Hostname: page-component-586b7cd67f-dlnhk Total loading time: 0 Render date: 2024-11-27T20:20:29.172Z Has data issue: false hasContentIssue false
  • English
  • Français

Ethanol adsorption on the {104} calcite surface: preliminary observations with atomic force microscopy

Published online by Cambridge University Press:  05 July 2018

K. K. Sand ,
S. L. S. Stipp ,
T. Hassenkam ,
M. Yang ,
D. Cooke  and
E. Makovicky
K. K. Sand*
Affiliation:
Nano-Science Center, Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark
S. L. S. Stipp
Affiliation:
Nano-Science Center, Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark
T. Hassenkam
Affiliation:
Nano-Science Center, Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark
M. Yang
Affiliation:
Nano-Science Center, Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark
D. Cooke
Affiliation:
University of Huddersfield, Queensgate, Huddersfield, HD1 3DH, UK
E. Makovicky
Affiliation:
Department of Geography and Geology, University of Copenhagen, Øster Voldgade 10, DK-1350 Copenhagen, Denmark
*
*E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

Preliminary atomic force microscopy investigations of the {104} calcite surface cleaved in ethanol indicate a different surface behaviour than that of the {104} surface cleaved in air. The results are consistent with recent theoretical studies and suggest strong ordering of ethanol over the termination of the bulk calcite structure.

Type
Research Article
Information
Mineralogical Magazine , Volume 72 , Issue 1 , February 2008 , pp. 353 - 357
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2008

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bohr, J., Stipp, S.L.S., Morris, P.M. and Wogelius, R.A. Structure and density of the water layer formed from vapour on calcite surfaces, Geochimica et Cosmochimica Ada, (accepted).Google Scholar
Henriksen, K. and Stipp, S.L.S. (2002) Image distortion in scanning probe microscopy. American Mineralogist, 87, 5–16.CrossRefGoogle Scholar
Henriksen, K., Stipp, S.L.S., Young, J.R. and Marsh, M.E. (2004) Biological control on calcite crystallization: AFM investigation of coccolith polysac-charide function. American Mineralogist, 89, 1709–1716.CrossRefGoogle Scholar
Reeder, RJ. (1996) Interaction of divalent cobalt, zinc, cadmium, and barium with the calcite surface during layer growth. Geochimica et Cosmochimica Ada, 60, 1543–1552.CrossRefGoogle Scholar
Stipp, S.L. and Hochella, M.F. (1991) Structure and bonding environments at the calcite surface as observed with X-ray photoelectron-spectroscopy (XPS) and low-energy electron-diffraction (LEED). Geochimica et Cosmochimica Ada, 55, 1723–1736.CrossRefGoogle Scholar
Stipp, S.L.S., Eggleston, C.M. and Nielsen, B.S. (1994) Calcite surface-structure observed at microtopographic and molecular scales with atomic-force microscopy (AFM). Geochimica et Cosmochimica Acta, 58, 3023–3033.CrossRefGoogle Scholar
Stipp, S.L.S., Gutmannsbauer, W. and Lehmann, T. (1996) The dynamic nature of calcite surfaces in air. American Mineralogist, 81, 1–8.CrossRefGoogle Scholar