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A study of iron-bearing rutiles in the paragenesis TiO2-Al2O3-P2O5-SiO2

Published online by Cambridge University Press:  05 July 2018

A. Putnis
Affiliation:
Department of Mineralogy and Petrology, University of Cambridge, Downing Place, Cambridge CB2 3EW
M. M. Wilson
Affiliation:
Department of Geology and Mineralogy, University of Queensland, St. Lucia, Queensland 4067

Summary

Hydrothermal ruffles from a suite of rocks at Mount Perry, Queensland, have been studied in thin section, by electron microprobe analysis, and by transmission electron microscopy. The iron-bearing rutiles, while originally singte-phase, are found to exsolve a sequence of iron-rich precipitates on experimental annealing, with hematite being formed as the stable equilibrium precipitate. Experiments at different temperatures and annealing times enable a time-temperature-transformation plot to be drawn for the exsolution process. The kinetics of this process are used to conclude that the rutiles formed below about 450 °C.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1978

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References

Buravikhin, (V. A.), Litvintsev, (V. V.), and Ushakov, (A. I.), 1977. Polymorphic transformations and physical properties of thin films. Phys. stat. sol. (a), 40, 1127.Google Scholar
Chadwick, (G. A.), 1972. Metallography of phase transformations. Butterworths.Google Scholar
Champness, (P. E.) and Lorimer, (G. W.), 1976. Exsolution in silicates, 174204. In Wenk, (H. R.), ed. Electron microscopy in mineralogy, Springer-Verlag, Berlin.CrossRefGoogle Scholar
Christian, (J. W.), 1975. The theory of transformations in metals and alloys, 2nd edn. Pergamon Press, Oxford.Google Scholar
Connah, (T. H.), 1957. Lode rutile, Mount Perry. Queensland Govt Min. J. 58, 909-11.Google Scholar
Deer, (W. A.), Howie, (R. A.), and Zussman, (J.), 1966. An introduction to the rock-forming minerals. Longman.Google Scholar
Denaro, (T.), 1976. The geology of the Mount Perry rutile deposits. Department of Geology, University of Queensland. Unpublished Honours Thesis.Google Scholar
El Goresy, (A.) and Ramdohr, (P.), 1975. Subsolidus reduction of lunar opaque oxides: Textures, assem-blages, geochemistry and evidence for a late-stage endogenic gaseous mixture. Proc. 6th Lunar Sci. Conf. 1, 729-45.Google Scholar
Esphenshade, (G. H.) and Potter, (D. B.), 1960. Kyanite, sillimanite and andalusite deposits of the southeastern States. U.S. Geol. Surv. Prof. Pap. 336.CrossRefGoogle Scholar
Geijer, (P.), 1963. Genetic relationships of the paragenesis Al2SiO5-lazulite-rutile.Ark. Miner. geol. 3(24), 423-64.Google Scholar
Gross, (E. B.) and Parwell, (A.), 1968. Rutile mineralization at the White Mountain andalusite deposits, California. Ibid. 4(29), 493-7.Google Scholar
Haggerty, (S. E.), 1976. Opaque mineral oxides in terrestrial igneous rocks, pp. Hg 101-277 in Rumble, (D.), ed. Oxide Minerals, Min. Soc. Am. Short Course Notes, 3.CrossRefGoogle Scholar
Kandiah, (K.), Smith, (A. J.), and White, (G.), 1975. A pulse processor for X-ray spectrometry with Si(Li) detectors. Paper 2.9 2nd ISPRA Nuclear Electronics Symposium, Stresa, Italy.Google Scholar
Lindsley, (D. H.), 1965. Iron-titanium oxides, Carnegie Inst. Washington Year Book, 64, 144-8.Google Scholar
Lindsley, (D. H.) 1976. The crystal chemistry and structure of oxide minerals as exemplified by the Fe-Ti oxides, pp. L 61-88 in Rumble, (D.), ed. Oxide Minerals, Min. Soc. Am. Short Course Notes, 3.Google Scholar
Martin, (J. W.) and Doherty, (R. D.), 1976. Stability of microstructure in metallic systems. Cambridge University Press.Google Scholar
Putnis, (A.), 1977. The mechanism of exsolution of hematite from natural iron-bearing rutiles. Submitted to Phys. Chem. Minerals. Google Scholar
Ross, (C. S.), 1941. Occurrence and origin of the titanium deposits of Nelson and Amhurst Counties, Virginia. U.S. Geol. Surv. Prof. Pap. 198.Google Scholar
Shewmon, (P. G.), 1969. Transformations in metals. McGraw-Hill.Google Scholar
Statham, (P. J.), 1976. A comparative study of techniques for quantitative analysis of the X-ray spectra obtained with a Si(Li) detector. X-ray Spectrometry, 5, 1628.CrossRefGoogle Scholar
Verhoeven, (J. D.), 1975. Fundamentals of physical metallurgy. Wiley.Google Scholar
Wittke, (J. P.), 1967. Solubility of iron in rutile. J. Am. Ceram. Soc. 50, 586-8.CrossRefGoogle Scholar