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X-ray diffraction study revealing phase coexistence in barium titanate stannate

Published online by Cambridge University Press:  01 October 2004

Volkmar Mueller ,
Horst Beige ,
Hans-Peter Abicht  and
Christian Eisenschmidt
Volkmar Mueller*
Affiliation:
Fachbereich Physik, Martin-Luther-Universität Halle, D-06108 Halle, Germany
Horst Beige
Affiliation:
Fachbereich Physik, Martin-Luther-Universität Halle, D-06108 Halle, Germany
Hans-Peter Abicht
Affiliation:
Fachbereich Chemie, Martin-Luther-Universität Halle, D-06120 Halle, Germany
Christian Eisenschmidt
Affiliation:
Fachbereich Physik, Martin-Luther-Universität Halle, D-06120 Halle, Germany
*
a)Address all correspondence to this author.e-mail: [email protected]
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Abstract

In this paper, the results of a temperature dependent x-ray diffraction (XRD) study on BaTi0.95Sn0.05O3 (BTS-5) ceramics are compared with dielectric measurements. The orthorhombic-tetragonal phase transition at T2 = 306 K is found to proceed in a considerably wider temperature range than expected from the dielectric anomaly. Although the macroscopic properties of BTS-5 indicate a rather sharp ferroelectric phase transition at Tc = 358K, we observe anomalous XRD-patterns in a 25 K wide temperature range. This is interpreted in terms of mechanically clamped tetragonal and cubic phase, coexisting in the vicinity of Tc in grains with inhomogeneous Sn-distribution.

Keywords

FerroelectricityPhase transformationX-ray diffraction (XRD)
Type
Articles
Information
Journal of Materials Research , Volume 19 , Issue 10 , October 2004 , pp. 2834 - 2840
Copyright
Copyright © Materials Research Society 2004

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References

REFERENCES

1Smolensky, G.A. and Isupov, V.A. Ferroelectric characteristics of solid solutions of barium stannate in barium titanate (in Russian), Zh. Tekh. Fiz. 24, 1375 (1954).Google Scholar
2Smolensky, G.A.: Physical phenomena in ferroelectrics with diffused phase transition. J. Phys. Soc. Jpn. 28, 26 (1970).Google Scholar
3Jaffe, B., Cook, J. and Jaffe, H.: Piezoelectric Ceramics (Academic, London, U.K., 1971).Google Scholar
4Yasuda, N., Ohwa, H. and Asano, S.: Dielectric properties and phase transitions of BaTi1- x Snx O3 solid solution. Jpn. J. Appl. Phys. 35, 5099 (1996).Google Scholar
5Baskaran, N. and Chang, H.: Effect of Sn doping on the phase transformation properties of ferroelectric BaTiO3. J. Mater. Sci. 12, 527 (2001).Google Scholar
6Oh, K., Uchino, K. and Cross, L.E.: Optical study of domains in Ba(Ti,Sn)O3. J. Am. Ceram. Soc. 77, 2809 (1994).CrossRefGoogle Scholar
7Mueller, V., Beige, H. and Abicht, H-P.: Non-debye dielectric dispersion of barium titanate stannate in the relaxor and diffuse phase-transition state. Appl. Phys. Lett. 84, 1341 (2004).CrossRefGoogle Scholar
8Westphal, V., Kleemann, W. and Glinchuk, M.D.: Diffuse phase transitions and random-field-induced domain states of the “relaxor” ferroelectric PbMg1/3Nb2/3O3. Phys. Rev. Lett. 68, 847 (1992).Google Scholar
9Tagantsev, A.K. and Glazounov, A.E.: Mechanism of polarization response in the ergodic phase of a relaxor ferroelectric. Phys. Rev. B 57, 18 (1998).CrossRefGoogle Scholar
10Viehland, D., Jang, S.J., Cross, L.E. and Wuttig, M.: Devation from Curie–Weiss behavior in relaxor ferroelectrics. Phys. Rev. B 46, 8003 (1992).Google Scholar
11Bobnar, V., Kutnjak, Z., Pirc, R., Blinc, R. and Levstik, A.: Crossover from glassy to inhomogeneous-ferroelectric nonlinear dielectric response in relaxor ferroelectrics. Phys. Rev. Lett. 84, 5892 (2000).CrossRefGoogle ScholarPubMed
12You, H. and Zhang, Q.M.: Diffuse x-ray scattering study of lead magnesium niobate single crystals. Phys. Rev. Lett. 79, 3950 (1997).CrossRefGoogle Scholar
13Gehring, P.M., Wakimoto, S., Ye, Z-G. and Shirane, G.: Soft mode dynamics above and below the burns temperature in the relaxor Pb(Mg1/3Nb2/3)O3. Phys. Rev. Lett. 87, 277601 (2001).Google Scholar
14Hlinka, J., Kamba, S., Petzelt, J., Kulda, J., Randall, C.A. and Zhang, S.J.: Origin of the “Waterfall” effect in phonon dispersion of relaxor perovskites. Phys. Rev. Lett. 91, 107602 (2003).Google Scholar
15Simon, A., Ravez, J. and Maglione, M.: The crossover from a ferroelectric to a relaxor state in lead-free solid solutions. J. Phys.: Condens. Matter 16, 963 (2004).Google Scholar
16Chang, W-K., Hsieh, S-F., Lee, Y-H., Cheng, K-N., Wu, N-C. and Wang, A.A.: X-ray diffraction studies of phase transformations between tetragonal and cubic phases in the BaSn x Ti1-x O3 system. J. Mater. Sci. 33, 1765 (1998).Google Scholar
17Landolt-Börnstein, III/16. Ferroelectric Oxides (Springer, Berlin, 1981)Google Scholar
18Li, X., Shih, W.Y., Vartuli, J.S., Milius, D.L., Aksay, I.A. and Shih, W-H.: Effect of a transverse tensile stress on the electric-field-induced domain reorientation in soft PZT: In situ XRD study. J. Am. Ceram. Soc. 85, 844 (2002).CrossRefGoogle Scholar
19Hammer, M., Monty, C., Endriss, A. and Hoffmann, M.J.: Correlation between surface texture and chemical composition in undoped, hard, and soft piezoelectric PZT ceramics. J. Am. Ceram. Soc. 81, 721 (1998).Google Scholar
20Fritsberg, V.J., Zvirgzde, J.V. and Romanovskis, T.B.: Transformation of crystal structure in BaTiO3 at the cubic-to-tetragonal phase transition. Ferroelectrics 20, 197 (1978).Google Scholar
21Lin, J.N. and Wu, T.B.: Effects of isovalent substitutions on lattice softening and transition character of BaTiO3 solid solutions. J. Appl. Phys. 68, 985 (1990).CrossRefGoogle Scholar
22Burns, G. and Dacol, F.H.: Polarization in the cubic phase of BaTiO3. Solid State Commun. 42, 9 (1982).Google Scholar
23Steinhausen, R., Kouvatov, A., Pientschke, C., Seifert, W., Beige, H., Langhammer, H.T. and Abicht, H-P. Bending behavior of monolithic Ba(Ti,Sn)O3-ceramics with a Functionally gradient of the piezoelectric properties. Ferroelectrics (in press).Google Scholar
24Mueller, V., Jäger, L., Beige, H., Abicht, H-P. and Müller, T.: Thermal expansion in the Burns-phase of barium titanate stannate. Solid State Commun. 129, 757 (2004).Google Scholar
25Jacobs, A.E.: Landau theory of structures in tetragonal-orthorhombic ferroelastics. Phys. Rev. B 61, 6587 (2000).Google Scholar