. (1982) A.I.Ch.E. Symp. Series, No. 213, 78, 915.Google Scholar
Dyer, A., Celler, W. Z., and Shute, M. (1971) ACS Symposium Series 101, 436-42.Google Scholar
Dyer, A., Gettins, R. B., and Brown, J. G. (1970) J. Inorg. Nucl. Chem. 32, 2389-94.CrossRefGoogle Scholar
Dyer, A. and Townsend, R. P. (1973) Ibid. 35, 3001.Google Scholar
Goto, Y., Matsuzawa, J., and Matsuda, S. (1982) Developments in Sedimentology, 35, 789-980.Google Scholar
Guth, J. L., Caullet, P., and Wey, R. (1980) In Proc. 5th Int. Conf. on Zeolites (L. V. C. Rees, ed.), Heyden and Son, 30-9.Google Scholar
Hespe, E. D. (1971) Atomic Energy Review, 9, 195-207.Google Scholar
Matsuzuru, H., and Ito, A. (1978) Health Physics, 34, 643-8.CrossRefGoogle Scholar
Mercer, B. W., and Ames, L. L. (1978) In Natural Zeolites: Occurrence, Properties, Uses (Sand, L. B. and Mumpton, F. A., eds.), Pergamon Press, 451-62.Google Scholar
Roy, Rustum (1981) Ber. Kernforschungsanlage Juelich (Conf.) Juel-Conf-42, (Vol. 42) Proc. Int. Semin. Chem. Process Eng. High-Level Liquid Waste Solidification, 576-602.Google Scholar
Siemens, D. H., Knowlton, D. E., and Shupe, M. W. (1982) A.I.Ch.E. Symp. Series, No. 213, 78, 41-4.Google Scholar
Taylor, M. A., and Kuwairi, A. (1978) Cement and Concrete Res. 8, 491-500.CrossRefGoogle Scholar