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Momentum Distribution in Molecular Systems

Part III. Bonds of Higher Order

Published online by Cambridge University Press:  24 October 2008

C. A. Coulson
C. A. Coulson
Affiliation:
University CollegeDundee
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Extract

The discussion of momentum distribution is extended to cover electrons in double bonds and conjugated bonds of fractional order. The mean radial distribution function is obtained, and it shows that the mean momentum of the electrons is less than if they were rigidly attached to their own particular nuclei. Polar diagrams show that, if electronic mobility is high in any direction in a molecule, the momentum is generally small in that direction.

Type
Research Article
Information
Mathematical Proceedings of the Cambridge Philosophical Society , Volume 37 , Issue 1 , January 1941 , pp. 74 - 81
Copyright
Copyright © Cambridge Philosophical Society 1941

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References

REFERENCES

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