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The determination of ammonia in sea water

Published online by Cambridge University Press:  11 May 2009

B. S. Newell
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Extract

A sensitive, specific and precise method for the determination of ammonia in sea water is presented. The method depends upon the oxidation of ammonia by chloramine-T and subsequent coupling with phenol to produce indophenol blue in an n-hexanol extract. Molar absorption coefficient ca 84,000. Values of ammonia measured in samples from the English Channel are given and the effect of freezing on samples for ammonia analysis is discussed.

Type
Research Article
Information
Journal of the Marine Biological Association of the United Kingdom , Volume 47 , Issue 2 , June 1967 , pp. 271 - 280
Copyright
Copyright © Marine Biological Association of the United Kingdom 1967

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References

REFERENCES

Armstrong, F. A. J. & Butler, E. I., 1959. Chemical changes in sea water off Plymouth during 1957. J. mar. biol. Ass. U.K., Vol. 38, pp. 41–5.CrossRefGoogle Scholar
Armstrong, F. A. J. & Butler, E. I. 1960 Chemical changes in sea water off Plymouth during 1958. J. mar. biol. Ass. U.K., Vol. 39, pp. 299–302.CrossRefGoogle Scholar
Bolleter, W. T., Bushman, C. J. & Tidwell, P. W., 1961. Spectrophotometric determination of ammonia as indophenol. Analyt. Chem., Vol. 33, pp. 592–4.CrossRefGoogle Scholar
Czech, F. W., Fuchs, R. J. & Antzak, H. F., 1961. Determination of mono, di and trichloramines by ultra-violet absorption spectrophotometry. Analyt. Chem., Vol. 33, pp. 705–7.Google Scholar
Degens, E. T., Reuter, J. H. & Shaw, K. N. F., 1964. Biochemical compounds in offshore California sediments and sea water. Geochim. cosmochim. Acta, Vol. 28, pp. 23–44.CrossRefGoogle Scholar
Johnston, R. 1966. Determination of ammonia in sea water as rubazoic acid. I.C.E.S.C.M., Hydrogr. Comm., 1966, Pap. no. N:10.Google Scholar
Marvin, K. T. & Proctor, R. R., 1965. Stabilising the ammonia nitrogen content of estuarine and coastal waters by freezing. Limnol. Oceanogr., Vol. 10, pp. 288–9.CrossRefGoogle Scholar
Newell, B. & Dal Pont, G., 1964. Ammonia in sea water. Nature, Land., Vol. 201, pp. 36–7.CrossRefGoogle Scholar
Newell, B. S., Morgan, B. & Cundy, J., 1967. The determination of urea in sea water. J. mar. Res. (in the Press).CrossRefGoogle Scholar
Prochazkova, L., 1964. Spectrophotometric determination of ammonia as rubazoic acid with bispyrazolone reagent. Analyt. Chem., Vol. 36, pp. 865–71.CrossRefGoogle Scholar
Richards, F. A. & Kletsch, R. A., 1964. The spectrophotometric determination of ammonia and labile amino compounds in fresh and sea water by oxidation to nitrite. In Recent Researches in the Fields of Hydrosphere, Atmosphere and Nuclear Geochemistry, pp. 65–81. Tokyo: Maruzen and Co. [Also as Univ. Wash. Dept. Oceanogr. Tech. Rep., No. 97].Google Scholar
Riley, J. P. 1953. The spectrophotometric determination of ammonia in natural waters, with particular reference to sea water. Analyt. chim. acta, Vol. 9, pp. 575–89.CrossRefGoogle Scholar
Riley, J. P., 1965. Analytical chemistry of sea water. In Chemical Oceanography, edit. Riley, and Skirrow, , pp. 295–411. London: Academie Press.Google Scholar
Tetlow, J. A. & Wilson, A. L., 1964. An absorptiometric method for determining ammonia in boiler feed water. Analyst, Lond., Vol. 89, pp. 453–65.CrossRefGoogle Scholar