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Microwave techniques for the synthesis and deuteration of minerals, with particular reference to scorodite, FeAsO4.2H2O

Published online by Cambridge University Press:  05 July 2018

David R. Baghurst ,
Jack Barrett ,
Esther E. Coleyshaw ,
William P. Griffith  and
D. Michael P. Mingos
David R. Baghurst
Affiliation:
Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, UK
Jack Barrett
Affiliation:
Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, UK
Esther E. Coleyshaw
Affiliation:
Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, UK
William P. Griffith
Affiliation:
Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, UK
D. Michael P. Mingos
Affiliation:
Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, UK
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Abstract

Microwave dielectric heating methods for the preparation of a number of arsenate, phosphate, vanadate, molybdate and carbonate minerals and their deuterated analogues are reported; rapid and efficient syntheses of these have been achieved. The application of this to the study of vibrational spectroscopy of minerals is discussed, with particular reference to scorodite.

Keywords

microwave techniquessynthesisdeuterationscorodite
Type
Mineralogy
Information
Mineralogical Magazine , Volume 60 , Issue 402 , October 1996 , pp. 821 - 828
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1996

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Author to whom reprint requests should be addressed

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