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Flow field-flow fractionation (FlFFF) coupled to sensitive detection techniques: a way to examine radionuclide interactions with nanoparticles

Published online by Cambridge University Press:  05 July 2018

M. Bouby ,
N. Finck  and
H. Geckeis
M. Bouby*
Affiliation:
Karlsruher Institut für Technologie-Campus Nord (KIT-CN), Institut für Nukleare Entsorgung (INE), Postfach 3640, D-76021 Karlsruhe, Germany
N. Finck
Affiliation:
Karlsruher Institut für Technologie-Campus Nord (KIT-CN), Institut für Nukleare Entsorgung (INE), Postfach 3640, D-76021 Karlsruhe, Germany
H. Geckeis
Affiliation:
Karlsruher Institut für Technologie-Campus Nord (KIT-CN), Institut für Nukleare Entsorgung (INE), Postfach 3640, D-76021 Karlsruhe, Germany
*
*E-mail: [email protected]
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Abstract

The capabilities of the asymmetrical flow field-flow fractionation (AsFlFFF) technique coupled with inductively coupled plasma mass spectrometry and UV–Vis spectrophotometry in the characterization of synthetic and natural colloidal samples are demonstrated in two different systems.The first system is a sol of hectorite which was co-precipitated in the presence of Lu. The results show that hectorite nanoparticles can be mobilized from a bulk sample and that they still contain the dopant Lu, which is homogeneously incorporated into the hectorite crystal structure. Thesecond system is a natural groundwater from the Gorleben site on the northern German plain, which is being tentatively explored to assess its suitability as a nuclear waste repository. Colloidal matter heterogeneity is evident in this system. Alkaline-earth elements are mainly found as ionicspecies. Rare earth elements (REEs) and actinides are distributed in two main colloidal fractions: the heavier REEs and U are concentrated in the <4 nm fraction corresponding to the size range of organic colloidal particles, whereas lighter REEs and Th are concentratedin colloidal particles between 4 and 18 nm in size that are both organic and inorganic in nature. Similar results are reported for another sample from the same site, collected ∼2 km from the first one, demonstrating the homogeneity of the aquifer system and/or a possible colloid migrationpathway. The extent of the reversibility of colloid–radionuclide interactions remains to be evaluated.

Keywords

colloidsnanoparticlesradioactive wasterare earth elementslutetiumhectoritelanthanidesactinidesflow field-flow fractionationFLFFF
Type
Research Article
Information
Mineralogical Magazine , Volume 76 , Issue 7 , December 2012 , pp. 2709 - 2721
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2016

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