Hostname: page-component-cd9895bd7-jkksz Total loading time: 0 Render date: 2024-12-24T20:08:44.789Z Has data issue: false hasContentIssue false
  • English
  • Français

Partitioning of trace elements between garnet, clinopyroxene and diamond-forming carbonate-silicate melt at 7 GPa

Published online by Cambridge University Press:  05 July 2018

A. V. Kuzyura ,
F. Wall ,
T. Jeffries  and
Yu. A. Litvin
A. V. Kuzyura*
Affiliation:
Institute of Experimental Mineralogy RAS, 142432, Institutskaya Str., 4, Chernogolovka, Moscow region, Russia
F. Wall
Affiliation:
Camborne School of Mines, University of Exeter, Cornwall Campus, Truro, Cornwall TR10 9EZ, UK
T. Jeffries
Affiliation:
Department of Mineralogy, Natural History Museum, Cromwell Road, London SW7 5BD, UK
Yu. A. Litvin
Affiliation:
Institute of Experimental Mineralogy RAS, 142432, Institutskaya Str., 4, Chernogolovka, Moscow region, Russia
*
*E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

Concentrations of trace elements in coexisting garnet, clinopyroxene and completely miscible carbonate-silicate melt (formed at 7 GPa from the Chagatai silicocarbonatite rock known to be diamondiferous) were determined using LA-ICP-MS. The partition coefficients for Li, Rb, Cs, Ba, Th, U, Ta, Nb, La, Ce, Pb, Pr, Sr, Nd, Zr, Hf, Sm, Eu, Gd, Tb, Dy, Y, Ho, Er, Tm, Yb, Lu, Sc and Zn were determined. The new experimental data for trace-element partitioning between garnet, clinopyroxene and carbonate-silicate melt have been compared with published data for partitioning between garnet, clinopyroxene and carbonatite melt, and garnet, clinopyroxene and silicate melt. The results show that the trace-element partitioning is not significantly altered by changes in melt composition, with HREE always concentrated in the garnet. Carbonate-silicate melt, as a diamond-forming medium, and carbonatite or silicate melt equilibrated with mantle silicate minerals, behave similarly in respect of trace-element distribution.

