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The decomposition of konyaite: importance in CO2 fixation in mine tailings

Published online by Cambridge University Press:  05 July 2018

S. J. Mills ,
S. A. Wilson ,
G. M. Dipple  and
M. Raudsepp
S. J. Mills*
Affiliation:
Mineral Deposit Research Unit, Department of Earth and Ocean Sciences, The University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada
S. A. Wilson
Affiliation:
Mineral Deposit Research Unit, Department of Earth and Ocean Sciences, The University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada
G. M. Dipple
Affiliation:
Mineral Deposit Research Unit, Department of Earth and Ocean Sciences, The University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada
M. Raudsepp
Affiliation:
Mineral Deposit Research Unit, Department of Earth and Ocean Sciences, The University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada
*
*E-mail: [email protected]
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Abstract

The sodium-magnesium hydrated double salt konyaite, Na2Mg(SO4)2·5H2O, has been studied by single-crystal X-ray diffraction and thermogravimetry on synthetic samples and by quantitative X-ray diffraction utilizing the Rietveld method on natural samples from the Mount Keith mine, Western Australia. Konyaite crystallizes in space group P21/c, with the cell parameters: a = 5.7594(10), b = 23.914(4), c = 8.0250(13) Å, β = 95.288(9)°, V = 1100.6(3) Å3 and Z = 4. The crystal structure has been refined to R1 = 3.41% for 2155 reflections [Fo>4σ(Fo)] and 6.44% for all 3061 reflections, with all atoms located.

Quantitative phase analysis utilizing the Rietveld method was undertaken on five samples of konyaite-bearing mine tailings from the Mount Keith Nickel Mine, Western Australia. Konyaite was found to decompose over time and after 22 months had transformed to other sulphate and amorphous phases. Blödite did not increase in any ofthe samples indicating that konyaite may not always transform to blödite. Over the same time frame, synthetic konyaite completely decomposed to a mixture of thenardite (Na2SO4), hexahydrite (MgSO4·6H2O), blödite (Na2Mg(SO4)2·4H2O) and löweite (Na12Mg7(SO4)13). Detection of konyaite and other Mg-rich sulphates is important in terms of CO2 fixation. Magnesium bound to sulphate mineral phases reduces the overall potential of tailings piles to lock up atmospheric carbon in Mg carbonates, such as hydromagnesite. Amorphous sulphates are also highly reactive and may contribute to acid mine drainage ifpresent in large quantities, and may dissolve carbonate phases which have already sequestered carbon.

Keywords

konyaitesynthesisdecompositioncrystal structuremine tailingMount KeithRietveld methodcarbon sequestrationdouble saltacid mine drainageMarsAustralia
Type
Research Article
Information
Mineralogical Magazine , Volume 74 , Issue 5 , October 2010 , pp. 903 - 917
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2010

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Footnotes

†

Current address: Department of Geological Sciences, Indiana University, 1001 East 10th St., Bloomington, IN 47405-1405, USA

