Hostname: page-component-cd9895bd7-8ctnn Total loading time: 0 Render date: 2024-12-27T08:51:26.963Z Has data issue: false hasContentIssue false
  • English
  • Français

Rare sulfides enriched in K, Tl and Pb from the Noril'sk and Salmagorsky complexes, Russia: new data and implications

Published online by Cambridge University Press:  02 January 2018

Andrei Y. Barkov ,
Robert F. Martin  and
Louis J. Cabri
Andrei Y. Barkov*
Affiliation:
Research Laboratory of Industrial and Ore Mineralogy, Cherepovets State University, 5 Lunacharsky Avenue, 162600 Cherepovets, Russia
Robert F. Martin
Affiliation:
Department of Earth and Planetary Sciences, McGill University, 3450 University Street, Montreal, Quebec, H3A 2A7 Canada
Louis J. Cabri
Affiliation:
Cabri Consulting Inc., 700-702 Bank Street, PO Box 14087, Ottawa, Ontario, K1S 3V0 Canada
*
*E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

New results (compositional data and reflectance values) are reported for some rare sulfides enriched in K, Tl and Pb, which are related to djerfisherite, thalfenisite, bartonite, a “Cl-bearing bartonite”, or chlorbartonite, and also for shadlunite, from the Noril'sk and Salmagorsky complexes, Russia. Our observations and comparisons with relevant data in the literature imply that: (1) bartonite is probably a S-dominant (or Cl-free) analogue of djerfisherite; and a “Cl-bearing bartonite” and chlorbartonite are probably compositional variants of the djerfisherite–bartonite series. (2) The most probable formulae of bartonite and djerfisherite are (K,Me2+)6(Fe,Cu,Ni)25–xS26(S,Cl) and (K,Me2+)6(Fe,Cu,Ni)25–xS26(Cl,S), where 0 ≤ x ≤ 5, respectively. (3) Two independent substitution mechanisms probably operate in the natural series. A coupled substitution [Me2+ + S2– ↔ K+ + Cl–] is reflected by an observed deficit in K, accompanied by the incorporation of Me2+(Pb, Fe, or Ni) in the K site. Another mechanism is inferred to be [2Fe3+ + 〈 ↔ 3Fe2+], which assumes the existence of vacancy-type defects at the Me site. Thus, the second mechanism could possibly control the existing variations of Σ(Fe, Cu, Ni) in the range of ∼21 to 25 a.p.f.u., documented in djerfisherite- and bartonite-type minerals. The minerals analysed from Noril'sk, which are free of Cl and related to bartonite and to a Tl-dominant analogue of bartonite (unnamed species), probably crystallized from microvolumes of late fluid rich in K and Tl, under conditions of relatively low oxygen fugacity in the environment. Uniform contentss of Fe and Cu, observed in coexisting phases of normal (Cl-bearing) djerfisherite and bartonite (or Cl-free analogue of djerfisherite) at Salmagorsky imply that they reached equilibrium with regard to the distribution of these elements during crystallization. These phases probably formed as a result of fluctuations in the ratios of sulfur and chlorine fugacity in a fluid at a postmagmatic hydrothermal stage.

Keywords

sulfidesdjerfisheritethalfenisitebartonitechlorbartoniteshadlunitecompositional variationsmechanisms of substitutionreflectance valuesNoril'skSalmagorskyRussia
Type
Research Article
Information
Mineralogical Magazine , Volume 79 , Issue 3 , June 2015 , pp. 799 - 808
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2015

