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Ferroelastic phase transition in SrAl2Si2O8 feldspar at elevated pressure

Published online by Cambridge University Press:  05 July 2018

M. D. McGuinn
Affiliation:
Department of Geology, The University, Manchester, M13 9PL, United Kingdom
S. A. T. Redfern
Affiliation:
Department of Geology, The University, Manchester, M13 9PL, United Kingdom

Abstract

Synthetic end-member strontium feldspar (SrAl2Si2O8) has been studied in a diamond-anvil cell at elevated pressures up to 10.3 GPa using energy-dispersive X-ray powder diffraction. Cell parameters have been refined between ambient pressure and 6 GPa. SrAl2Si2O8 undergoes a ferroelastic phase transition from the ambient pressure monoclinic space group I2/c to the high-pressure triclinic space group I at 3.2 ± 0.4 GPa. The transition appears to be first-order and the ferroelastic and co-elastic components of the spontaneous strain tensor have been calculated.

Type
Mineralogy
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1994

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References

Aizu, K. (1970) Determination of the state para-meters and formulation of spontaneous strain for ferroelastics. J. Physical Soc. Japan, 28, 706–16.Google Scholar
Angel, R. J. (1988) High pressure structure of anorthite. Amer. Mineral, 73, 1114–9.Google Scholar
Bambauer, H-U. and Nager, H. E. (1981) Gitterkon-stanten und displazive transformationen synthe-tischer Erdalkalifeldspate: I. System Ca[Al2Si2O8]-Sr[Al2Si2O8]-Ba[AI2Si208]. N. Jahrb. Min. Abh., 141, 225–39.Google Scholar
Bruno, E. and Gazzoni, G. (1970) Single crystal investigations on strontium feldspar. Zeit. Krist, 132, 327–31.Google Scholar
Decker, D. L. (1971) High-pressure equation of state of NaCl, KC1 and CsCl. J. App. Phys., 42, 3239–44.Google Scholar
Hackwell, T. P. and Angel, R. J. (1993) High pressure, high temperature inversion in anorthite. Terra abstracts, supplement no.l to Terra Nova, 5, 490.Google Scholar
Hazen, R. M. (1977) Temperature, pressure, and composition: structurally analogous variables. Phys. Chem. Min., 1, 83–94.Google Scholar
Jensen, B. B. (1973) Patterns of trace element partitioning. Geochim. Cosmochim. Ada, 37, 2227–42.Google Scholar
McGuinn, M. D. and Redfern, S. A. T. (1994) Ferroelastic phase transition along the join CaAl2Si2O8-SrAl2Si2O8. Amer. Mineral., (in press).Google Scholar
Piermarini, G. J., Block, S. and Barnett, J. D. (1973) Hydrostatic limits in liquids and solids to 100 kbar. J. App. Phy., 44, 5377–82.Google Scholar
Piermarini, G. J., Block, S. and Salje, E. (1987) Thermodynamics of plagioclase II: Temperature evolution of the spontaneous strain at the /1-P1 phase transition in anorthite. Phy. Chem. Min., 14, 189–95.Google Scholar