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Mineralogical controls on storage of As, Cu, Pb and Zn at the abandoned Mathiatis massive sulphide mine, Cyprus

Published online by Cambridge University Press:  05 July 2018

K. A. Hudson-Edwards  and
S. J. Edwards
K. A. Hudson-Edwards*
Affiliation:
Research School of Earth Sciences at UCl-Birkbeck, Birkbeck, University of London, London WC1E 7HX, UK
S. J. Edwards
Affiliation:
Department of Earth and Environmental Sciences, University of Greenwich at Medway, Chatham Maritime, Kent ME4 4TB, UK
*
*E-mail: [email protected]
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Abstract

The Mathiatis massive sulphide deposit in Cyprus was a low-grade (0.3% Cu), three million ton ore body of pyrite and minor chalcopyrite occurring within basaltic lavas of the Troodos ophiolite. Cessation of mining in 1987 left a deep open pit surrounded by large heaps of spoil, which are undergoing oxidation and leaching. The aim of this study was to determine the mineralogical controls on the storage and potential remobilization of As, Cu, Pb and Zn within, and from, mine spoil heaps. Most of the spoil samples collected, and related materials (stream sediment, reaction zone between a boulder of massive pyrite and calcareous chert, salt crusts on stream beds), are enriched in As (27—220 ppm), Cu (110—400 ppm), Pb (10—140 ppm) and Zn (290—12,000 ppm) relative to both the basalt and calcareous chert (As 4—10 ppm, Cu 20—76 ppm, Pb 3—6 ppm, Zn 39—200 ppm).

Arsenic, Cu, Pb and Zn in the spoil and related materials are associated with Fe(-Al-S)-O, Fe(-Al-Mg)-S-O, Al(-Mg-Fe)-S-O and Mg(-Al-Fe)-S-O phases (the brackets represent minor components of less than 20 wt.% within the phases). Chemical extraction work using CaCl2 suggests that Cu, Zn and to some extent, As, are potentially more soluble than Pb. This is corroborated by the very high total concentrations of Cu and Zn in both the secondary salt crusts and the reaction zone material, high CaCl2-extractable As, Cu and Zn in the salt crusts, and aqueous data for the Mathiatis mine area collected for a European Union LIFE report. This may have implications for ecosystem health and water quality in the Mathiatis area and areas of similar mineralogy and climate world wide.

Keywords

mine spoilarseniccopperleadzincMathiatisCyprussulphate
Type
Research Article
Information
Mineralogical Magazine , Volume 69 , Issue 5 , October 2005 , pp. 695 - 706
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2005