References

Acero, P., Ayora, C. and Carrera, J. (2007) Coupled thermal, hydraulic and geochemical evolution of pyritic tailings in unsaturated column experiments. Geochimica et Cosmochimica Acta, 71, 5325–5338.CrossRefGoogle Scholar
Agnew, M. and Taylor, G. (2000) Laterally extensive surface hardpans in tailings storage facilities as possible inhibitors of acid rock drainage. Proceedings of the 5th International Conference on Acid Rock Drainage, Society for Mining, Metallurgy, and Exploration, Inc., 1337–1346.Google Scholar
Akao, M. and Iwai, S. (1977) The hydrogen bonding of hydromagnesite. Acta Crystallographica B33, 1273–1275.CrossRefGoogle Scholar
Bales, R.C. and Morgan, J.J. (1985) Dissolution kinetics of chrysotile at pH 7 to 10. Geochimica et Cosmochimica Acta, 49, 2281–2288.CrossRefGoogle Scholar
Batchelder, D.N. and Simmons, R.O. (1964) Lattice constants and thermal expansivities of silicon and of calcium fluoride between 6 and 322 K. Journal of Chemical Physics, 41, 2324–2329.CrossRefGoogle Scholar
BHP Billiton (2005) Mt Keith Nickel Operations: Environmental Data. Retrieved in 2008 from the BHP Billiton Sustainable Development Reports Website:http://hsecreport.bhpbilliton.com/wmc/2004/performance/mko/data/index.htm. Google Scholar
Braithwaite, R.S.W., Dunn, P.I., Pritchard, R.G. and Paar, W.H. (1994) Iowaite, a re-investigation. Mineralogical Magazine, 58, 79–85.CrossRefGoogle Scholar
Brindley, G.W. (1945) The effect of grain or particle size on X-ray reflections from mixed powders and alloys, considered in relation to the quantitative determination of crystalline substances by X-ray methods. Philosophical Magazine, 36, 347–369.Google Scholar
Bruker AXS (2003) SAINT, SADABS and SHELXTL. Bruker AXS Inc., Madison, Wisconsin, USA.Google Scholar
Bruker AXS (2004) Topas V 3.0: General Profile and Structure Analysis Software for Powder Diffraction Data. Bruker AXS, Germany.Google Scholar
Bruker AXS (2008) DIFFRACTplus EVA V 14 Release 2008. Bruker AXS, Germany.Google Scholar
Catti, M., Ferraris, G., Hull, S. and Pavese, A. (1995) Static compression and H disorder in brucite, Mg(OH)2, to 11 GPa: A powder diffraction study. Physics and Chemistry of Minerals, 22, 200–206.CrossRefGoogle Scholar
Cheary, R.W. and Coelho, A.A. (1992) A fundamental parameters approach to X-ray line-profile fitting. Journal of Applied Crystallography, 25, 109–121.CrossRefGoogle Scholar
Chipera, S. and Vaniman, D.T. (2007) Experimental stability of magnesium sulfate hydrates that may be present on Mars. Geochimica et Cosmochimica Acta, 71, 241–250.CrossRefGoogle Scholar
Cole, W.F. and Lancucki, C.J. (1974) Refinement of the crystal structure of gypsum CaSO4 × 2H2O. Acta Crystallographica B30, 921–929.CrossRefGoogle Scholar
Dipple, G.M., Raudsepp, M. and Gordon, T.M. (2002) Assaying wollastonite in skarn. Industrial Minerals in Canada, Canadian Institute of Mining, Metallurgy and Petroleum Special Volume, 53, 303–312.Google Scholar
Dipple, G.M., Wilson, S.A., Barker, S., Thorn, J.M., Raudsepp, M., Power, I., Southam, G. and Fallon, S.J. (2009) Carbon sequestration in ultramafic mine tailings. Proceedings of the 10th Biennial Meeting of the Society for Geology Applied to Mineral Deposits, Townsville, Queensland, Australia, pp. 762–764.Google Scholar
Dollase, W.A. (1986) Correction of intensities for preferred orientation in powder diffractometry: application of the March model. Journal of Applied Crystallography, 19, 267–272.CrossRefGoogle Scholar
Environment Canada (2010) Canadian Climate Normals 1971–2000: Vancouver International Airport. Retrieved in 2010 from the National Climate Data and Information Archieve Website: http://www.cli-mate.weafheroffice.ec.gc.ca/climate_normals/stnselect_e.html. Google Scholar
