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Temperature- and moisture-dependent powder X-ray diffraction studies of kanemite (NaSi2O4(OH)·3H2O)

Published online by Cambridge University Press:  02 January 2018

Daniela Schmidmair ,
Volker Kahlenberg ,
Daniel M. Többens ,
Herwig Schottenberger ,
Jochem De Wit  and
Ulrich J. Griesser
Daniela Schmidmair
Affiliation:
Institute of Mineralogy and Petrography, University of Innsbruck, Innrain 52, A-6020 Innsbruck, Austria
Volker Kahlenberg*
Affiliation:
Institute of Mineralogy and Petrography, University of Innsbruck, Innrain 52, A-6020 Innsbruck, Austria
Daniel M. Többens
Affiliation:
Helmholtz-Zentrum Berlin für Materialien und Energie, Department of Crystallography, Hahn-Meitner-Platz 1, D-14109 Berlin, Germany
Herwig Schottenberger
Affiliation:
Institute of General, Inorganic and Theoretical Chemistry, University of Innsbruck, Center for Chemistry and Biomedicine, Innrain 80-82, A-6020 Innsbruck
Jochem De Wit
Affiliation:
Institute of Pharmacy, Pharmaceutical Technology, University of Innsbruck, Innrain 52c, A-6020 Innsbruck, Austria
Ulrich J. Griesser
Affiliation:
Institute of Pharmacy, Pharmaceutical Technology, University of Innsbruck, Innrain 52c, A-6020 Innsbruck, Austria
*
*E-mail: [email protected]
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Abstract

The high-temperature- and moisture-dependent behaviour of synthetic kanemite (NaSi2O4(OH)·3H2O or SKS-10) has been studied by in situ powder X-ray diffraction. Heating experiments in the range between ambient temperatures and 250°C confirm earlier investigations that the dehydration of kanemite occurs in two steps. According to our results the two different reactions start at ∼30 and 75°C. The dehydration products have the following compositions: NaSi2O4(OH)·H2O (monohydrate) and NaSi2O4(OH), respectively. The crystal structures of both phases have been solved at ambient conditions ab initio from laboratory powder diffraction data using samples that have been carefully dehydrated at 60 and 150°C, respectively, and refined subsequently by the Rietveld method. Basic crystallographic data are as follows: NaSi2O4(OH)·H2O: orthorhombic, space group Pna21, a = 7.2019(1), b = 15.3252(2), c = 4.8869(1) Å, V = 539.37(1) Å3, Z = 4; NaSi2O4(OH): monoclinic, space group P21, a = 6.3873(1), b = 4.8876(1), c = 7.1936(1) Å, β = 93.36(1)°, V = 224.19(1) Å3, Z = 2. Both compounds belong to the group of single-layer silicates based on Si2O4 (OH) sheets. The sodium cations are located between the tetrahedral sheets and are surrounded by oxygen atoms from silicate anions and/or water molecules. Depending on the dehydration step the coordination numbers of the alkali ions vary between six (kanemite) and five (NaSi2O4(OH)). Kanemite and its two dehydration products show structural similarities which are discussed in detail. Moisture-dependent diffraction studies at ambient temperatures indicate that kanemite is stable between 10% and at least 90% relative humidity. Below the lower threshold a transformation to the monohydrate phase was observed. Dehydration and rehydration as a function of humidity is reversible. However, this process is combined with a significant loss of crystallinity of the samples.

Keywords

kanemiteNaSi2O4(OH)·3H2O, NaSi2O4(OH)·H2O, NaSi2O4(OH)dehydrationmoisture dependencypowder X-ray diffraction
Type
Research Article
Information
Mineralogical Magazine , Volume 79 , Issue 1 , February 2015 , pp. 103 - 120
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2015

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