We studied, in steady and in unsteady state, the gas-solid reaction of gas nitriding(NH3-H2) of steel, in order to control the atomic nitrogentransfer in α-iron as a function of the inlet flow rates. We obtained the simultaneoussimulation of the gas phase variations, and the nitrogen transfer in the sample. Theevolution of the nitrogen concentration at the surface and inside of the α-iron, as afunction of the time, is presented. The results are in good agreement with the experimentand with previous work. We also established a correlation between the gas compositionaround the sample and the inlet conditions, in order to obtain an optimal nitrogentransfer at the sample’s surface, and thus control the nitride layer growth.