Feldman, W.C., Prettyman, T.H., Maurice, S., Plaut, J.J., Bish, D.L., Vaniman, D.T., Mellon, M.T., Metzger, A.E., Squyres, S.W., Karunatillake, S., Boynton, W.V., Elphic, R.C., Funsten, H.O., Lawrence, D.J. and Tokar, R.L. (2004) Global distribution of near-surface hydrogen on Mars. Journal of Geophysical Research 109, E09006, doi:10.1029/2003JE002160CrossRefGoogle Scholar
Glinnemann, J., King, H.E. Jr., Schulz, H., Hahn, T., La Placa, S.J. and Dacol, F. (1992) Crystal structures of the low-temperature quartz-type phases of silica and germanium dioxide at elevated pressure. Zeitschrifi für Kristallographie, 198, 177–212.CrossRefGoogle Scholar
Grguric, B.A. (2003) Minerals of the MKD5 nickel deposit, Mount Keith, Western Australia. Australian Journal of Mineralogy, 9, 55–71.Google Scholar
Grguric, B.A., Madsen, I.C. and Pring, A. (2001) Woodallite, a new chromium analogue of iowaite from the Mount Keith nickel deposit, Western Australia. Mineralogical Magazine 65, 427–435.CrossRefGoogle Scholar
Hawthorne, F.C. and Ferguson, R.B. (1975) Anhydrous sulphates I: Refinement of the crystal structure of celestite with an appendix on the structure of thenardite. The Canadian Mineralogist, 13, 181–187.Google Scholar
Hill, R.E.T., Barnes, S.J., Gole, M.J. and Dowling, S.E. (1990) The physical volcanology of komatiites in the Norseman-Wiluna belt. In Third International Archean Symposium, Perth 1990, Excursion Guidebook (Ho, S.E., Glover, J.E., Myers, J.S., and Muhling, J.R., editors). University of Western Australia, pp. 362–397.Google Scholar
Jambor, J.L., Nordstrom, D.K. and Alpers, C.N. (2000) Metal-sulfate salts from sulfide mineral oxidation. Pp. 303–350 in: Sulfate Minerals: Crystallography, Geochemistry, and Environmental Significance (Alpers, C.N., Jambor, J.L. and Nordstrom, D.K., editors). Reviews in Mineralogy & Geochemistry, 40, Mineralogical Society of America, Washington, D.C. Google Scholar
Järvinen, M. (1993) Application of symmetrized harmonics expansion to correction of the preferred orientation effect. Journal of Applied Crystallography, 26, 525–531.CrossRefGoogle Scholar
Keller, L.P., McCarthy, G.J. and Richardson, J.L. (1986) Laboratory modelling of North Great Plains salt efflorescence mineralogy. Soil Science Society of America Journal, 50, 1363–1367.CrossRefGoogle Scholar
Lackner, K.S., Wendt, C.H., Butt, D.P., Joyce, G.L. and Sharp, D.H. (1995) Carbon dioxide disposal in carbonate minerals. Energy, 20, 1153–1170.CrossRefGoogle Scholar
Leduc, E.M.S., Peterson, R.C. and Wang, R. (2009) The crystal structure and hydrogen bonding of synthetic konyaite, Na2Mg(SO4)2.5H2O. American Mineralogist, 94, 1005–1011.CrossRefGoogle Scholar
Madsen, I.C., Grey, I.E. and Mills, S.J. (2010) In situ diffraction studies: Thermal decomposition of a natural plumbojarosite and the development of Rietveld-based data analysis techniques. Materials Science Forum 651, 37–64.CrossRefGoogle Scholar
March, A. (1932) Mathematische theorie der regelung nach der korngestalt bei affmer deformation. Zeitschrift für Kristallographie, 81, 285–297.Google Scholar
Markgraf, S.A. and Reeder, R.J. (1985) High-temperature structure refinements of calcite and magne-site. American Mineralogist, 70, 590–600.Google Scholar
Maslen, E.N., Streltsov, V.A., Streltsova, N.R. and Ishizawa, N. (1995) Electron density and optical anisotropy in rhombohedral carbonates. III. Synchrotron X-ray studies of CaCO3, MgCO3 and MnCO3 . Acta Crystallographica B51, 929–939.CrossRefGoogle Scholar
Mellini, M. and Viti, C. (1994) Crystal structure of lizardite-lT from Elba, Italy. American Mineralogist, 79, 1194–1198.Google Scholar
Mills, S.J., Madsen, I.C., Grey, I.E. and Birch, W.D. (2009) In situ XRD study of the thermal decomposition of natural arsenian plumbojarosite. The Canadian Mineralogist, 47, 683–696.CrossRefGoogle Scholar
