Hostname: page-component-cd9895bd7-gvvz8 Total loading time: 0 Render date: 2024-12-18T23:56:23.436Z Has data issue: false hasContentIssue false
  • English
  • Français

Investigation of Nano-Mechanical and- Tribological Properties of Hydrogenated Diamond Like Carbon (DLC) Coatings

Published online by Cambridge University Press:  28 October 2016

Y.-R. Jeng ,
S. Islam ,
K-T. Wu ,
A. Erdemir  and
O. Eryilmaz
Y.-R. Jeng
Affiliation:
Department of Mechanical EngineeringAdvanced Institute of Manufacturing with High–Tech Innovations (AIM-HI)National Chung Cheng UniversityChia-Yi, Taiwan
S. Islam*
Affiliation:
Department of Mechanical EngineeringFaculty of Engineering & ScienceCurtin UniversitySarawak, Malaysia
K-T. Wu
Affiliation:
Department of Mechanical EngineeringNational Chung Cheng UniversityChia-Yi, Taiwan
A. Erdemir
Affiliation:
Energy Technology DivisionArgonne National LaboratoryArgonne, USA
O. Eryilmaz
Affiliation:
Energy Technology DivisionArgonne National LaboratoryArgonne, USA
*
*Corresponding author ([email protected])

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Hydrogenated diamond like Carbon (H-DLC) is a promising lubricious coating that attracted a great deal of interest in recent years mainly because of its outstanding tribological properties. In this study, the nano-mechanical and -tribological properties of a range of H-DLC films were investigated. Specifically, four kinds of H-DLC coatings were produced on Si substrates in pure acetylene, pure methane, 25% methane + 75% hydrogen, 50% methane + 50% hydrogen discharge plasmas using a plasma enhanced chemical vapour deposition (PECVD) system. Nano indentation was performed to measure the mechanical properties such as hardness and young's modulus and nanoscartching was performed to investigate the frictional behavior and wear mechanism of the H-DLC samples in open air. Moreover, Vickers indentation method was utilized to assess the fracture toughness of the samples. The results revealed that there is a strong correlation between the mechanical properties (hardness, young's modulus, fracture toughness) and the friction coefficient of DLC coatings and the source gas chemistry. Lower hydrogen to carbon ratio in source gas leads to higher hardness, young's modulus, fracture toughness and lower friction coefficient. Furthermore, lower wear volume of the coated materials was observed when the friction coefficient was lower. It was also confirmed that lower hydrogen content of the DLC coating leads to higher wear resistance under nanoscratch conditions.

Keywords

Hydrogenated DLC coatingHardnessFracture toughnessWear
Type
Research Article
Information
Journal of Mechanics , Volume 33 , Issue 6 , December 2017 , pp. 769 - 776
Copyright
Copyright © The Society of Theoretical and Applied Mechanics 2017 