Keywords

trace elementspartition coefficientcarbonate-silicate meltgarnetclinopyroxenediamond-forming medium
Type
Research Article
Information
Mineralogical Magazine , Volume 74 , Issue 2 , April 2010 , pp. 227 - 239
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bobrov, A.V., Litvin, Yu.A. and Divaev, F.K. (2004) Phase relations and diamond synthesis in the carbonate-silicate rocks of the Chagatai complex, Western Uzbekistan: Results of experiments at P = 4–7 GPa and T = 1200–1700°C. Geochemistry International, 42, 39–48.Google Scholar
Djuraev, A.D. and Divaev, F.K. (1999) Melanocratic carbonatites – new type of diamond-bearing rocks, Uzbekistan. Pp. 639–642 in: Mineral Deposits: Processes to Processing (Stanley, S.N., editor). Balkena, Rotterdam.Google Scholar
Dobosi, G. and Kurat, G. (2002) Trace element abundances in garnets and clinopyroxenes from diamondites – a signature of carbonatitic fluids. Mineralogy and Petrology, 76, 21–38.CrossRefGoogle Scholar
Harte, B. and Kirkley, M. (1997) Partitioning of trace elements between clinopyroxene and garnet: data from mantle eclogites. Chemical Geology, 136, 1–24.CrossRefGoogle Scholar
Ireland, T.R., Rudnick, R.L. and Spetsius, Z. (1994) Trace elements in diamond inclusions from eclogites reveal link to Archean granites. Earth and Planetary Science Letters, 128, 199–213.CrossRefGoogle Scholar
Kennedy, C.S. and Kennedy, G.C. (1976) The equilibrium boundary between graphite and diamond. journal of Geophysical Research, 81, 2467–2470.CrossRefGoogle Scholar
Kurat, G. and Dobosi, G. (2000) Garnet and diopside-bearing diamondites (framesites). Mineralogy and Petrology, 69, 143–159.CrossRefGoogle Scholar
Lapin, A.V., Divaev, F.K. and Kostityn, Yu.A. (2005) Petrochemical interpretation of carbonatite-like rocks from the Chagatai complex of the Tien Shan with application to the problem of diamond potential. Petrology, 13, 499–511.Google Scholar
Litvin, Yu.A. (2007 a) High pressure mineralogy of diamond genesis. Pp. 83–103 in: Advances in High-Pressure Mineralogy (Ohtani, E., editor). Special Paper 421, Geological Society of America, Boulder, Colorado, USA.Google Scholar
Litvin, Yu.A. (2007 b) Experiment in solution of the diamond genesis problem. Zapiski of the Russian Mineralogical Society, 136, Special Issue 7, 138–158. (in Russian).Google Scholar
Litvin, Yu.A. (2009) Experimental study of physico-chemical conditions of diamond formation in the mantle substance. Russian Geology and Geophysics, 50(12), 1188–1200.CrossRefGoogle Scholar
Litvin, Yu.A., Jones, A.P., Beard, A.D., Divaev, F.K. and Zharikov, V.A. (2001) Crystallization of diamond and syngenetic minerals in melts of diamondiferous carbonatites of the Chagatai Massif, Uzbekistan: experiment at 7.0 GPa. Doklady Earth Sciences, 381(9), 1066–1070.Google Scholar
Litvin, Yu.A., Kurat, G. and Dobosi, G. (2005) Experimental study of diamondite formation in carbonate-silicate melts: a model approach to natural processes. Russian Geology and Geophysics, 46(12), 1285–1300.Google Scholar
Litvin, Yu.A., Litvin, V.Yu. and Kadik, A.A. (2008) Experimental characterization of diamond crystallization in melts of mantle silicate-carbonate-carbon systems at 7.0–8.5 GPa. Geochemistry International, 46(6), 531–553.CrossRefGoogle Scholar
Moore, K.R., Wall, F., Divaev, F.K. and Savatenkov, V.M. (2009) Mingling of carbonate and silicate magmas under turbulent flow conditions: Evidence from rock textures and mineral chemistry in sub-volcanic carbonatite dykes in Chagatai, Uzbekistan. Lithos, 110, 65–82.CrossRefGoogle Scholar
Navon, O., Izraeli, E.S. and Klein-BenDavid, O. (2003) Fluid inclusions in diamonds – the carbonatitic connection. 8th International Kimberlite Conference Long Abstracts, FLA_0107.Google Scholar
Schrauder, M. and Navon, O. (1994) Hydrous and carbonatitic mantle fluids in fibrous diamonds from Jwaneng, Botswana. Geochimica et Cosmochimica Acta, 58, 761–771.CrossRefGoogle Scholar
Schrauder, M., Koeberl, Ch. and Navon, O. (1996) Trace element analyses of fluid-bearing diamonds from Jwaneng, Botswana. Geochimica et Cosmochimica Acta, 60, 4711–4724.CrossRefGoogle Scholar
Shimizu, N. and Richardson, S.H. (1987) Trace element abundance patterns of garnet inclusions in peridotite-suite diamonds. Geochimica et Cosmochimica Acta, 51, 755–758.CrossRefGoogle Scholar
Shushkanova, A.V. and Litvin, Yu.A. (2005) Phase relations in diamond-forming carbonate-silicate-sulfide systems on melting. Russian Geology and Geophysics, 46, 1355–1344.Google Scholar
Shushkanova, A.V. and Litvin, Yu.A. (2008) Experimental evidence for liquid immiscibility in the model system CaCO3 – pyrope – pyrrotite at 7.0 GPa: the role of carbonatite and sulfide melts in diamond genesis. The Canadian Mineralogist, 46, 991–1005.CrossRefGoogle Scholar
Sweeney, R.J., Green, D.H. and Sie, S.H. (1992) Trace and minor element partitioning between garnet and amphibole and carbonatitic melt. Earth and Planetary Science Letters, 114, 1–14.CrossRefGoogle Scholar
Sweeney, R.J., Prozesky, V. and Przybylowich, W. (1995) Selected trace and minor element partitioning between peridotite minerals and carbonatite melts at 18–46 kb pressure. Geochimica et Cosmochimica Ada, 59, 3671–3683.CrossRefGoogle Scholar
van Westrenen, W., Blundy, J. and Wood, B. (1999) Crystal-chemical controls of trace element partitioning between garnet and anhydrous silicate melt. American Mineralogist, 84, 838–847.CrossRefGoogle Scholar
Walter, M.J., Bulanova, G.P., Armstrong, L.S., Keshav, S., Blundy, J.D., Gudfinnson, G., Lord, O.T., Lennie, A.R., Clark, S.M., Smith, C.B. and Gobbo, L. (2008) Primary carbonatite melt from deeply subducted oceanic crust. Nature, 454, 622–626.CrossRefGoogle ScholarPubMed
Zedgenizov, D.A., Kagi, H., Shatsky, V.S. and Sobolev, N.V. (2004) Carbonatitic melts in cuboid diamonds from Udachnaya kimberlite pipe (Yakutia): evidence from vibrational spectroscopy. Mineralogical Magazine, 68, 61–73.CrossRefGoogle Scholar