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Influence of freshwater flux on 87Sr/86Sr chronostratigraphy in marginal marine environments and dating of vertebrate and invertebrate faunas

Published online by Cambridge University Press:  14 July 2015

J. Daniel Bryant
Affiliation:
Department of Vertebrate Paleontology, American Museum of Natural History, Central Park West at 79th Street, New York, New York 10024
Douglas S. Jones
Affiliation:
Lamont-Doherty Earth Observatory and Department of Geological Sciences, Columbia University, Palisades, New York 10964
Paul A. Mueller
Affiliation:
Florida Museum of Natural History, University of Florida, Gainesville 32611, and Department of Geology, University of Florida, Gainesville 32611

Abstract

87Sr/86Sr chronostratigraphy is an important tool for dating and correlating vertebrate and invertebrate faunas preserved in marginal marine sequences. Freshwater flux in marginal marine environments can influence the 87Sr/86Sr of mollusks and, consequently, Sr-chronostratigraphic interpretations based upon them. To appraise the potential problem we have used a two-component mixing equation to evaluate levels of “measurable effects” (defined as ±5 × 10-5 departure from the marine 87Sr/86Sr ratio) in marginal marine environments. A measurable effect occurs at 12 parts per thousand salinity for a weighted world average river, but can occur at salinity > 34 ppt for rivers draining basins with ancient granitic rocks. Predictions were tested with analyses of mollusks from estuaries in the Mississippi Sound and coastal Florida. Analyses document the largely regular variation in 87Sr/86Sr predicted, but also show that a simple two-component model cannot account for all of the variation. Carbonates formed in restricted marine settings may not record a marine 87Sr/86Sr signal, emphasizing the need to consider freshwater flux for 87Sr/86Sr chronostratigraphy.