References

1. Gangopadhyay, A., et al., “Friction, wear, and surface film formation characteristics of diamond-like carbon thin coating in valve train application,” Tribology Transactions, 54, pp. 104–114 (2011).CrossRefGoogle Scholar
2. Huang, S.J., Jeng, Y.R. and Liu, K.F., “Sliding wear characteristics of the diamond-like carbon films on alloy substrates,” Wear, 263, pp. 1266–1273 (2007).Google Scholar
3. Jeng, Y.R., et al., “Effect of feed gas composition effects on the nanotribological properties of diamond-like carbon films,” Thin Solid Films, 529, pp. 301–305 (2013).CrossRefGoogle Scholar
4. Grill, A., “Diamond-like carbon: state of the art,” Diamond and Related Materials, 8, pp. 428–434 (1999).CrossRefGoogle Scholar
5. Colaco, R., Serro, A.P., Eryilmaz, O. L. and Erdemir, A., “Micro-to-nano triboactivity of hydrogenated DLC films,” Journal of Physics D: Applied Physics, 42, pp. 1–8 (2009).CrossRefGoogle Scholar
6. Erdemir, A., “The role of hydrogen in tribological properties of diamond-like carbon films,” Surface and Coatings Technology, 146, pp. 292–297 (2001).Google Scholar
7. Gonzalez, R., Battez, H., Viesca, J.L., Garrodo, A.H. and Gozalez, A.F., “Lubrication of DLC coatings with two tris (pentafluoroethyl) trifluorophosphate anion-based ionic liquids,” Tribology Transactions, 56, pp. 887–895 (2013).Google Scholar
8. Erdemir, A., Bindal, C., Pagan, J. and Wilbur, P., “Characterization of transfer layers on steel surfaces sliding against diamond-like hydrocarbon films in dry nitrogen,” Surface and Coatings Technology, 76-77, pp. 559–563 (1995).CrossRefGoogle Scholar
9. Erdemir, A., Eryilmaz, O. L., Nilufer, B. and Fenske, G.R., “Effect of source gas chemistry on tribological performance of diamond-like carbon films,” Diamond and Related Materials, 9, pp. 632–637 (2000).Google Scholar
10. Erdemir, A. Nichols, F. A., Pan, X. Z., Wei, R. and Wilbur, P., “Friction and wear performance of ion-beam-deposited diamond-like carbon films on steel substrates,” Diamond and Related Materials, 3, pp. 119–125 (1993).CrossRefGoogle Scholar
11. Erdemir, A., Nilufer, I.B., Eryilmaz, O.L., Beschliesser, M. and Fenske, G.R., “Friction and wear performance of diamond-like carbon films grown in various source gas plasmas,” Surface and Coatings Technology, 120, pp. 589–593(1999).CrossRefGoogle Scholar
12. Bhushan, B., “Chemical, mechanical and tribological characterization of ultra-thin and hard amorphous carbon coatings as thin as 3.5 nm: recent developments,” Diamond and Related Materials, 8, pp. 1985–2015 (1999).CrossRefGoogle Scholar
13. Mistry, K. K., et al., “Synthesis and tribology of micro-carbon sphere additives for enhanced lubrication,” Tribology Transactions, 58, pp. 474–480 (2015).CrossRefGoogle Scholar
14. Erdemir, A., et al., “Friction and wear properties of smooth diamond films grown in fullerene + argon plasmas,” Diamond and Related Materials, 5, pp. 923–931 (1996).Google Scholar
15. Meletis, E., Erdemir, A. and Fenske, G.R., “Tribological characteristics of DLC films and duplex plasma nitriding/DLC coating treatments,” Surface and Coatings Technology, 73, pp. 39–45 (1995).CrossRefGoogle Scholar
16. Liu, Y., Erdemir, A. and Meletis, E.I., “Influence of environmental parameters on the frictional behavior of DLC coatings,” Surface and Coatings Technology, 94-95, pp. 463–468 (1997).CrossRefGoogle Scholar
17. White, R. L., Doerner, M. F. and Walker, G. W., “Mechanical properties of carbon films for thin film disks,” MRS Proceedings, 188, pp. 213–218 (1990).Google Scholar
18. Bhushan, B. and Doerner, M.F., “Role of mechanical properties and surface texture in the real area of contact of magnetic rigid disks,” ASME Journal of Tribology, 3, pp. 452–458 (1989).CrossRefGoogle Scholar
