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Micromorphological instability of a growing face as a source of oscillatory zoning in crystals

Published online by Cambridge University Press:  05 July 2018

A. G. Shtukenberg  and
YU. O. Punin
A. G. Shtukenberg*
Affiliation:
Crystallography Department, Geological Faculty, St. Petersburg State University, Universitetskaya emb., 7/9, 199034 St. Petersburg, Russia
YU. O. Punin
Affiliation:
Crystallography Department, Geological Faculty, St. Petersburg State University, Universitetskaya emb., 7/9, 199034 St. Petersburg, Russia
*
*E-mail: [email protected]
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Abstract

Oscillatory zoning in solid solutions of alums ((K,NH4)Al(SO4)2·12H2O, K(Al,Cr)(SO4)2·12H2O, (K,Rb)Al(SO4)2·12H2O) and nitrates of divalent metals ((Sr,Pb)(NO3)2, (Ba,Pb)(NO3)2) grownfrom low-temperature aqueous solutions is considered. The zoning is detected by means of X-ray diffraction topography, crystal optics and electron probe microanalysis and involves variations of the crystal composition and degree of the growth ordering of atoms. The zoning patterns are very different in the predominant ﹛111﹜ and ﹛1̄11﹜ and subordinate ﹛100﹜ and ﹛110﹜ growth sectors. The different types of micromorphological instabilities of a growing face are suggested to explain the origin of the observed zoning.

Keywords

oscillatory zoningalumlead nitratestrontium nitratebarium nitratedislocation growth
Type
Research Article
Information
Mineralogical Magazine , Volume 75 , Issue 1 , February 2011 , pp. 169 - 183
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2011

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