Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-23T22:20:29.108Z Has data issue: false hasContentIssue false

Mineralogy of the near-surface expression of Au-As-Cu mineralization in an arid environment

Published online by Cambridge University Press:  05 July 2018

R. Bogoch
Affiliation:
Geological Survey of Israel, 30 Malkhei Israel St., Jerusalem 95501, Israel
M. Shirav
Affiliation:
Geological Survey of Israel, 30 Malkhei Israel St., Jerusalem 95501, Israel
A. Gilat
Affiliation:
Geological Survey of Israel, 30 Malkhei Israel St., Jerusalem 95501, Israel
L. Halicz
Affiliation:
Geological Survey of Israel, 30 Malkhei Israel St., Jerusalem 95501, Israel

Abstract

In the arid, Late Precambrian terrain of southern Israel, a complex suite of minerals and amorphous species were deposited in host gneiss from fluids under near-neutral conditions within 1 m of the surface. The morphology of secondary gold appears to relate to its host mineral (skeletal-dendritic with quartz; multi-faceted crystals with arsenates; spherical droplets with iron oxide). The gold is very fine-grained, and was most likely complexed as a thiosulphate.

Three amorphous phases are present (iron oxide, chrysocolla, Cu-Mn-(Fe-As) silicate). At least in part, gold and baryte appear to have crystallized out of a metal-Fe-oxide gel. Other minerals, including apatite, anglesite, and conichalcite, may have grown from appropriate crystallites present in the gel.

The conichalcite occurs mainly as bladed to acicular radial spherulites. In the presence of lead, a solid solution phase between duftite and conichalcite (‘Pb-conichalcite’) was formed.

Type
Mineralogy
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Andrade, W. O., Machesky, M. L. and Rose, A. W. (1991) Gold distribution and mobility in the surficial environment, Carajas region, Brazil. In Geochemical Exploration 1989. (A. W. Rose and P. M. Taufen, eds.). J. Geochem. Expl, 40, 95–114.CrossRefGoogle Scholar
Bergeron, M. and Harrison, Y. (1989) Le transport chimique de l'or dans les environments de surface: formation d'un colloide et complexation organi-que. Can. J. Earth Set, 26, 2327–32.CrossRefGoogle Scholar
Bogoch, R., Shirav, M., Beyth, M. and Halicz, L. (1993) Geochemistry of ephemeral stream sedi-ments in the Precambrian mountainous terrain of southern Israel. J. Geochem. Expl., 46, 349—64.Google Scholar
Bowell, R. J. (1992) Supergene gold mineralogy at Ashanti, Ghana: Implications for the supergene behaviour of gold. Mineral. Mag., 56, 545—60.Google Scholar
Cabello, J. (1985) Geochemical prospecting at the Caracoles silver district, Atacama Desert, Anto-fagasta Province, Chile. In Prospecting in Areas of Desert Terrain (G. R. Davis, ed.) Inst. Mining Metall., London, 21-30.Google Scholar
Dana, E. S. (1911) The System of Mineralogy, 6th ed., John Wiley, New York.Google Scholar
Enzweiler, J. and Joekes, I. (1991) Adsorption of colloidal gold on colloidal iron oxides. In Geochemical Exploration 1989. (A. W. Rose and P. M. Taufen, eds.. J. Geochem. Expl., 40, 133–42.CrossRefGoogle Scholar
Grigor'ev, D. P. (1965) Ontogeny of minerals., Isr. Program. Sci. Trans., Jerusalem, 250 pp.CrossRefGoogle Scholar
Jambor, J. L., Owens, D. R. and Dutrizac, J. E. (1980) Solid solution in the adelite group of arsenates. Canad. Mineral., 18, 191—5Google Scholar
Lakin, H. W., Curtin, G. C. and Hubert, A. E. (1974) Geochemistry of gold in the weathering cycle. U.S. Geol. Surv. Bull,. 1330, 80 pp.Google Scholar
Magalhaes, M. C. F. and Pedrosa de Jesus, J. D. (1988) The chemistry of formation of some secondary arsenate minerals of Cu(II), Zn(II) and Pb(II). Mineral. Mag., 52, 679–90.CrossRefGoogle Scholar
Mann, A. W. (1984) Mobility of gold and silver in lateritic weathering profiles: some observations from Western Australia. Econ. Geol. 70, 38-49.Google Scholar
Nancollas, G. H. The precipitation of calcium phosphates. Thermodynamic and kinetics consid-erations. Proc. 2nd Inter. Congr. on Phosphorous Compounds, Institut Mondial du Phosphat, 11-23.Google Scholar
Palache, C, Berman, H. and Frondel, C. (1951) Dana's system of Mineralogy, 2, John Wiley, New York, 806-8.Google Scholar
Prieto, M., Putnis, A., Arribas, J. and Fernandez-Diaz, L. (1992) Ontogeny of baryte crystals grown in a porous medium. Mineral. Mag., 56, 587—98.Google Scholar
Qurashi, M. M. and Barnes, W. H. (1963) The structure of the minerals of the descloizite and adelite groups; IV, descloizite and conichalcite (part 2), the structure of conichalcite. Canad. Mineral, 7, 561–77.Google Scholar
Radcliffe, D. and Simmons, W. B. Jr. (1971) Austinite: chemical and physical properties in relation to conichalcite. Amer. Mineral., 56, 1359–65.Google Scholar
Richardson, S. and Vaughan, D. J. (1989) Arseno-pyrite: a spectroscopic investigation of altered surfaces. Mineral. Mag., 53, 223–9.CrossRefGoogle Scholar
Robins, R. G. (1981). The solubility of metal arsenates. Metall. Trans., B, 12B, 103-9Google Scholar
Saunders, J. A. (1990) Colloidal transport of gold and silica in epithermal precious-metal systems: Evi-dence from the Sleeper deposit, Nevada. Geology, 18, 757–60.2.3.CO;2>CrossRefGoogle Scholar
Tipping, E. (1981) The adsorption of aquatic humic substances by iron oxides. Geochim. Cosmochim. Ada, 45, 191–9.CrossRefGoogle Scholar
Tipping, E. and Ohnstad, M. (1984) Colloid stability of iron oxide particles from a freshwater lake. Nature, 308, 266–8.CrossRefGoogle Scholar
Vasconcelos, P. and Kyle, J.R. (1991) Supergene geochemistry and crystal morphology of gold in a semiarid weathering environment: application to gold exploration. In Geochemical Exploration 1989. A. W. Rose and P. M. Taufen (eds.. J. Geochem. Expl, 40, 115–32.CrossRefGoogle Scholar
Webster, J. G. (1986) The solubility of gold and silver in the system Au-Ag-S-O2-H2O at 25°C and 1 atm. Geochim. Cosmochim. Ada, 50, 1837–45.CrossRefGoogle Scholar
Webster, J. G. and Mann, A. W. (1984) The influence of climate, geomorphology and primary geology on the supergene migration of gold and silver. J. Geochem. Expl., 22, 21–42.CrossRefGoogle Scholar
Weiser, H. B. (1933) Inorganic colloid chemistry. Vol. I, The colloidal elements. John Wiley, New York, 389 pp.Google Scholar