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On the existence of hydronium hydrates H9O+4 and H15O+7 in minerals

Published online by Cambridge University Press:  14 March 2018

Jan Kubisz
Jan Kubisz*
Affiliation:
Dept. of Mineralogy and Petrology, Academy of Mining and Metallurgy, Cracow, Poland
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Summary

Properties and possible structures of hydronium trihydrate H9O+4 and hexahydrate H15O+7 are considered. From the 2330 minerals listed in Strunz's mineralogical tables nineteen were selected that appear to contain H+.4H2O or H+.7H2O, and the possibility of discrete H9O+4 or H15O+7 groupings existing in their crystal lattice is discussed. From a crystallochemical point of view the most probable examples of hydronium hydrate compounds are layer lattice minerals like H-montmorillonite, H-vermiculite, troegerite, H-meta-autunite, sabugalite, and hewettite.

Type
Research Article
Information
Mineralogical magazine and journal of the Mineralogical Society , Volume 36 , Issue 276 , December 1966 , pp. 1071 - 1079
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1966

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