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References

Alpers, C.N., Nordstrom, D.K. and Thompson, J.M. (1994) Seasonal variations of Zn/Cu ratios in acid mine water from Iron Mountain, California. Pp. 324–344 in: Environmental Geochemistry ofSulfide Oxidation (Alpers, C.N. and Blowes, D.W., editors). American Chemical Society Symposium Series, 550.Google Scholar
Bayless, E.R. and Olyphant, G.A (1993) Acid-generating salts and their relationship to the chemistry of groundwater and storm runoff at an abandoned mine site in southwestern Indiana U.S.A. Journal of Contaminant Hydrology, 12, 313–328.CrossRefGoogle Scholar
Bigham, J.M. and Nordstrom, D.K. (2000) Iron and aluminium hydroxysulfates from acid sulphate waters. Pp. 351–403 in: Sulfate Minerals Crystallography, Geochemistry, and Environmental Significance. Reviews in Mineralogy and Geochemistry, 40. Mineralogical Society of America and the Geochemical Society, Washington, D.C.Google Scholar
Boult, S., Collins, D.N., White, K.N. and Curtis, C.D. (1994) Metal transport in stream polluted by acid mine drainage; the Afon Goch, Anglesey, UK. Environmental Pollution, 84, 279–284.CrossRefGoogle ScholarPubMed
Buckby, T., Black, S., Coleman, M.L. and Hodson, M.E. (2003) Fe-sulphate-rich evaporative mineral precipitates from the Rio Tinto, southwest Spain. Mineralogical Magazine, 67, 263—278.CrossRefGoogle Scholar
Chapman, B.M., Jones, D.R. and Jung, R.F. (1983) Processes controlling the metal ion attenuation in acid mine drainage streams. Geochimica et Cosmochimica Acta, 47, 1957–1973.CrossRefGoogle Scholar
Charalambides, A., Kyriacou, E., Constantinou, C., Baker, J., van Os, B., Gurnari, G., Shiathas, A., van Dijk, P. and van der Meer, F. (1998) Mining Waste Management on Cyprus: Assessment, Strategy Development and Implementation. LIFE project final report, Geological Survey Department, Nicosia.Google Scholar
Constantinou, G. (1980) Metallogenesis associated with Troodos ophiolite. Pp. 663–674 in: Ophiolites —Proceedings, International Ophiolite Symposium, Cyprus 1979 (Panayiotou, A., editor). Geological Survey Department Cyprus, Nicosia.Google Scholar
Courtin-Nomade, A., Bril, H., Neel, C. and Lenain, J.-F. (2003) Arsenic in iron cements developed within tailings of a former metalliferous mine — Enguialès, Aveyron, France. Applied Geochemistry, 18, 395–408.CrossRefGoogle Scholar
Cravotta, C.A.I. (1994) Secondary iron-sulfate minerals as sources of sulphate and acidity. Pp. 345–364 in: 204th National Meeting of the American Chemical Society (Alpers, C.N. and Blowes, D.W., editors). American Chemical Society, Washington D.C.Google Scholar
Dutrizac, J.E. and Jambor, J.L. (2000) Jarosites and their application in hydrometallurgy. Pp. 405–452 in: Sulfate Minerals — Crystallography, Geochemistry, and Environmental Significance (Alpers, C.N., Jambor, J. and Nordstrom, D.K., editors). Reviews in Mineralogy and Geochemistry, 40. Mineralogical Society of America and the Geochemical Society, Washington, D.C.Google Scholar
Edwards, S.J., Harper, M. and Malpas, J. (1996) Oxidising sulphides, acid drainage and metal-rich sediments in the disused copper mines of Cyprus. Pp. 402–405 in: Fourth International Symposium on the Geochemistry of the Earth's Surface. International Association of Geochemistry and Cosmochemistry, Ilkley, UK.Google Scholar
Förstner, U. and Wittman, G.T.W. (1981) Metal Pollution in the Aquatic Environment. Springer-Verlag, Berlin.CrossRefGoogle Scholar
Foster, A.L., Brown, G.E. Jr, Tingle, T.N. and Parks, G.A. (1998) Quantitative arsenic speciation in mine tailings using X-ray absorption spectroscopy. American Mineralogist, 83, 553—568.CrossRefGoogle Scholar
Hochella, M.F. Jr., Moore, J.N., Golla, U. and Putnis, A. (1999) A TEM study of samples from acid mine drainage systems: Metal-mineral association with implications for transport. Geochimica et Cosmochimica Acta, 63, 3395–3406.CrossRefGoogle Scholar
Hudson-Edwards, K.A., Schell, C. and Macklin, M.G. (1999) Mineralogy and geochemistry of alluvium contaminated by metal mining in the Rio Tinto area, southwest Spain. Applied Geochemistry, 14, 55–70.CrossRefGoogle Scholar