19. Bhushan, A.B., Kellock, J., Cho, N-H. and Ager, J. W., “Characterization of chemical bonding and physical characteristics of diamond-like amorphous carbon and diamond films,” Journal of Materials Research, 7, pp. 404–410 (1992).Google Scholar
20. Gupta, B.K. and Bhushan, B., “Mechanical and tribological properties of hard carbon coatings for magnetic recording heads,” Wear, 190, pp. 110–122 (1995).Google Scholar
21. Erdemir, A., Eryilmaz, O.L. and Fenske, G., “Synthesis of diamond like carbon films with super low friction and wear properties,” Journal of Vacuum Science and Technology A, 18, pp. 1987–1992 (2000).CrossRefGoogle Scholar
22. Johnson, J. A., et al., “Insights into near-frictionless carbon films,” Journal of Applied Physics, 95, pp. 7765–7771 (2004).CrossRefGoogle Scholar
23. Kim, H.I., Lince, J.R., Eryilmaz, O.L. and Erdemir, A., “Environmental effects on the friction of hydrogenated DLC films,” Tribology Letters, 21, pp. 51–56 (2006).Google Scholar
24. Eryilmaz, O.L. and Erdemir, A., “Tof-sims and xps characterization of diamond-like carbon films after tests in inert and oxidizing environments,” Wear, 265, pp. 244–254 (2008).Google Scholar
25. Horsfall, R.H., “Commercial applications using non-hydrogenated carbon films for industrial uses such as cutting tools and wear components,” Proceedings of the 41st Annual Technical Conference, Society of Vacuum Coaters, Boston, MA, USA (1998).Google Scholar
26. Sullivan, J.P., Friedmann, T.A. and Hjort, K., “Diamond and amorphous carbon mems,” MRS Bulletin, 26, pp. 309–311 (2001).Google Scholar
27. Laugier, M. T., “Palmqvist indentation toughness in WC-Co composites,” Journal of Materials Science Letters, 6, pp. 897–900 (1987).Google Scholar
28. Tsai, H. and Bogy, D. B., “Characterization of diamond like carbon films and their application as overcoats on thin film media for magnetic recording,” Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, 5, pp. 3287–3312 (1987).Google Scholar
29. Knight, D.S. and White, W.B., “Characterization of diamond films by raman spectroscopy,” Journal of Materials Research, 4, pp. 385–393 (1989).Google Scholar
30. Robertson, J., “Amorphous carbon,” Advances in Physics, 35, pp. 317–321 (1986).CrossRefGoogle Scholar
31. Donnet, C. and Erdemir, A., Tribology of Diamond Like Carbon Films, Springer, Berlin (2008).Google Scholar
32. Oliver, W.C. and Phar, M. G., “An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments,” Journal of Material Research, pp. 1564–1583 (1992).Google Scholar
33. Li, X. and Bhushan, B., “Measurement of fracture toughness of ultra-thin amorphous carbon films,” Thin Solid Films, 315, pp. 214–221(1998).CrossRefGoogle Scholar
34. Li, X., Diao, D. and Bhushan, B., “Fracture mechanisms of thin amorphous carbon films in nanoindentation,” Acta Materialia, 45, pp. 4453–4461 (1997).Google Scholar
35. Donnet, C., et al., “The respective role of oxygen and water vapor on the tribology of hydrogenated diamond-like carbon coatings,” Tribology Letters, 4, pp. 259–265 (1998).Google Scholar
36. Islam, S., Ibrahim, R. and Khandoker, N., “The mechanics of single crystal cu machining at nanoscale,” Procedia Engineering, 10, pp. 2369–2374 (2011).Google Scholar
37. Islam, S. and Ibrahim, R., “Investigation of deformation behaviour and abrasive wear mechanism in nanomachining,” International Journal of Surface Science and Engineering, 5, pp. 38–50 (2011).CrossRefGoogle Scholar
38. Islam, S. and Ibrahim, R., “Mechanism of abrasive wear in nanomachining,” Tribology Letters, 42, pp. 275–284 (2011).Google Scholar
39. Islam, S., Ibrahim, R.N. and Das, R., “Study of abrasive wear mechanism through nano machining,” Key Engineering Materials, 462, pp. 931–936 (2011).Google Scholar
40. Angus, J. C. and Jansen, F., “Dense diamond like hydrocarbons as random covalent networks,” Journal of Vacuum Science & Technology, A: Vacuum, Surfaces, and Films, 6, pp. 1778–1784 (1998).CrossRefGoogle Scholar