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Single-crystal X-ray diffraction, EMPA, FTIR and X-ray photoelectron spectroscopy study of narsarsukite from Murun Massif, Russia

Published online by Cambridge University Press:  02 January 2018

E. Schingaro ,
E. Mesto ,
M. Lacalamita ,
F. Scordari ,
E. Kaneva  and
F. N. Vladykin
E. Schingaro
Affiliation:
Dipartimento di Scienze della Terra e Geoambientali, Università degli Studi di Bari “Aldo Moro”, via E. Orabona 4, Bari I-70125, Italy
E. Mesto*
Affiliation:
Dipartimento di Scienze della Terra e Geoambientali, Università degli Studi di Bari “Aldo Moro”, via E. Orabona 4, Bari I-70125, Italy
M. Lacalamita
Affiliation:
Dipartimento di Scienze della Terra e Geoambientali, Università degli Studi di Bari “Aldo Moro”, via E. Orabona 4, Bari I-70125, Italy
F. Scordari
Affiliation:
Dipartimento di Scienze della Terra e Geoambientali, Università degli Studi di Bari “Aldo Moro”, via E. Orabona 4, Bari I-70125, Italy
E. Kaneva
Affiliation:
Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk-33, 664033, Russia
F. N. Vladykin
Affiliation:
Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk-33, 664033, Russia
*
*E-mail: [email protected]
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Abstract

A crystal chemical study of narsarsukite from the Murun alkaline massif, Russia has been carried out combining single-crystal X-ray diffraction, electron microprobe analyses, micro-Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS). The narsarsukite single crystals are tetragonal (space group I4/m) with unit-cell parameters: 10.7140(1) ≤ a ≤ 10.7183(2) Å and 7.9478(1) ≤ c ≤ 7.9511(1) Å. The XPS analysis showed that Fe occurs in the mineral as Fe3+, whereas the FTIR spectrum showed that the sample studied is anhydrous. The average crystal chemical formula of the Murun narsarsukite is: Na2.04K0.01(V0.015+Ti0.74Zr0.01Al0.01Fe0.223+Mg0.01)1.00Si4.00(O10.74F0.23OH0.03)11.00. Structural disorder at octahedral and interstitial sites was modelled and also discussed in consideration of the main substitutional mechanism Ti4+ + O2– ↔ Fe3+ + (F–, OH–) active in the structure of the mineral.

Keywords

narsarsukiteiron speciationdisorder modellingcrystal chemistry
Type
Research Article
Information
Mineralogical Magazine , Volume 81 , Issue 2 , April 2017 , pp. 339 - 354
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2017

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