Hostname: page-component-cd9895bd7-lnqnp Total loading time: 0 Render date: 2024-12-24T18:33:13.712Z Has data issue: false hasContentIssue false
  • English
  • Français

The catalysis of mineral reactions by water and restrictions on the presence of aqueous fluid during metamorphism

Published online by Cambridge University Press:  05 July 2018

David C. Rubie
David C. Rubie*
Affiliation:
Department of Geology, The University of Manchester, Manchester M13 9PL, UK
Get access Rights & Permissions [Opens in a new window]

Abstract

The problems of characterizing inter-granular regions and of estimating rates of intergranular diffusion in metamorphic rocks are discussed. Inter-granular regions can be anhydrous, hydrated but under-saturated with H2O, or saturated with H2O, but only in the latter case can a free aqueous fluid phase be present. Estimates of intergranular diffusion coefficients (DIGR) at 550°C derived from a variety of published experimental work, vary from ∼ 10−8 m2 s−1 for diffusion of species through an intergranular fluid film to ⩽ 4 × 10−24 m2 s−1 for diffusion of SiO2 or O in anhydrous grain boundaries in quartzite. Estimates of DIGR for hydrated grain boundaries vary from ∼ 10−13 m2 s−1 to ∼ 10−21 m2 s−1; the concentration of H2O in the grain boundaries and the identity of the diffusing species (generally unknown) may be important controlling factors, and there exists the possibility of a spectrum of values between these two extremes.

Using available kinetic data it is shown that a free aqueous fluid could never have been present in parts of the basement terrane of the Sesia Zone (Western Alps) during uplift from the eclogite facies, except possibly late in the cooling history. The breakdown of sodic pyroxene + quartz occurred in response to the localized infiltration of catalytic aqueous fluid, possibly over a time interval as short as 6–6000 a, and possibly under conditions remote from equilibrium. H2O-present conditions during a dehydration reaction in metapelites of the Adula nappe (central Alps) could also have been of short duration. These examples are consistent with a model in which basement rocks at deep crustal levels are dry for long periods of time and in which the development of equilibrium mineral assemblages and microstructures generally occurs over relatively short periods of time under transitory fluid-present conditions (caused by devolatilization and/or infiltration).

Keywords

metamorphismdiffusionintergranular diffusionaqueous fluid
Type
Rates of Metamorphic Reactions
Information
Mineralogical Magazine , Volume 50 , Issue 357 , September 1986 , pp. 399 - 415
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1986

