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The crystal structure of julgoldite
Published online by Cambridge University Press: 05 July 2018
Summary
The structure of julgoldite, , has been determined and refined to an R value of 4·6 % based on 2417 symmetry-independent reflections, of which 765 are unobserved (weighted R = 4·3 %). The cell dimensions are a 8·922(4), b 6·081(3), c 19·432(9) Å, β 97·60(6)°, the space group is A2/m with Z = 4 and Dcalc 3·56 g cm-3. Julgoldite is isostructural with pumpellyite; the Si-O and Ca-O distances of julgoldite are identical, within experimental accuracy, with corresponding distances in pumpellyite; the Fe-O distances of julgoldite are about 0·09 Å longer than the corresponding (Al, Mg)-O distances in pumpellyite. The four hydroxyl groups and the extent of O-for-OH substitution are identified by valence-sum calculations.
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- Copyright © The Mineralogical Society of Great Britain and Ireland 1973
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