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Stability constants and formation of Cu(II) and Zn(II) phosphate minerals in the oxidized zone of base metal orebodies

Published online by Cambridge University Press:  05 July 2018

M. Clara
Affiliation:
Department of Chemistry, University of Aveiro, Aveiro, Portugal
F. Magalhães
Affiliation:
Department of Chemistry, University of Aveiro, Aveiro, Portugal
Julio Pedrosa de Jesus
Affiliation:
Department of Chemistry, University of Aveiro, Aveiro, Portugal
Peter A. Williams
Affiliation:
Department of Chemistry, University College, PO Box 78, Cardiff CF1 1XL, Wales, UK

Abstract

The free energies of formation of the minerals libethenite, Cu2PO4OH, pseudomalachite, Cu5(PO4)2(OH)4, cornetite, Cu3PO4(OH)3, tarbuttite, Zn2PO4OH, spencerite, Zn2PO4OH · 1.5H2O, and scholzite, CaZn2(PO4)2 · 2H2O, have been determined at 298.2 K using solution techniques. The values of ΔfG° (298.2 K) for the above minerals are, respectively, −1228.8±3.0, −2840.3±4.2, −1600.9±5.9, −1632.1±4.0, −1982.4±3.1, and −3556.7±7.6 kJ mol−1. These results, together with others from the literature concerning hopeite, Zn3(PO4)2·4H2O, hydroxyapatite, Ca5(PO4)3(OH), and the synthetic salt Cu3(PO4)2 · 2H2O have been used to construct a model for the formation of suites of Zn(II) and Cu(II) phosphate minerals found in the oxidation zone of base metal orebodies. The distributions and modes of occurrence of many natural assemblages of these minerals are readily explained by the model. Particular attention has been focused on deposits at Broken Hill, Zambia, and Saginaw Hill, Arizona, USA.

Type
Mineral Chemistry
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1986

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Footnotes

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Author for correspondence

References

Aires-Barros, L. (1966) Garcia de Orta. 14, 103-8.Google Scholar
Baes, C.F., and Mesmer, R.E. (1976) The Hydrolysis of Cations. John Wiley and Sons.Google Scholar
Berry, L.G. (1950) Am. Mineral. 35, 365-85.Google Scholar
Chubb, E.C. (1908) Proc. Rhodesia Scientific Assoc. 7, 21-5.Google Scholar
Embrey, P.G. (1978) Mineral. Mag. 42, 169-77.Google Scholar
Environmental Protection Agency (1979) Methods for Chemical Analysis of Water and Waste.Choice of Research and Development, US Environmental Protection Agency. Cincinatti, Ohio.Google Scholar
Henderson, B. (1981) Mineral. Rec. 12, 105-11.Google Scholar
Hey, M.H. (1955) An Index of Mineral Species and Varieties Arranged Chemically.British Museum (Natural History).Google Scholar
Johnston, C.W., and Hill, R.J. (1978) Mineral. Rec. 9, 20-4.Google Scholar
Khin, B. (1970. Ibid. 1, 117-18.Google Scholar
Korowski, S.P., and Notebaart, C.W. (1978. Ibid. 9, 341-6.Google Scholar
McColl, D.H. (1978. Ibid. 9, 295.Google Scholar
Noble, R.J. (1980) Quart. Geol. Notes Geol. Surv. S. Aust. 76, 2-5.Google Scholar
Notebaart, C.W., and Korowski, S.P. (1980) Mineral. Rec. 11, 339-48.Google Scholar
Nriagu, J.O. (1975) Can. J. Earth Sci. 13, 717-36.Google Scholar
Nriagu, J.O. (1984) in Phosphate Minerals (J. O. Nriagu and P. B. Moore, eds.). Springer-Verlag, 318-29.CrossRefGoogle Scholar
Nriagu, J.O. and Dell, C.I. (1974) Am. Mineral. 59, 934-46.Google Scholar
Nriagu, J.O. and Dell, C.I. and Moore, P.B., eds. (1984) Phosphate Minerals. Springer-Verlag.CrossRefGoogle Scholar
Perrin, D.D., and Sayce, I.G. (1967) Talanta. 14, 833-42.CrossRefGoogle Scholar
Robie, R.A., Hemingway, B.S., and Fisher, J.R. (1978) Thermodynamic Properties of Minerals and Related substances at 298.15 K and 1 Bar (105 Pascals) Pressure and at Higher Temperatures. US Geol. Surv. Bull. 1452.Google Scholar
Roe, A. (1980) Mineral. Rec. 11, 261-5.Google Scholar
Smith, R.M., and Martell, A.E. (1976) Critical Stability Constants. Plenum Press.CrossRefGoogle Scholar
Spencer, L.J. (1908) Mineral. Mag. 15, 1-38.Google Scholar
Truesdell, A.H., and Jones, B.F. (1974) J. Res. US Geol. Surv. 2, 233-48.Google Scholar
Vieillard, P., and Tardy, Y. (1984) in Phosphate Minerals (J. O. Nriagu and P. B. Moore, eds.). Springer-Verlag, 171214.CrossRefGoogle Scholar
Volkov, A.I. (1979) Khim. Khim. Tekhnol. (Minsk). 14, 58-64.Google Scholar
Walker, T.L. (1916) Mineral. Mag. 18, 76-81.Google Scholar
Walker, T.L. (1918) Univ. Toronto Stud., Geol. Ser. 10, 1-25.Google Scholar
White, F. (1908) Proc. Rhodesia Scientific Assoc. 7, 13-21.Google Scholar