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Ahrens, T.J., and Schubert, G. (1975) Rev. Geophys. Space Phys. 13, 383-400.CrossRefGoogle Scholar
Beach, A. (1982) J. Struct. Geol. 4, 137-49.CrossRefGoogle Scholar
Blacic, J.D., and Christie, J.M. (1984) J. Geophys. Res. 89, 4223-39.CrossRefGoogle Scholar
Boullier, A.M., and Gueguen, Y. (1975) Contrib. Mineral. Petrol. 50, 93-104.CrossRefGoogle Scholar
Brace, W.F., and Walsh, J.B. (1962) Am. Mineral. 47, 1111-22.Google Scholar
Brady, J.B. (1983) Am. J. Sci.283-A, 181–200.Google Scholar
Brearley, A.J. (1984) Petrological and Electron Optical Studies of Metamorphic Reactions.Ph.D. thesis, Univ. of Manchester.Google Scholar
Brindley, G.W., and Hayami, R. (1965) Phil. Mag. 12, 505-14.CrossRefGoogle Scholar
Brown, W.H. Fyfe, W.S., and Turner, F.J. (1962) J. Petrol. 3, 566-82.CrossRefGoogle Scholar
Burte, A.S., and Nicholson, P.S. (1972) J. Am. Ceram. Soc.55, 469-72.CrossRefGoogle Scholar
Carlson, W.D., and Rosenfeld, J.D. (1981) J. Geol. 89, 615-38.CrossRefGoogle Scholar
Churayev, N.V. (1970) Spec. Discuss. Faraday Soc. 1, 259-61.CrossRefGoogle Scholar
Sobolev, V.D., and Zorin, Z.M. (1970) Ibid. 1, 213-20.Google Scholar
Compagnoni, R. (1977) Rend. Soc. ltd. Mineral. Petro. 33, 335-74.Google Scholar
Compagnoni, R. and Maffeo, B. (1973) Schweiz. Mineral. Petrogr. Mitt. 53, 355-78.Google Scholar
Dal Piaz, G.V., Hunziker, J.C. Gosso, G., Lombardo, B., and Williams, P.F. (1977) Rend. Soc. ltd. Mineral. Petrol. 33, 281-334.Google Scholar
Davies, J.T., and Rideal, E.K. (1963) Interfacial Phenomen. Academic Press, New York.Google Scholar
Elton, G.A.H. (1948) Proc. R. Soc. Ser. A. 194, 259-74.Google Scholar
Etheridge, M.A., Wall, V.J., and Vernon, R.H. (1983) J. Metamorphic Geol. 1, 205-26.CrossRefGoogle Scholar
Cox, S.F., and Vernon, R.H. (1984). J. Geophys. Res. 89, 4344-58.Google Scholar
Ferry, J.M. (1983) J. Geol. Soc. Lond. 140, 551-76.CrossRefGoogle Scholar
Ferry, J.M. (1984) J. Petrol. 25, 871-93.CrossRefGoogle Scholar
Fisher, G.W. (1978) Geochim. Cosmochim. Ada. 42, 1035-50.CrossRefGoogle Scholar
Fletcher, R.C. and Hofmann, A.W. (1974) In Geochemical Transport and Kinetics(A. W. Hofmann B.J. Giletti H.S. Yoder, and R. A. Yund., eds.). Carnegie Institute, Washington, 243-59.Google Scholar
Frueh-Green, G. (1985) Trans. Am. Geophys. Union. 66, 1126-7.Google Scholar
Frueh-Green, G. and Thompson, A.B. (1985) Terra Cognita. 5, 336.Google Scholar
Fyfe, W.S., Turner, F.J., and Verhoogen, J. (1958) Metamorphic reactions and metamorphic fades,Geol. Soc. Am. Mem. 73.Google Scholar
Price, N.J., and Thompson, A.B. (1978) Fluids in the Earth's Crus. Elsevier, Amsterdam.Google Scholar
Gifkins, R.C. (1976) Met. Tran. 7A, 1225-32.CrossRefGoogle Scholar
Giletti, B.J., and Nagy, K.L. (1981) Trans. Am. Geophys. Union. 62, 428.Google Scholar
Giletti, B.J., and Nagy, K.L. and Yund, R.A. (1984) J. Geophys. Res. 89, 4039-46.CrossRefGoogle Scholar
Graham, C.M., Greig, K.M., Sheppard, S.M.F., and Turi, B. (1983) J. Geol. Soc. Lond. 140, 577-99.CrossRefGoogle Scholar
Heinrich, C.A. (1982) Contrib. Mineral. Petrol. 81, 30-8..CrossRefGoogle Scholar
Heinrich, C.A. (1986) J. Petrol. 27, 123-54.CrossRefGoogle Scholar
Helgeson, H.C. and Kirkham, D.H. (1974) Am. J. Sc. 274, 1089-198.CrossRefGoogle Scholar
Hoernes, S., and Friedrichsen, H. (1978) Contrib. Mineral. Petrol. 67, 305-15.CrossRefGoogle Scholar
Holland, T.J.B., and Powell, R. (In press) J. Metamorphic Geol. Google Scholar
Ildefonse, J.P., and Gabis, V. (1976) Geochim. Cosmochim. Ada. 40, 297-303.CrossRefGoogle Scholar
Joesten, R. (1983) Am. J. Sci. 283-A, 233-54.Google Scholar
Joesten, R. (1985) J. Am. Ceram. So. 68, C–62-C–64.Google Scholar
Koons, P.O. (1982) An Investigation of Experimental and Natural High-Pressure Assemblages from the Sesia Zone, Western Alps, Ital. Dr. Sc. Nat. Thesis, ETH, Zurich.Google Scholar
Koons, P.O. and Rubie, D.C. (1983) Terra Cognita. 3, 186.Google Scholar
Rubie, D.C. and Frueh-Green, G. (in press) Submitted to J. Petrol. Google Scholar
Kridelbaugh, S.J. (1973) Am. J. Sci. 273, 757-77.CrossRefGoogle Scholar
Lardeaux, J.M., Gosso, G., Kienast, J.R., and Lombardo, B. (1982) Bull. Soc. Geol. France. 24, 793-800.CrossRefGoogle Scholar
