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Cr-pyrope xenocrysts with oxide mineral inclusions from the Chompolo lamprophyres (Aldan shield): Insights into mantle processes beneath the southeastern Siberian craton

Published online by Cambridge University Press:  12 January 2022

Dmitriy I. Rezvukhin Open the ORCID record for Dmitriy I. Rezvukhin [Opens in a new window] ,
Evgeny I. Nikolenko Open the ORCID record for Evgeny I. Nikolenko [Opens in a new window] ,
Igor S. Sharygin Open the ORCID record for Igor S. Sharygin [Opens in a new window] ,
Olga V. Rezvukhina Open the ORCID record for Olga V. Rezvukhina [Opens in a new window] ,
Maria V. Chervyakovskaya Open the ORCID record for Maria V. Chervyakovskaya [Opens in a new window]  and
Andrey V. Korsakov Open the ORCID record for Andrey V. Korsakov [Opens in a new window]
Dmitriy I. Rezvukhin*
Affiliation:
Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk630090, Russia
Evgeny I. Nikolenko
Affiliation:
ALROSA (ZIMBABWE) Ltd., 19 Van Praagh Avenue, Milton Park, Harare, Zimbabwe
Igor S. Sharygin
Affiliation:
Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk630090, Russia Institute of the Earth's Crust, Siberian Branch of the Russian Academy of Sciences, Irkutsk664033, Russia
Olga V. Rezvukhina
Affiliation:
Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk630090, Russia
Maria V. Chervyakovskaya
Affiliation:
Zavaritsky Institute of Geology and Geochemistry UB RAS, Yekaterinburg, 620016, Russia
Andrey V. Korsakov
Affiliation:
Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk630090, Russia
*
*Author for correspondence: Dmitriy I. Rezvukhin, Email: [email protected], [email protected]
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Abstract

Pyrope xenocrysts (N = 52) with associated inclusions of Ti- and/or Cr-rich oxide minerals from the Aldanskaya dyke and Ogonek diatreme (Chompolo field, southeastern Siberian craton) have been investigated. The majority of xenocrysts are of lherzolitic paragenesis and have concave-upwards (normal) rare earth element (REEN) patterns that increase in concentration from light REE to medium–heavy REE (Group 1). Four Ca-rich (5.7–7.4 wt.% CaO) pyropes are extremely low in Ti, Na and Y and have sinusoidal REEN spectra, thus exhibiting distinct geochemical signatures (Group 2). A peculiar xenocryst, s165, is the only sample to show harzburgitic derivation, whilst demonstrating a normal-to-weakly sinusoidal REEN pattern and the highest Zr (93 ppm) and Sc (471 ppm). Chromite–magnesiochromite, rutile, Mg-ilmenite and crichtonite-group minerals comprise a suite of oxide mineral inclusions in the pyrope xenocrysts. These minerals are characteristically enriched in Cr with 0.6–7.2 wt.% Cr2O3 in rutile, 0.7–3.6 wt.% in Mg-ilmenite and 7.1–18.0 wt.% in the crichtonite-group minerals. Complex titanates of the crichtonite group enriched in large ion lithophile elements (LILE) are high in Al2O3 (0.9–2.2 wt.%), ZrO2 (1.5–5.4 wt.%) and display a trend of compositions from the Ca–Sr-specific varieties to the Ba-dominant species (e.g. lindsleyite). In the pyrope xenocrysts the oxides coexist with silicates (clino- and orthopyroxene and olivine), hydrous silicates (talc, phlogopite and amphibole), carbonate (magnesite), sulfides (pentlandite, chalcopyrite, breakdown products of monosulfide and bornite solid solutions), apatite and graphite. P–T estimates imply the inclusion-bearing pyrope xenocrysts have been derived from low-temperature peridotite assemblages that resided at temperatures of ~600–800°C and a pressure range of ~25–35 kbar in the graphite stability field. Pyrope genesis is linked to the metasomatic enrichment of peridotite protoliths by Ca–Zr–LILE-bearing percolating fluid–melt phases containing significant volatile components. These metasomatic agents are probably volatile-rich melts or supercritical C–O–H–S fluids that were released from a Palaeo-subduction slab.

Keywords

pyropeinclusioncrichtonite-group mineralsmantle metasomatismChompolo fieldAldan shield
Type
Article
Information
Mineralogical Magazine , Volume 86 , Issue 1 , February 2022 , pp. 60 - 77
Copyright
Copyright © The Author(s), 2022. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Makoto Arima

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