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Definitive data on bohdanowiczite, a new silver bismuth selenide

Published online by Cambridge University Press:  05 July 2018

M. Banaś
Affiliation:
Academy of Mining and Metallurgy, Institute of Geology and Mineral Deposits, CracowPoland
D. Atkin
Affiliation:
Geochemical Division, Institute of Geological Sciences, 64/78 Gray's Inn Road, London WC1X 8NG
J. F. W. Bowles
Affiliation:
Geochemical Division, Institute of Geological Sciences, 64/78 Gray's Inn Road, London WC1X 8NG
P. R. Simpson
Affiliation:
Geochemical Division, Institute of Geological Sciences, 64/78 Gray's Inn Road, London WC1X 8NG

Summary

Bohdanowiczite was first described in 1967 but incomplete data prevented its acceptance as a new mineral at that time. Additional data on the same material now characterize bohdanowiczite as a new species with the formula:

3[(Ag0.98Cu0.02)0.97(Bi0.97Pb0.03)1.02(Se0.83S0.17)2.01]

The mineral occurs in intimate intergrowths with clausthalite and wittichenite in polymetallic mineralization at Kletno in Poland. In reflected light bohdanowiczite has a creamy-yellow colour and short polysynthetic twinning is frequently observed. Cell parameters indexed on a hexagonal lattice are a = 4.183±0.008 Å and c = 19.561± 0.016 Å. Pm1 is the most likely space group. The strongest lines of the powder pattern are 2.91(100), 2.03(30), 3.40(20), 6.54(20), 2.09(18), 3.26(18). The calculated density is 7.72 gm/cm3 and the VHN between 63 and 96 kg/mm2.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1979

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References

Banaś, (M.), 1964. Nasturan from the metamorphic complex of Snieżnik Klodzki (Sudetes). Bull. Acad. Pol. Sci. Sér. géol. gbogr. 12, 169-72.Google Scholar
Banaś, (M.) 1965a. Przejawy mineralizacji w metamorfiku Śnież-nika Klodzkiego. (Signs of mineralization in the meta¬morphic complex of Snie∼nik Klodzki-Sudetes Mts.) Prace Geol. 27, 1-83 [M.A. 17-465].Google Scholar
Banaś, (M.) 1965b. New site of Pb, Hg, and Cu selenides in the Sudetes. Bull. Acad. Pol. Sci. Sér. géol. géogr. 13, 267-71.Google Scholar
Banaś, (M.) 1966. Products of oxidation of pitchblende from Kletno. Ibid. 14, 23-6 [M.A. 18-17].Google Scholar
Banaś, (M.) and Ottemann, (J.), 1967. Bohdanowiczyt-nowy naturalny selenek srebra i bizmutu z Kletna w Sudetach. (A new natural silver and bismuth selenide from Kletno in the Sudetes Mts.) Przeglad Geol. No. 5, 240 [M.A. 19-148].Google Scholar
Banaś, (M.) and Ottemann, (J.) 1969. Dalsze losy bohdanowiczytu. (Further fate of bohdanowiczite.) Przeglad Geol. No. 5, 235-8.Google Scholar
Banaś, (M.) and Ottemann, (J.) 1971. Supplementary data on bohdanowiczite, a natural silver-bismuth selenide. Mineral. Polonica. 2, 37-44 [M.A. 73-2940].Google Scholar
Banaś, (M.) 1971. Bohdanowiczite, a new silver and bismuth selenide. Zap. Vses. Min. Obshch. 100, 612-13 [M.A. 72-2328] (in Russian).Google Scholar
Bowles, (J. F. W.), 1975. An automatic data-handling system for quantitative X-ray microprobe analysis. Inst. of Geol. Sc., Lond. Report No. 75/9 [M.A. 76-82].Google Scholar
Geller, (S.) and Wernick, (J. H.), 1959. Ternary semi-conducting compounds with sodium chloride-like structure: AgSbSe2, AgSbTe2, AgBiS2, AgBiSe2 . Acta Crystallogr. 12, 46-54.CrossRefGoogle Scholar
Harris, (D. C.) and Thorpe, (R. I.), 1969. New observations on matildite. Can. Mineral. 9, 655-62 [M.A. 70-I585].Google Scholar
Mason, (P. K.), Frost, (M.), and Reed, (S. J. B.), 1969. BM-IC-NPL computer programs for calculating correc¬tions in quantitative X-ray microanalysis. National Physical Laboratory, I.M.S. Report No. 2.Google Scholar