Hostname: page-component-cd9895bd7-7cvxr Total loading time: 0 Render date: 2024-12-18T10:40:35.750Z Has data issue: false hasContentIssue false

Thermal decomposition of Li8(Al6Si6O24)Cl2

Published online by Cambridge University Press:  05 July 2018

D. Taylor*
Affiliation:
Fairey Tecramics Limited, Filleybrooks, Stone, Staffordshire, ST15 OPU

Abstract

Li8(Al6Si6O24)Cl2, a synthetic member of the sodalite family (Henderson and Taylor, 1977), was prepared by heating natural sodalite, Na8(Al- 6Si6O24)Cl2 (from Låven, Norway), in molten LiC1 at 800 °C for 2h, washing uncombined LiC1 from the product and drying at 110 °C Chemical analyses of the natural sodalite and the Li-sodalite are given in Table 1. The cell edge of the Lisodalite was 8.4476(9) Å (Si as internal standard: a = 5.43065/Å at 25 °C in good agreement with literature values (Henderson and Taylor, 1977).

Type
Short Communications
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1989

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Henderson, C. M. B., and Taylor, D. (1977) Acta Spectrochim. Acta, 33A, 283-90.Google Scholar
Henderson, C. M. B., and Taylor, D. (1978) Phys. Chem. Minerals, 2, 337-47.CrossRefGoogle Scholar
Murthy, M. K., and Hummel, F. A. (1954) J. Am. Ceram. Soc. 37, 14-7.CrossRefGoogle Scholar
Pillars, W. W., and Peacor, D. R. (1973) Am. Mineral. 58, 681-90.Google Scholar
Schipper, D. J., Lathouwers, T. W., and van Doorn, C. Z. (1973) J. Am. Ceram. Soc. 56, 523-5.CrossRefGoogle Scholar
Schultz, H. (1974) Ibid. 57, 313-8.Google Scholar
Wellman, T. R. (1969) Geochim. Cosmochim. Acta, 33, 1302-4.CrossRefGoogle Scholar