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Carbonate-carbonate immiscibility, neighborite and potassium iron sulphide in Oldoinyo Lengai natrocarbonatite

Published online by Cambridge University Press:  05 July 2018

Roger H. Mitchell
Roger H. Mitchell*
Affiliation:
Department of Geology, Lakehead University, Thunder Bay, Ontario, Canada P7B 5El
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Abstract

Porphyritic natrocarbonatite lavas erupted from the Oldoinyo Lengai volcano (Tanzania) on 17 October 1995 and 15–19 December 1995 differ from previously studied lavas in that they preserve textures indicative of groundmass carbonate-carbonate immiscibility. The immiscible fractions are considered to involve: a Na-K-Ca-CO2-Cl-rich, F-bearing fluid crystallizing gregoryite, sodian sylvite, potassium neighborite as well as a complex Ba-rich carbonate; and a Na-rich, Cl-poor carbonate liquid approximating to a nyerereite-gregoryite cotectic composition. Compositional data are given for potassium neighborite, this mineral being the first recognized occurrence of a fluorine-based perovskite group mineral in a magmatic environment. New compositional data are also given for a previously recognized potassium iron sulphide which indicate that this phase is probably a solid solution between the ternary sulphides, KFe3S4, K2Fe3S4, and KFe2S3. Textural and paragenetic data are interpreted to suggest that these recent lavas are more evolved than previously investigated Oldoinyo Lengai lavas and that natrocarbonatite is a highly evolved rather than a primitive magma.

Keywords

carbonatiteliquid immiscibilityneighboritepotassium iron sulphidesylviteOldoinyo LengaiTanzania
Type
Petrology
Information
Mineralogical Magazine , Volume 61 , Issue 409 , December 1997 , pp. 779 - 789
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1997

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