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A hibonite-spinel-corundum-hematite assemblage in plagioclase-clinopyroxene pyrometamorphic rocks, Hatrurim Basin, Israel: mineral chemistry, genesis and formation temperatures

Published online by Cambridge University Press:  02 July 2018

Victor V. Sharygin
Victor V. Sharygin*
Affiliation:
Institute of Geology and Mineralogy SB RAS, pr. Koptyuga 3, Novosibirsk, 630090, Russia; and Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia; and Institute of Physics and Technology, Ural Federal University, ul. Mira 19, Ekaterinburg, 620002, Russia
*
Author for correspondence: Victor V. Sharygin, E-mail: [email protected]
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Abstract

The intergrowths of Fe-rich corundum + Al-rich hematite + spinel + hibonite have been found as an assemblage in a plagioclase-clinopyroxene rock (paralava, former hornfels) at the Hatrurim Basin, Hatrurim combustion metamorphic Formation. Most spinels show oriented exsolution structures and vary from (Mg0.75${\rm Fe}_{{\rm 0}{\rm. 25}}^{2 +} $)(Al1.80${\rm Fe}_{{\rm 0}{\rm. 20}}^{3 +} $)O4 (with exsolutions) to (Mg0.77${\rm Fe}_{{\rm 0}{\rm. 23}}^{2 +} $)(Al1.95${\rm Fe}_{{\rm 0}{\rm. 05}}^{3 +} $)O4 (homogeneous) indicating a tendency towards magnesioferrite and magnetite, and enrichment in NiO (up to 1.9 wt.%) and ZnO (up to 1.4 wt.%). Hibonite is Ti rich (TiO2 > 8 wt.%) and close to CaAl9Fe3+(Mg,Fe2+)TiO19. Corundum varies in Fe2O3 (4.2–11.8 wt.%). Hematite is also inhomogeneous and contains oriented exsolution structures of corundum. It shows variable concentrations of TiO2 (0.7–5.6 wt.%), Al2O3 (0.7–8.6 wt.%), Cr2O3 (0.2–1.5 wt.%), V2O3 (0.1–1.0 wt.%) and MgO (0.3–2.0 wt.%). Crystallization of this specific assemblage is assumed to be at 1000–1200°C using evaluations for the corundum hematite pair with reference to published experimental data. The active role of superheated oxidised volatiles is suggested during both crystallisation of this corundum-bearing association and host-rock transformation (melting event for hornfels → paralava).

Keywords

corundumhematitehiboniteparalavahornfelscorundum-hematite geothermometercombustion metamorphismHatrurim BasinIsrael
Type
Article
Information
Mineralogical Magazine , Volume 83 , Issue 1 , February 2019 , pp. 123 - 135
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

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Footnotes

Associate Editor: Craig Storey

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