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Two-dimensional natural pyrite crystals and their formation

Published online by Cambridge University Press:  05 July 2018

Z. Sawlowicz
Affiliation:
Institute of Geological Sciences, Jagiellonian University, ul. Oleandry 2a, Kraków, Poland
A. Łatkiewicz
Affiliation:
Institute of Geological Sciences, Jagiellonian University, ul. Oleandry 2a, Kraków, Poland
E. Stefaniak
Affiliation:
Institute of Physical Chemistry, Lublin Catholic University, Lublin, Poland

Abstract

Two-dimensional pyrite crystals (40–80 µm wide and 2–3 µm thick) and large thin crusts are reported from the mudstones from the Carboniferous coal basin in Poland. Crystals occur on a flat surface, originally probably a crack in the rock, and are composed of uniform particles (150–200 nm wide). A hypothetical pathway of the formation of 2D pyrite crystals is presented: (1) formation of pyrite particles (or monosulphide precursors) in the suspension introduced onto the surface of the crack, and forming a film with a smooth meniscus at the air/suspension interface on the rock substrate; (2) thinning of the suspension film due to the water loss, increase of particle concentration, and formation of the first monolayers; (3) growth leading to the formation of thin crystals complying with pyrite crystallography.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2005

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References

Bianconi, P.A., Lin, J. and Strzelecki, A.R. (1991) Crystallisation of an inorganic phase controlled by a polymer matrix. Nature, 349, 315317..CrossRefGoogle Scholar
Bronold, M., Kubala, S., Pettenkofer, C. and Jaegermann, W. (1997) Thin pyrite (FeS2) films by molecular beam deposition. Thin Solid Films, 304, 178182.CrossRefGoogle Scholar
Cairns-Smith, A.G., Hall, A.J. and Russell, M.J. (1992) Mineral theories of the origin of life and an iron sulfide example. Origin Life Evolution Biosphere, 22, 161180.CrossRefGoogle Scholar
Craig, J.R., Vokes, F.M. and Solberg, T.N. (1998) Pyrite: physical and chemical textures. Mineralium Deposita, 34, 82101.CrossRefGoogle Scholar
Dushkin, C.D., Lazarov, G.S., Kotsev, S.N., Yoshimura, H. and Nagayama, K. (1999) Effect of growth conditions on the structure of two-dimensional latex crystals: experiment. Colloid Polymer Science, 111, 914930.CrossRefGoogle Scholar
LaMer, V.K. and Dinegar, R.H. (1950) Theory, Production and Mechanism of Formation of Monodispersed Hydrosols. Journal of the American Chemical Society, 72, 48474854.CrossRefGoogle Scholar
Laufer, E.E., Scott, J.D and Packwood, R. (1985) Inhibition of pyrite growth by amorphous carbon. The Canadian Mineralogist, 23, 5760.Google Scholar
Maenosono, S., Dushkin, CD., Yamaguchi, Y., Nagayama, K. and Tsuji, Y. (1999) Effect of growth conditions on the structure of two-dimensional latex crystals: modelling. Colloid Polymer Science, 111, 11521161.CrossRefGoogle Scholar
Mann, S. (1988) Molecular recognition in biomineralization. Nature, 332, 119124.CrossRefGoogle Scholar
Matijevic, E. (1996) Internally and externally composite monodispersed colloid particles. Pp. 1 — 12 in: Fine Particles Science and Technology (Pelizzetti, E., editor). Kluwer Academic Publishers, Dordrecht, The Netherlands.Google Scholar
Morse, J.W. and Qiwei, W. (1997) Pyrite formation under conditions approximating those in anoxic sediments: II. Influence of precursor iron minerals and organic matter. Marine Chemistry 57, 187193CrossRefGoogle Scholar
Porzycki, J. (1980) Fundamental properties of the geological structure and evaluation of the deposits of the Lublin Coal Basin. Biuletyn Instytutu Geologicznego (Warszawa), 328, 2135.Google Scholar
Rickard, D.T., Schoonen, N.A.A. and Luther, G.W. III (1995) Chemistry of iron sulphides in sedimentary environments. Pp. 168193 in: Geochemical Transformations of Sedimentary Sulfur (Vairavamurthy, M.A. and M.Schoonen, A.A., editors). ACS Symposium Series, 612, American Chemical Society.CrossRefGoogle Scholar
Sawlowicz, Z. (1993) Pyrite framboids and their development: a new conceptual mechanism. Geologische Rundschau, 82, 148156.CrossRefGoogle Scholar
Sawlowicz, Z. (2000) Framboids: from their origin to application. Mineralogical Transactions (PAN Krakow), 88, 180.Google Scholar
Schoonen, M.A.A. and Barnes, H.L. (1991a) Reactions forming pyrite and marcasite from solution. I. Nucleation of FeS2 below 100°C. Geochimica et Cosmochimica Acta, 55, 14951504.CrossRefGoogle Scholar
Schoonen, M.A.A. and Barnes, H.L. (1991b) Reactions forming pyrite and marcasite from solution. II. Via FeS precursor below 100°C. Geochimica et Cosmochimica Acta, 55, 15051514.CrossRefGoogle Scholar
Taylor, G.R. (1982) A mechanism for framboid formation as illustrated by a volcanic exhalative sediment. Mineralium Deposita, 17, 2336.CrossRefGoogle Scholar
Wächtershauser, G. (1988) Pyrite formation, the first energy source for life: a hypothesis. Systematic Applied Microbiology, 10, 207210.CrossRefGoogle Scholar
Wei, D. and Osseo-Asare, K. (1997) Aqueous synthesis of finely divided pyrite particles. Colloids & Surfaces A: Physicochemical Engineering Aspects, 121, 2736.CrossRefGoogle Scholar
Wilkin, R.T. and Barnes, H.L. (1997) Formation processes of framboidal pyrite. Geochimica et Cosmochimica Acta, 61, 323339.CrossRefGoogle Scholar
Yamamoto, A., Nakamura, M., Seki, A, Li, EX., Hashimoto, A. and Nakamura, S. (2003) Pyrite (FeS2) thin films prepared by spray method using FeSO4 and (NH4)2SX . Solar Energy & Solar Cells 75, 451456CrossRefGoogle Scholar