Jambor, J.L. (2000) The relationship of mineralogy to acid- and neutralization-potential values in ARD. Pp. 141 — 159 in: Environmental Mineralogy: Microbial Interactions, Anthropogenic Influences, Contaminated Land and Waste Management (Cotter-Howells, J.D., Campbell, L.S., Valsami-Jones, E. and Batchelder, M., editors). Mineralogical Society Series, 9. Mineralogical Society, London.Google Scholar
Jambor, J.L., Nordstrom, D.K. and Alpers, C.N. (2000) Metal-sulfate salts from sulphide mineral oxidation. Pp. 303–350 in: Sulfate Minerals -Crystallography, Geochemistry, and Environmental Significance (C.N., Alpers, J., Jambor and D.K., Nordstrom, editors). Reviews in Mineralogy and Geochemistry, 40. Mineralogical Society of America and the Geochemical Society, Washington, D.C.Google Scholar
Jerz, J.K. and Rimstidt, J.D. (2003) Efflorescent iron sulphate minerals: paragenesis, relative stability, and environmental impact. American Mineralogist, 88, 1919–1932.CrossRefGoogle Scholar
Johnson, C.A. (1986) The regulation of trace element concentrations in river and estuarine waters contaminated with acid mine drainage: The adsorption of Cu and Zn on amorphous Fe oxyhydroxide. Geochimica et Cosmochimica Acta, 50, 2433—2438.CrossRefGoogle Scholar
Langmuir, D. and Whittemore, D.O. (1971) Variations in the stability of precipitated ferric oxyhydroxides. Pp. 209–234 in: Non-equilibrium Systems in Natural Water Chemistry (Hem, J.D., editor). American Chemical Society, Advances in Chemistry Series, 106.CrossRefGoogle Scholar
Lin, Z. (1997) Mobilization and retention of heavy metals in mill-tailings from Garpenberg sulfide mines, Sweden. Science of the Total Environment, 198, 13–31.CrossRefGoogle Scholar
Nordstrom, D.K. (1982) Aqueous pyrite oxidation and the consequent formation of secondary iron minerals. Pp. 37–63 in: Acid Sulfate Weathering (Kittrick, J.A., Fanning, D.S. and Hossner, L.R., editors). Soil Science Society of America, Wisconsin, Madison.Google Scholar
Nordstrom, D.K. and Alpers, C.N. (1999) Geochemistry of acid waters. Pp. 133–156 in: The Environmental Geochemistry of Mineral Deposits, Part A: Processes, Techniques and Health Issues (Plumlee, G.S. and Logsdon, M.G., editors). Society of Economic Geologists, Reviews in Economic Geology, 6A.Google Scholar
Nordstrom, D.K., Ball, J.W., Robertson, C.E. and Hanshaw, B.B. (1984) The effect of sulphate on aluminium concentrations in natural waters: II. Field occurrences and identification of aluminium hydroxysulphate precipitates. Geological Society of America Program with Abstracts, 16(6), 611.Google Scholar
Novozamsky, I., Lexmond, T.H. and Houba, V.J. (1993) A single extraction procedure of soil for evaluation of uptake of some heavy metals by plants. International Journal of Environmental Analytical Chemistry, 51, 47–58.CrossRefGoogle Scholar
Palache, C., Berman, H. and Frondel, C. (1951) The System of Mineralogy, 7th edition, vol. 2. John Wiley and Sons Inc., New York.Google Scholar
Pickering, W.F. (1986) Metal ion speciation — soils and sediments (A review). Ore Geology Reviews, 1, 83–146.CrossRefGoogle Scholar
Savage, K.S., Tingle, T.N., O'Day, P.A., Waychunas, G.A. and Bird, D.K. (2000) Arsenic speciation in pyrite and secondary weathering phases, Mother Lode Gold District, Tuolumne County, California. Applied Geochemistry, 15, 1219–1244.CrossRefGoogle Scholar
Smith, K.S. (1999) Metal sorption on mineral surfaces: an overview with examples relating to mineral deposits. Pp. 161 — 182 in: The Environmental Geochemistry of Mineral Deposits, Part A. Processes, Techniques and Health Issues. Society of Economic Geologist, Reviews in Economic Geology, 6A.Google Scholar
Vidal, M., López-Sánchez, J.F., Sastre, J., Jiménez, G., Dagnac, T., Rubio, R. and Rauret, G. (1999) Prediction of the impact of the Aznalcóllar toxic spill on the trace element contamination of agricultural soils. Science of the Total Environment, 242, 131–148.CrossRefGoogle ScholarPubMed
Wong, C.K. and Malpas, J.A. (2000) Case study of acid mine drainage, Sia, Cyprus: preliminary results. Pp. 365–376 in: Proceedings of the Third International Conference on the Geology of the Eastern Mediterranean (Panayides, I., Xenophontos, C. and Malpas, J., editors). Geological Survey Department Cyprus, Nicosia.Google Scholar