Hostname: page-component-788cddb947-tr9hg Total loading time: 0 Render date: 2024-10-15T05:13:57.013Z Has data issue: false hasContentIssue false

Studies of mineral sulpho-salts: XIII—Polybasite and pearceite1

Published online by Cambridge University Press:  14 March 2018

M. A. Peacock
Affiliation:
University of Toronto
L. G. Berry
Affiliation:
Queen's University, Kingston, Ontario

Extract

These two minerals are analogous silver compounds with similar pseudo-hexagonal monoclinic form and similar compositions: polybasite, 8(Ag,Cu)2.(Sb,As)2S3, and pearceite, 8(Ag,Cu)2S.As2S3. Cu replaces Ag in considerable and varying amounts in both minerals, and in polybasite there may also be substantial replacement of Sb by As. However, the rather numerous existing analyses do not indicate continuous chemical variation from arsenian polybasite to pearceite, and therefore it is proper to recognize the two minerals as distinct species rather than end-members of a series.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1947

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

1

For the preceding paper of this series see E. W. Nuffield (1946) [M.A. 10–15]. No. II by L. G. Berry on jamesonite appeared in this Magazine, 1940, vol. 25, pp. 597–608.

References

Bodländer, G. (1895): Die Zusammensetzung des Polybasits. Neues Jahrb. Min., vol. i, pp. 98100.Google Scholar
Dana, J. D. & Dana, E. S. (1944): See Palache, Berman & Frondel (1944).Google Scholar
Domeyko, I. (1879): Elementos de mineralojía. 3rd edition, Santiago, Chile.Google Scholar
Genth, F. A. (1886): Contributions to mineralogy. Amer. Phil. Soc., vol. 23, pp. 3047.Google Scholar
Gossner, B. & Kraus, O. (1934): Über Kristallform und chemische Zusammensetzung von Polybasit. Centralblatt Min., Abt. A, pp. 16. [M.A. 6–171.]Google Scholar
Hintze, G. (1904): Handbuch der Mineralogie. Vol. 1, pt. 1, Berlin and Leipzig.Google Scholar
Miers, H. A. (1889): Polybasite.… Min. Mag., vol. 8, pp. 204209.CrossRefGoogle Scholar
Nuffield, E. W. (1946): Studies of mineral sulpho-salts: XII—Fülöppite and zinckenite. Univ. Toronto Studies, Geol. Ser., no. 50 (for 1945), pp. 4962. [M.A. 10–15.]Google Scholar
Palache, C., Berman, H. & Frondel, C. (1944): The system of mineralogy of J. D. Dana & E. S. Dana, 7th edition, vol. 1, New York.Google Scholar
Penfield, S. L. (1896): On pearceite, a sulpharsenite of silver and on the crystallization of polybasite. Amer. Journ. Sci., ser. 4, vol. 2, pp. 1729.CrossRefGoogle Scholar
Penfield, S. L. & Pearce, S. H. (1892): On polybasite and tennantite from the Mollie Gibson mine in Aspen, Colorado. Amer. Journ. Sci., ser. 3, vol. 44, pp. 1518.CrossRefGoogle Scholar
Prior, G. T. (1890): On zinc sulphide replacing stibnite and orpiment; analyses of stephanite and polybasite. Min. Mag., vol. 9, pp. 915.Google Scholar
Reuss, A. E. (1860) : Neue Mineralien — Vorkommnisse auf Przihramer Erz-Gängen in Böhmen. Neues Jahrb. Min., pp. 712717.Google Scholar
Rose, H. (1829): Ueber die in der Natur vorkommenden nicht oxydirten Verbindungen des Antimons und des Arseniks. Ann. Phys. Chem. (Poggendorff), vol. 15, pp. 573591.CrossRefGoogle Scholar
Rose, H. (1833): Ueber die Zusammensetzung des Polybasits und über das Atomen-gewicht des Silbers. Ann. Phys. Chem. (Poggendorff), vol. 28, pp. 156160.CrossRefGoogle Scholar
Short, M. N. (1940): Microscopic determination of the ore minerals. U.S. Geol. Surv., Bull. 914.Google Scholar
Staples, A. B. & Warren, H. V. (1946): Minerals from the Highland-Bell silver mine, Beaverdell, British Columbia. Univ. Toronto Studies, Geol. Ser., no. 50 (for 1945), pp. 27–33.Google Scholar
Ungemach, H. (1910): Contribution à la minéralogie du Mexique. Bull. Soc. Franç. Min., vol. 33, pp. 375409.Google Scholar
Van Horn, F. R. & Cook, C. W. (1911): A new occurrence of pearceite. Amer. Journ. Sci., ser. 4, vol. 31, pp. 518524.CrossRefGoogle Scholar