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Cuyaite, Ca2Mn3+As3+14O24Cl, a new mineral with an arsenite framework from near Cuya, Camarones Valley, Chile.

Published online by Cambridge University Press:  27 April 2020

Anthony R. Kampf Open the ORCID record for Anthony R. Kampf [Opens in a new window] ,
Stuart J. Mills ,
Barbara Nash ,
Maurizio Dini  and
Arturo A. Molina Donoso
Anthony R. Kampf*
Affiliation:
Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Blvd., Los Angeles, CA90007, USA
Stuart J. Mills
Affiliation:
Geosciences, Museums Victoria, GPO Box 666, Melbourne 3001, Victoria, Australia
Barbara Nash
Affiliation:
Department of Geology and Geophysics, University of Utah, Salt Lake City, Utah84112, USA
Maurizio Dini
Affiliation:
Pasaje San Agustin 4045, La Serena, Chile
Arturo A. Molina Donoso
Affiliation:
Los Algarrobos 2986, Iquique, Chile
*
*Author for correspondence: Anthony R. Kampf, Email: [email protected]
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Abstract

Cuyaite (IMA2019-126), Ca2Mn3+As3+14O24Cl, is a new arsenite mineral from near Cuya in the Camarones Valley, Arica Province, Chile. It is associated with anhydrite, native arsenic, arsenolite, calcite, claudetite, ferrinatrite, gajardoite-3R, leiteite, magnesiocopiapite, phosphosiderite, pyrite, realgar and talmessite and formed from the oxidation of As-bearing primary phases and alteration by saline fluids derived from evaporating meteoric water under hyperarid conditions. Cuyaite occurs as pale brown thin needles (elongated on [010]), typically in divergent sprays and subparallel intergrowths. The streak is white. Crystals are transparent with adamantine lustre; subparallel intergrowths exhibit silky lustre. The mineral has Mohs hardness of 2½, is brittle, exhibits no cleavage and has irregular fracture. The calculated density is 4.140 g cm–3. Cuyaite is optically biaxial (–), with α = 1.87(1), β = 1.956(calc) and γ = 1.98(1), determined in white light; 2Vmeas = 60(1)°; and orientation: X = b and Y ^ a = 53° in obtuse β. Electron microprobe analyses provided the empirical formula Ca2.03Mn3+0.95(As3+13.66Sb3+0.65)Σ14.31O24Cl0.88. The six strongest powder X-ray diffraction lines are [dobs Å(I)(hkl)]: 4.73(45)(111, $\bar{1}$12), 3.162(100)($\bar{3}$14), 3.035(28)(213), 3.004(37)(204), 2.931(90)($\bar{2}$15, 312) and 2.779(28)(020). Cuyaite is monoclinic, Pn, a = 14.7231(6), b = 5.58709(19), c = 17.4185(12) Å, β = 112.451(8)°, V = 1324.23(14) Å3 and Z = 2. In the crystal structure of cuyaite (R1 = 0.0369 for 2095 I > 2σI reflections), AsO3 pyramids share O corners to form a ‘loose’ 3D framework; Jahn–Teller distorted Mn3+O6 octahedra and CaO8 polyhedra link by edges and corners to form columns; the columns also link by edge- and corner-sharing to the AsO3 pyramids in the framework; Cl occupies channels along [010] in the framework. The Raman spectrum is consistent with the presence of multiple As3+O3 groups.

Keywords

cuyaitenew mineralarsenite frameworkcrystal structureRaman spectroscopyCuyaCamarones ValleyChile
Type
Article
Information
Mineralogical Magazine , Volume 84 , Issue 3 , June 2020 , pp. 477 - 484
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2020

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Footnotes

Associate Editor: Irina O. Galuskina

References

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