Mills, S.J., Whitfield, P.S., Wilson, S.A., Woodhouse, J.A., Dipple, G.M., Raudsepp, M. and Francis, C.A. (2011) The crystal structure of stitchtite, re-examination of barbertonite and the nature of polytypism in MgCr hydrotalcites. American Mineralogist, 96, in press.CrossRefGoogle Scholar
Nickels, J.E., Fineman, M.A. and Wallace, W.E. (1949) X-ray diffraction studies of sodium chloride-sodium bromide solid solutions. Journal of Physical Chemistry, 53, 625–628.CrossRefGoogle ScholarPubMed
Pawley, G.S. (1981) Unit-cell refinement from powder diffraction scans. Journal of Applied Crystallography, 14, 357–361.CrossRefGoogle Scholar
Raudsepp, M. and Pani, E. (2003) Application of Rietveld analysis to environmental mineralogy. Pp. 165–180 in: Environmental Aspects of Mine Wastes (Jambor, J.L., Blowes, D.W. and Ritchie, A.I.M., editors). Mineralogical Association of Canada Short Course Volume 3, Mineralogical Association of Canada.Google Scholar
Raudsepp, M., Pani, E. and Dipple, G.M. (1999) Measuring mineral abundance in skarn. I. The Rietveld method using X-ray powder-diffraction data. The Canadian Mineralogist, 37, 1–15.Google Scholar
Rietveld, H.M. (1969) A profile refinement method for nuclear and magnetic structures. Journal of Applied Crystallography, 2, 65–71.CrossRefGoogle Scholar
Ross, N.X. and Reeder, R.J. (1992) High-pressure structural study of dolomite and ankerite. American Mineralogist, 77, 412–421.Google Scholar
Sheldrick, G.M. (2008) A short history of SHELX . Acta Crystallographica, A64, 112–122.CrossRefGoogle Scholar
Shirozu, H. and Bailey, S.W. (1966) Crystal structure of a two-layer Mg-vermiculite. American Mineralogist, 51, 1124–1143.Google Scholar
Stromberg, B. and Banwart, S. (1994) Kinetic modelling of geochemical processes at the Aitik mining waste rock site in northern Sweden. Applied Geochemistry, 9, 583–595.CrossRefGoogle Scholar
Timpson, M.E., Richardson, J.L., Keller, L.P. and McCarthy, G.J. (1986) Evaporate mineralogy associated with saline seeps in south-western North Dakota. Soil Science Society of America Journal, 50, 490–493.CrossRefGoogle Scholar
Tsukimura, K., Sasaki, S. and Kimizuka, N. (1997) Cation distributions in nickel ferrites. Japanese Journal of Applied Physics, 36, 3609–3612.CrossRefGoogle Scholar
Uehara, S. (1998) TEM and XRD study of antigorite superstructures. The Canadian Mineralogist, 36, 1595–1605.Google Scholar
Valente, T.M. and Gomes, C.L. (2009) Fuzzy modelling of acid mine drainage environments using geochemical, ecological and mineralogical indicators. Environmental Geology, 57, 653–663.CrossRefGoogle Scholar
van Doesburg, J.D.J., Vergouwen, L. and van der Plas, L. (1982) Konyaite, Na2Mg(SO4)2.5H2O, a new mineral from the Great Konya Basin, Turkey. American Mineralogist, 67, 1035–1038.Google Scholar
Vizcayno, C. and Garcia-Gonzalez, M.T. (1999) Na2Mg(SO4)2.4H2O, the Mg end-member of the blodite-type of mineral. Acta Crystallographica C55, 8–11.Google Scholar
Wilson, S.A. (2009) Mineral traps for greenhouse gases in mine tailings: A protocol for verifying and quantifying CO sequestration in ultramafic mines. Unpublished PhD thesis, The University of British Columbia, Vancouver, British Columbia, Canada, 336 pp.Google Scholar
Wilson, S.A., Raudsepp, M. and Dipple, G.M. (2006) Verifying and quantifying carbon fixation in minerals from serpentine-rich mine tailings using Rietveld method with X-ray powder diffraction data. American Mineralogist, 91, 1331–1341.CrossRefGoogle Scholar
Wilson, S.A., Dipple, .M., Power, I.M., Raudsepp, M., Gabites, J.E. and Southam, G. (2009) Carbondioxide fixation within mine tailings at the Clinton Creek and Cassiar chrysotile deposits, Canada. Economic Geology, 104, 95–112.CrossRefGoogle Scholar
Zalkin, A., Ruben, H. and Templeton, D.H. (1964) Crystal structure and hydrogen bonding of magnesium sulfate hexahydrate. Acta Crystallographica B17, 235–240.CrossRefGoogle Scholar