Laubscher, H.P., and Bernoulli, D. (1980). In Geology of Switzerland, A Guide Book, Part B: Geological Excursion. Wepf, Basel, 183–209.Google Scholar
Lenz, J.G., Nicholson, P.S., and Smeltzer, W.W. (1977) J. Am. Ceram. Soc. 60, 370-1.CrossRefGoogle Scholar
Levine, S., Marriott, J.R., and Robinson, K. (1975a) J. Chem. Soc. Faraday Trans. II. 71, 1-11.CrossRefGoogle Scholar
Neale, G., and Epstein, N. (1975b) J. Colloid Interface Sci. 52, 136-49.Google Scholar
Lidstrom, L. (1968) Ada Polytechn. Scand.(Chem. Ser.), 75.Google Scholar
Lombardo, B., Compagnoni, R., Fiora, L., and Facchinelli, A. (1977) Rend. Soc. Ital. Mineral. Petrol. 33, 375-87.Google Scholar
Loomis, T.P. (1979) J. Petrol. 20, 271-92.CrossRefGoogle Scholar
McGregor, R. (1974) Diffusion and Sorption in Fibers and Film. Academic Press, New York.Google Scholar
Martin, J.W., and Doherty, R.D. (1976) Stability of Microstrudure in Metallic System. Cambridge University Press, Cambridge.Google Scholar
Matthews, A. (1980) Geochim. Cosmochim. Ada. 44, 387-402.CrossRefGoogle Scholar
Moore, W.J. (1972) Physical Chemistr. Prentice-Hall, New Jersey.Google Scholar
Norris, R.J., and Henley, R.W. (1976) Geology. 4, 333-6.Google Scholar
Oberhaensli, R., Hunziker, J.C. Martinotti, G., and Stem, W.B. (1985) Chem. Geol. 52, 165-84.Google Scholar
Olivares, W., Croxton, T.L., and McQuarrie, D.A. (1980) J. Phys. Chem. 84, 867-9.CrossRefGoogle Scholar
Peterson, N.L. (1983) Int. Metals Rev. 28, 65-91.Google Scholar
Rice, C.L., and Whitehead, R. (1965) J. Phys. Chem. 69, 4017-24.CrossRefGoogle Scholar
Ricoult, D.L., and Kohlstedt, D.L. (1983) Phys. Chem. Minerals. 9, 133-8.CrossRefGoogle Scholar
Robie, R.A., Hemingway, B.S., and Fisher, J.R. (1978) U.S. Geol. Surv. Bull. 1452, 456.pp.Google Scholar
Rubie, D.C. (1983) Tectonophys.96, 331-52.CrossRefGoogle Scholar
Rubie, D.C.(1984) J. Geol. 92, 21-36.CrossRefGoogle Scholar
Rubie, D.C. (1985) Mineral. Soc. Bull. 66, 2.Google Scholar
Rubie, D.C. and Thompson, A.B. (1985) In Advances in Physical Geochemistry,4 (A. B. Thompson and D. C. Rubie, eds.). Springer-Verlag, New York, 27-79.Google Scholar
Rubie, D.C. and Thompson, A.B. (1986) In Kinetics and Mass Transport of Silicate and Oxide System.(R. Freer and P. F. Dennis, eds.). Mat. Sci. Forum7. Trans. Tech., Switzerland, 155-62.Google Scholar
Rumble, D., Ferry, J.M., Hoering, T.C. and Boucot, A.J. (1982) Am. J. Sci. 282, 886-919.CrossRefGoogle Scholar
Rutter, E.H. (1976) Phil. Trans. R. Soc. Lond. 4283, 203-19.Google Scholar
Rutter, E.H. and Brodie, K.H. (1985) In Advances in Physical Geochemistr. 4 (A. B. Thompson and D. C. Rubie, eds.). Springer-Verlag, New York, 242-50.Google Scholar
Schramke, J.A., Kerrick, D.M., and Lasaga, A.C. (In press) Am. J. Sci. Google Scholar
Smoluchowski, M.V. (1918) Z. Phys. Chem. 92, 129-68.Google Scholar
Tanner, S.B., Kerrick, D.M., and Lasaga, A.C. (1985) Am. J. Sci. 285, 577-620.CrossRefGoogle Scholar
Thompson, A.B. (1983) J. Geol. Soc. Lond.140, 533-47.CrossRefGoogle Scholar
Thompson, J.B. (1955) Am. J. Sci. 253, 65-103.CrossRefGoogle Scholar
Tracy, R.J., and McLellan, E.L. (1985) In Advances in Physical Geochemistr. 4 (A. B. Thompson and D. C. Rubie, eds.). Springer-Verlag, New York, 118-37.Google Scholar
Tullis, J., and Yund, R.A. (1982) J. Geo. 90, 301-18.Google Scholar
Turner, F.J. (1981) Metamorphic Petrolog. McGraw- Hill, New York.Google Scholar
Vaughan, P.J., and Coe, R.S. (1981) J. Geophys. Res. 86, 389-404.CrossRefGoogle Scholar
Vernon, R.H. (1976) Metamorphic Processe. Allen and Unwin, London.Google Scholar
Walther, J.V., and Orville, P.M. (1982) Contrib. Mineral Petrol. 79, 252-7.CrossRefGoogle Scholar
Walther, J.V., and Orville, P.M. and Wood, B.J. (1984) Ibid. 88, 246-59.Google Scholar
White, J.C. and White, S.H. (1981) Tectonophysics. 78, 613-28.CrossRefGoogle Scholar
Wood, B.J., and Walther, J.V. (1983) Science. 222, 413-15.CrossRefGoogle Scholar
Yardley, B.W.D. (1983) J. Geol Soc. Lond. 140, 657-63.CrossRefGoogle Scholar
Yardley, B.W.D. and Baltatzis, E. (1985) Contrib. Mineral Petrol. 89, 59-68.CrossRefGoogle Scholar
Yund, R.A., and Tullis, J. (1980) Ibid. 72, 297-302.Google Scholar