Type
Research Article
Copyright
Copyright © The Paleontological Society 

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References

Andersson, P. S., Wasserburg, G. J., and Ingri, J. 1992. The sources and transport of Sr and Nd isotopes in the Baltic Sea. Earth and Planetary Science Letters, 113:459472.Google Scholar
Bryant, J. D., MacFadden, B. J., and Mueller, P. A. 1992. Improved chronologic resolution of the Hawthorn and Alum Bluff Groups in northern Florida: implications for Miocene chronostratigraphy. Geological Society of America Bulletin, 104:208218.Google Scholar
Carroll, J. L., and Lerche, I. 1990. A cautionary note on the use of 87Sr/86Sr sediment ages in stratigraphy studies. Nuclear Geophysics, 4:461466.Google Scholar
Chaudhuri, S., and Clauer, N. 1986. Fluctuations of isotopic composition of strontium in seawater during the Phanerozoic Eon. Chemical Geology (Isotope Geoscience Section), 59:293303.Google Scholar
Denison, R. E., Koepnick, R. B., Fletcher, A., Dahl, D. A., and Baker, M. C. 1993. Reevaluation of early Oligocene, Eocene, and Paleocene seawater strontium isotope ratios using outcrop samples from the U.S. Gulf Coast. Paleoceanography, 8:101126.Google Scholar
DePaolo, D. J., and Ingram, B. L. 1985. High-resolution stratigraphy with strontium isotopes. Science, 227:938941.Google Scholar
Goldstein, S. J., and Jacobsen, S. B. 1987. The Nd and Sr isotopic systematics of river-water dissolved material: implications for the sources of Nd and Sr in seawater. Chemical Geology (Isotope Geoscience Section), 66:245272.Google Scholar
Hess, J., Stott, L. D., Bender, M. L., Kennett, J. P., and Schiling, J.-G. 1989. The Oligocene marine microfossil record: age assessments using strontium isotopes. Paleoceanography, 4:655679.Google Scholar
Hodell, D. A., Mead, G. A., and Mueller, P. A. 1990. Variation in the strontium isotopic composition of seawater (8 Ma to present): implications for chemical weathering rates and dissolved fluxes to the oceans. Chemical Geology (Isotope Geoscience Section), 80:291307.Google Scholar
Hodell, D. A., Mueller, P. A., McKenzie, J. A., and Mead, G. A. 1989. Strontium isotope stratigraphy and geochemistry of the late Neogene ocean. Earth and Planetary Science Letters, 92:165178.Google Scholar
Ingram, B. L., and Sloan, D. 1992. Strontium isotopic composition of estuarine sediments as paleosalinity–paleoclimate indicator. Science, 255:6872.Google Scholar
Jones, D. S., MacFadden, B. J., Webb, S. D., Mueller, P. A., Hodell, D. A., and Cronin, T. M. 1991. Integrated geochronology of a classic Pliocene fossil site in Florida: linking marine and terrestrial biochronologies. Journal of Geology, 99:637648.Google Scholar
Jones, D. S., Quitmyer, I. R., Arnold, W. S., and Marelli, D. C. 1990. Annual shell banding, age, and growth rate of hard clams (Mercenaria spp.) from Florida. Journal of Shellfish Research, 9:215225.Google Scholar
Kaufman, D. S., Carter, L. D., Miller, G. H., Farmer, G. L., and Budd, D. A. 1993. Strontium isotopic composition of Pliocene and Pleistocene molluscs from emerged marine deposits, North American Arctic. Canadian Journal of Earth Sciences, 30:519534.Google Scholar
Koepnick, R. B., Denison, R. E., and Dahl, D. A. 1988. The Cenozoic seawater 87Sr/86Sr curve: data review and implications for correlation of marine strata. Paleoceanography, 3:743756.Google Scholar
Loomis, K. B. 1992. New 87Sr/86Sr data from invertebrate macrofossils in the Neogene Etchegoin Formation, San Joaquin Basin, California. Isochron/West, 58:1721.Google Scholar
MacFadden, B. J., Bryant, J. D., and Mueller, P. A. 1991. Srisotopic, paleomagnetic, and biostratigraphic calibration of horse evolution: evidence from the Miocene of Florida. Geology, 19:242245.Google Scholar
Müller, D. W., McKenzie, J. A., and Mueller, P. A. 1990. Abu Dhabi sabkha, Persian Gulf, revisited: application of strontium isotopes to test an early dolomitization model. Geology, 18:618621.Google Scholar
Palmer, M. R., and Edmond, J. M. 1989. The strontium isotope budget of the modern ocean. Earth and Planetary Science Letters, 92:1126.Google Scholar
Palmer, M. R., and Edmond, J. M. 1992. Controls over the strontium isotope composition of river water. Geochimica et Cosmochimica Acta, 56:20992111.Google Scholar
Rhoads, D. C., and Lutz, R. A. (eds.). 1980. Skeletal Growth of Aquatic Organisms: Biological Records of Environmental Change. Plenum Press, New York, 750 p.Google Scholar
Schmitz, B., Åberg, G., Werdelin, L., Forey, P., and Bendix-Almgreen, S. 1991. 87Sr/86Sr, Na, F, Sr, and La in skeletal fish debris as a measure of the paleosalinity of fossil-fish habitats. Geological Society of America Bulletin, 103:786794.Google Scholar
Sheraton, J. W., and Black, L. P. 1988. Chemical evolution of granitic rocks in the East Antarctic Shield, with particular reference to post-orogenic granites. Lithos, 21:3752.Google Scholar
Sikora, W. B., and Kjerfve, B.B. 1985. Factors influencing the salinity regime of Lake Ponchartrain, Louisiana, a shallow coastal lagoon: analysis of a long-term data set. Estuaries, 8:170180.Google Scholar
Thierstein, H. R., Macdougall, J. D., Martin, E. E., Larsen, B., Barron, J., and Baldauf, J. 1991. Age determinations of Paleogene diamictites from Prydz Bay (Site 739), Antarctica, using Sr isotopes of mollusks and biostratigraphy of microfossils (diatoms and coccoliths), p. 739745. In Barron, J., Larsen, B., et al. (eds.), Proceedings of the Ocean Drilling Program, Scientific Results, 119. Ocean Drilling Program, College Station, Texas.Google Scholar
Webb, S. D., Morgan, G. S., Hulbert, R. C. Jr., Jones, D. S., MacFadden, B. J., and Mueller, P. A. 1989. Geochronology of a rich early Pleistocene vertebrate fauna, Leisey Shell Pit, Tampa Bay, Florida. Quaternary Research, 32:96110.Google Scholar
Wisemann, W. J., Swenson, E. M., and Power, J. 1990. Salinity trends in Louisiana estuaries. Estuaries, 13:265271.Google Scholar