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Armstrong, J.T. (1995) CITZAF: A package of correction programs for the quantitative electron microbeam X-ray analysis of thick polished materials, thin films, and particles. Microbeam Analysis, 4, 177–200.Google Scholar
Azarova, Yu.V., Krinov, D.I. and Sokolova, M.N. (2006) A structural and genetic relationship of djerfisherite and bartonite, and the problem of isomorphous substitutions in the system djerfisherite-“Cu-djerfisherite”-bartonite. Novye Dannye o Mineralakh [New Data on Minerals], 41, 98–107. [in Russian].Google Scholar
Azarova, Yu.V., Krinov, D.I. and Krivovichev, S.V. (2010) New data on the structure of djerfisherite and its structural relationship with bartonite. Proceedings of the XI-th Session of the Russian Mineralogical Society and Fyodorov’ 2010 Session. St-Petersburg, Russia [pp. 5–7. in Russian].Google Scholar
Barkov, A.Y., Laajoki, K.V.O., Gehör, S.A., Yakovlev, Y.N. and Taikina-Aho, O. (1997) Chlorine-poor analogues of djerfisherite-thalfenisite from Noril’sk, Siberia and Salmagorsky, Kola Peninsula, Russia. The Canadian Mineralogist, 35, 1421–1430.Google Scholar
Cabri, L.J. and Szymański, J.T. (1998) On the synthesis and crystal structure of Ba6Cu12Fe13S27: a discussion. Journal of Solid State Chemistry, 137, 353. Clarke, D.B., Mitchell, R.H., Chapman, C.A.T. and Mackay, R.M. (1994) Occurrence and origin of djerfisherite from the Elwin Bay kimberlite, Somerset Island, Northwest Territories. The Canadian Mineralogist, 32, 815–823.Google Scholar
Czamanske, G.K., Erd, R.C., Leonard, B.F. and Clark, J.R. (1981) Bartonite, a new potassium iron sulfide mineral. The American Mineralogist, 66, 369–375.Google Scholar
Dmitrieva, M.T. (1976) The crystallochemical formulae of djerfisherite according to structural positions. I zvestiya Akademii Nauk SSSR; Seriya Geologicheskaya, 4, 97–101. [in Russian].Google Scholar
Evstigneeva, T.L., Genkin, A.D., Troneva, N.V., Filimonova, A.A. and Tsepin, A.I. (1973) Shadlunite, a new sulphide of copper, iron, lead, manganese, and cadmium from copper-nickel ores. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva, 102, 63–74. [in Russian].Google Scholar
Fuchs, L.H. (1966) Djerfisherite, alkali copper-iron sulfide: a new mineral from enstatite chondrites. Science, 153, 166–167.CrossRefGoogle ScholarPubMed
Genkin, A.D., Troneva, N.V. and Zhuravlev, N.N. (1969) The first find in ores of a potassium, iron and copper sulfide-djerfisherite. Geologiya Rudnykh Mestorozhdeniy, 5, 57–64. [in Russian].Google Scholar
Genkin, A.D., Distler, V.V., Gladyshev, G.D., Filimonova, A.A., Evstigneeva, T.L., Kovalenker, V.A., Laputina, I.P. , Smirnov, A.V. and Grokhovskaya, T.L. (1981) Sulphide Copper-Nickel Ores of the Noril’sk Deposits. Nauka, Moscow, 233 pp. [in Russian].Google Scholar
Korobeinikov, A.N., Mitrofanov, F.P., Gehör, S., Laajoki, K.V., Pavlov, V.P. and Mamontov, V.P. (1998) Geology and copper sulphide mineralization of the Salmagorskii ring igneous complex, Kola Peninsula, NW Russia. Journal of Petrology, 39, 2033–2041.CrossRefGoogle Scholar
Laflamme, J.H.G., Roberts, A.C., Criddle, A.J. and Cabri, L.J. (1995) Owensite , (Ba,Pb)6 (Cu,Fe,Ni)25S27, a new mineral species from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon. The Canadian Mineralogist, 33, 665–670.Google Scholar
Llanos, J., Mujica, C., Wittke, O., Gomez-Romero, P. and Ramirez, R. (1997) Synthesis and crystal structure of Ba6Cu12Fe13S27. Journal of Solid State Chemistry, 128, 62–65.CrossRefGoogle Scholar
Llanos, J., Rojas, D. and Mujica, C. (1998) Physical properties of the cubic phase Sr6Cu12Fe13S27. Boletín de la Sociedad Chilena de Química, 43, 177–182. [in Spanish].Google Scholar
Roig, A., Molins, E., Casan-Pastor, N., Gomez-Romero, P., Mujica, C. and Llanos, J. (1998) Mössbauer spectroscopy and magnetic properties of the threedimensional cubic phase Ba6Cu12Fe13S27. Materials Research Bulletin, 33, 1347–1352.CrossRefGoogle Scholar
Rudashevsky, N.S., Karpenkov, A.M., Shipova, G.S., Shishkin, N.N. and Ryabikin, V.A. (1979) Thalfenisite-the thallium analogue of djerfisherite. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva, 108, 696–701. [in Russian].Google Scholar
Sharygin, V.V., Kamenetsky, V.S. and Kamenetsky, M.B. (2008) Potassium sulfides in kimberlite-hosted chloride-“nyerereite” and chloride clasts of Udachnaya-East pipe, Yakutia, Russia. The Canadian Mineralogist, 46, 1079–1095.CrossRefGoogle Scholar
Snyder, G.J., Badding, M.E. and Disalvo, F.J. (1992) Synthesis, structure, and properties of Ba6Co25S27: a perovskite-like superstructure of Co8S6 and Ba6S clusters. Inorganic Chemistry, 31, 2107–2110.CrossRefGoogle Scholar
Szymański, J.T. (1995) The crystal structure of owensite, (Ba,Pb)6(Cu,Fe,Ni)25S27, a new member of the djerfisherite group. The Canadian Mineralogist, 33, 671–677.Google Scholar
Yakovenchuk, V.N., Pakhomovsky, Ya.A., Men’shikov, Yu.P., Ivanyuk, G.Yu., Krivovichev, S.V. and Burns, P.C. (2003) Chlorbartonite, K6Fe24S26(Cl,S), a new mineral species from a hydrothermal vein in the Khibina massif, Kola Peninsula, Russia: description and crystal structure. The Canadian Mineralogist, 41, 503–511.CrossRefGoogle Scholar
Zaccarini, F., Thalhammer, O.A.R., Princivalle, F., Lenaz, D., Stanley, C.J. and Garuti, G. (2007) Djerfisherite in the Guli dunite complex, Polar Siberia: a primary or metasomatic phase? The Canadian Mineralogist, 45, 1201–1211.Google Scholar