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Dzierżanowskite, CaCu2S2 – a new natural thiocuprate from Jabel Harmun, Judean Desert, Palestine Autonomy, Israel

Published online by Cambridge University Press:  02 January 2018

Irina O. Galuskina ,
Evgeny V. Galuskin ,
Krystian Prusik ,
Yevgeny Vapnik ,
Rafał Juroszek ,
Lidia Jeżak  and
Mikhail Murashko
Irina O. Galuskina*
Affiliation:
Faculty of Earth Sciences, Department of Geochemistry, Mineralogy and Petrography, University of Silesia, Będzińska 60, 41-200 Sosnowiec, Poland
Evgeny V. Galuskin
Affiliation:
Faculty of Earth Sciences, Department of Geochemistry, Mineralogy and Petrography, University of Silesia, Będzińska 60, 41-200 Sosnowiec, Poland
Krystian Prusik
Affiliation:
Institute of Materials Science, University of Silesia, 75 Pułku Piechoty 1A, 41-500 Chorzów, Poland
Yevgeny Vapnik
Affiliation:
Department of Geological and Environmental Sciences, Ben-Gurion University of the Negev, POB 653, Beer-Sheva 84105, Israel
Rafał Juroszek
Affiliation:
Faculty of Earth Sciences, Department of Geochemistry, Mineralogy and Petrography, University of Silesia, Będzińska 60, 41-200 Sosnowiec, Poland
Lidia Jeżak
Affiliation:
Institute of Geochemistry, Mineralogy and Petrology, Warsaw University, al. Żwirki i Wigury 93, 02-089 Warszawa, Poland
Mikhail Murashko
Affiliation:
Saint Petersburg State University, Faculty of Geology, 7-9 Universitetskaya nab., St. Petersburg, 199034, Russia
*
*E-mail: [email protected]
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Abstract

Dzierżanowskite, , a thiocuprate, was found in larnite pseudoconglomerate rocks of the Hatrurim Complex at Jabel Harmun, Palestinian Autonomy, Israel. Dzierżanowskite occurs in larnite pebbles, which are embedded in a low-temperature mineral matrix. Associated minerals are larnite, brownmillerite, fluorellestadite, ye'elimite, gehlenite, periclase, ternesite, nabimusaite, vorlanite, vapnikite, fluormayenite, fluorkyuygenite, oldhamite, jasmundite, covellite, chalcocite and pyrrhotite. Electron microprobe analyses yield an average composition of Cu 55.25, Fe 0.13, S 27.46 and Ca 16.99, total 99.83 wt.%. The empirical formula of dzierżanowskite, based on 5 atoms, is Ca0.98Cu2.02Fe0.01S1.99. Dzierżanowskite forms grains up to 15 μm in size or rims on oldhamite and laminar intergrowths with chalcocite and covellite. Dzierżanowskite is dark orange, has a cream streak and a submetallic lustre. In reflected light it is grey, with a cream tint and characteristic yellow-orange internal reflections. The calculated density of dzierżanowskite is 4.391 g cm -3. Three bands at 300, 103 and 86 cm -1 are observed in the Raman spectrum. The strongest lines of the calculated powder diffraction pattern are [d, Å (I) hkl]: 2.358(100) 102, 1.970(93)110, 3.023(78) 011, 6.523(36) 001, 3.412 (28) 100, 1.834(28) 103. Dzierżanowskite was also found in unusual jasmundite rocks, forming small ‘paleofumaroles’ within areas of low-temperature hydrothermal rocks bearing larnite pseudoconglomerates at Jabel Harmun. Dzierżanowskite is a superimposed phase of the high-temperature alteration of pyrometamorphic rocks subjected to by-products (melts/fluids and gases) of pyrometamorphism originating in the deeper levels of combustion.

Keywords

dzierżanowskiteCaCu2S2new mineralthiocuprateJabel HarmunHatrurim Complex
Type
Research Article
Information
Mineralogical Magazine , Volume 81 , Issue 5 , October 2017 , pp. 1073 - 1085
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2017

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