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New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XVII. Paraberzeliite, NaCaCaMg2(AsO4)3, an alluaudite-group member dimorphous with berzeliite

Published online by Cambridge University Press:  12 January 2022

Igor V. Pekov ,
Natalia N. Koshlyakova ,
Dmitry I. Belakovskiy ,
Marina F. Vigasina ,
Natalia V. Zubkova ,
Atali A. Agakhanov ,
Sergey N. Britvin ,
Evgeny G. Sidorov  and
Dmitry Yu. Pushcharovsky
Igor V. Pekov*
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia
Natalia N. Koshlyakova
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia
Dmitry I. Belakovskiy
Affiliation:
Fersman Mineralogical Museum of the Russian Academy of Sciences, Leninsky Prospekt 18-2, 119071 Moscow, Russia
Marina F. Vigasina
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia
Natalia V. Zubkova
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia
Atali A. Agakhanov
Affiliation:
Fersman Mineralogical Museum of the Russian Academy of Sciences, Leninsky Prospekt 18-2, 119071 Moscow, Russia
Sergey N. Britvin
Affiliation:
St. Petersburg State University, University Emb. 7/9, 199034 St. Petersburg, Russia
Evgeny G. Sidorov
Affiliation:
Institute of Volcanology and Seismology, Far Eastern Branch of Russian Academy of Sciences, Piip Boulevard 9, 683006 Petropavlovsk-Kamchatsky, Russia
Dmitry Yu. Pushcharovsky
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia
*
*Author for correspondence: Igor V. Pekov, Email: [email protected]
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Abstract

The new alluaudite-group mineral paraberzeliite was found in the Arsenatnaya fumarole, Second scoria cone of the Northern Breakthrough of the Great Tolbachik Fissure Eruption, Tolbachik volcano, Kamchatka, Russia. In the deepest zone of Arsenatnaya, paraberzeliite (holotype) is associated with anhydrite, diopside, hematite, svabite, berzeliite, schäferite, calciojohillerite, magnesioferrite, ludwigite, fluorapatite, powellite, baryte, and rhabdoborite-group and aphthitalite-group members. In the middle zone of the fumarole, paraberzeliite occurs with hematite, calciojohillerite, badalovite, johillerite, nickenichite, tilasite, svabite, fluorophlogopite, sanidine, cassiterite, anhydrite, metathénardite and belomarinaite. Paraberzeliite forms prismatic crystals up to 0.2 mm × 0.2 mm × 1 mm often occurring in open-work aggregates. It is transparent, brown (from light to dark brown, sometimes with purple or red hue) or green (from pale greenish to yellow–green). The mineral is brittle, cleavage was not observed. The Mohs hardness is 3½. Dcalc is 3.811 g cm–3. Paraberzeliite is optically biaxial (+), α = 1.718(4), β = 1.728(4), γ = 1.742(4) and 2Vmeas. = 85(5)°. The chemical composition (wt.%, electron-microprobe; holotype) is: Na2O 6.43, CaO 16.65, MgO 11.64, MnO 1.65, CuO 0.06, Fe2O3 2.45, V2O5 1.10, As2O5 59.46, total 99.44. The calculated empirical formula based on 12 O atoms per formula unit is (Na1.20Ca1.71Mg1.66Mn0.13Fe3+0.18)Σ4.88(As2.98V0.07)Σ3.05O12. Paraberzeliite is monoclinic, C2/c, a = 12.3143(7), b = 13.0679(5), c = 6.7717(4) Å, β = 113.657(7)°, V = 998.14(10) Å3 and Z = 4. The crystal structure was solved from single-crystal X-ray diffraction data, R = 0.0349. Paraberzeliite is isostructural with other alluaudite-group minerals. Its simplified crystal chemical formula is A(1)CaA(2)'NaM(1)CaM(2)Mg2(TAsO4)3. The idealised formula is NaCa2Mg2(AsO4)3, or, according to the actual nomenclature of alluaudite-group arsenates, NaCaCaMg2(AsO4)3. The name paraberzeliite reflects the dimorphism of this alluaudite-group mineral with the arsenate garnet berzeliite, ideally (Ca2Na)Mg2(AsO4)3.

Keywords

paraberzeliitenew mineralalluaudite groupberzeliitearsenatecrystal structurefumarole sublimateTolbachik volcanoKamchatka
Type
Article
Information
Mineralogical Magazine , Volume 86 , Issue 1 , February 2022 , pp. 103 - 111
Copyright
Copyright © The Author(s), 2022. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

†

Deceased 20 March 2021

Associate Editor: Ian T. Graham

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