Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-28T06:04:55.616Z Has data issue: false hasContentIssue false
  • English
  • Français

Tunable blue-green emission from ZnS(Ag) nanostructures grown by hydrothermal synthesis

Published online by Cambridge University Press:  05 November 2018

Manjula Sharma ,
Shashwati Sen ,
Jagannath Gupta ,
M. Ghosh ,
S. Pitale ,
Vinay Gupta  and
S.C. Gadkari
Manjula Sharma
Affiliation:
Technical Physics Division, Bhabha Atomic Research Center, Trombay, Mumbai 400085, India; and Department of Physics and Astrophysics, University of Delhi, New Delhi 110007, India
Shashwati Sen*
Affiliation:
Technical Physics Division, Bhabha Atomic Research Center, Trombay, Mumbai 400085, India
Jagannath Gupta
Affiliation:
Technical Physics Division, Bhabha Atomic Research Center, Trombay, Mumbai 400085, India
M. Ghosh
Affiliation:
Technical Physics Division, Bhabha Atomic Research Center, Trombay, Mumbai 400085, India
S. Pitale
Affiliation:
Technical Physics Division, Bhabha Atomic Research Center, Trombay, Mumbai 400085, India
Vinay Gupta
Affiliation:
Department of Physics and Astrophysics, University of Delhi, New Delhi 110007, India
S.C. Gadkari
Affiliation:
Technical Physics Division, Bhabha Atomic Research Center, Trombay, Mumbai 400085, India
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

We report the synthesis and optical properties of pure ZnS and Ag doped ZnS nanostructures. ZnS(Ag) was synthesized by using the hydrothermal technique and later annealed at different temperatures under vacuum conditions. It was observed that the photoluminescence (PL) emission from the ZnS(Ag) nanostructures can be easily tuned from the blue (445 nm) to green (530 nm) region of visible light by varying the annealing temperature. This tunability has been attributed to the introduction of excess sulfur vacancy states, which is evident from the PL excitation spectra. This observed change in the PL emission wavelength can be highly beneficial in the imaging screens where ZnS is regularly used and can be easily interfaced with the silicon photodiodes showing maximum sensitivity at 550 nm.

Keywords

hydrothermalsemiconductingluminescence
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 23 , 14 December 2018 , pp. 3963 - 3970
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Sunghoon, P., Soyeon, A., Hyunsung, K., Lee, S., and Lee, C.: Synthesis, structure and UV-enhanced gas sensing properties of Au-functionalized ZnS nano-wires. Sens. Actuators, B 188, 1270–1276 (2013).Google Scholar
Kole, A.K., Tiwary, C.S., and Kumbhakar, P.: Morphology controlled synthesis of wurtzite ZnS nanostructures through simple hydrothermal method and observation of white light emission from ZnO obtained by annealing the synthesized ZnS nanostructures. J. Mater. Chem. C 2, 4338 (2014).CrossRefGoogle Scholar
Boxi, S.S. and Paria, S.: Effect of silver doping on TiO2, CdS, and ZnS nanoparticles for the photocatalytic degradation of metronidazole under visible light. RSC Adv. 4, 37752 (2014).CrossRefGoogle Scholar
Liang, Y., Liang, H., Xiaoa, X., and Hark, S.: The epitaxial growth of ZnS nanowire arrays and their applications in UV-light detection. J. Mater. Chem. 22, 1199–1205 (2012).CrossRefGoogle Scholar
McCloy, J.S., Bliss, M., Miller, B., Wang, Z., and Stave, S.: Scintillation and luminescence in transparent colorless single and polycrystalline bulk ceramic ZnS. J. Lumin. 157, 416–423 (2015).CrossRefGoogle Scholar
Fang, X., Zhai, T., Gautam, U.K., Li, L., Wu, L., Bando, Y., and Golberg, D.: ZnS nanostructures: From synthesis to applications. Prog. Mater. Sci. 56, 175–287 (2011).CrossRefGoogle Scholar
Li, Z., Liu, B., Li, X., Yu, S., Wang, L., Hou, Y., Zou, Y., Yao, M., Li, Q., Zou, B., Zou, G., Wang, G., and Liu, Y.: Synthesis of ZnS nanocrystals with controllable structure and morphology and their photoluminescence property. Nanotechnol. 18, 255602 (2007).CrossRefGoogle Scholar
Mendil, R., Ayadi, Z.B., and Djessas, K.: Effect of solvent medium on the structural, morphological and optical properties of ZnS nanoparticles synthesized by solvothermal route. J. Alloys Compd. 678, 87–92 (2016).CrossRefGoogle Scholar
Geng, B.Y., Liu, X.W., Du, Q.B., We, X.W., and Zhang, L.D.: Structure and optical properties of periodically twinned ZnS nanowires. Appl. Phys. Lett. 88, 163104 (2006).CrossRefGoogle Scholar
Murase, N., Jagannathan, R., Kanematsu, Y., Watanbe, M., Kurita, A., Hirata, K., Yazawa, T., and Kushida, T.: Fluorescence and EPR characteristics of Mn2+-doped ZnS nanocrystals prepared by aqueous colloidal method. J. Phys. Chem. B 103, 754 (1999).CrossRefGoogle Scholar
Lin, K.B. and Su, Y.H.: Photoluminescence of Cu:ZnS, Ag:ZnS, and Au:ZnS nanoparticles applied in Bio-LED. Appl. Phys. B 113, 351–359 (2013).CrossRefGoogle Scholar
Lu, L., Zeng, W., Hu, S., Chen, D., Lei, J., and Ren, N.: Polarization-dependent fluorescence of CdSe/ZnS quantum dots coupling to a single gold-silver alloy nanotube. J. Alloys Compd. 731, 753–759 (2017).CrossRefGoogle Scholar
Xu, X.J., Hu, L.F., Gao, N., Liu, S., Wageh, S., Al-Ghamdi, A.A., Alshahrie, A., and Fang, X.: Controlled growth from ZnS nanoparticles to ZnS–CdS nanoparticle hybrids with enhanced photo- activity. Adv. Funct. Mater. 25, 445–454 (2015).CrossRefGoogle Scholar
Hao, E., Sun, Y., Yang, B., Zhang, X., Liu, J., and Shen, J.: Synthesis and photophysical properties of ZnS colloidal particles doped with silver. J. Colloid Interface Sci. 204, 369–373 (1998).CrossRefGoogle ScholarPubMed
Pan, Q., Yang, D., Zhao, Y., Ma, Z., Dong, G., and Qiu, J.: Facile hydrothermal synthesis of Mn doped ZnS nanocrystals and luminescence properties investigations. J. Alloys Compd. 579, 300–304 (2013).CrossRefGoogle Scholar
Lee, J-C. and Park, D-H.: Self-defects properties of ZnS with sintering temperature. Mater. Lett. 57, 2872–2878 (2003).CrossRefGoogle Scholar
Zhang, W., Zeng, X., Liu, H., and Lu, J.: Synthesis and investigation of blue and green emissions of ZnS ceramics. J. Lumin. 134, 498–503 (2013).CrossRefGoogle Scholar
Yang, P., Lu, M., Xu, D., Yuan, D.L., and Zhou, G.J.: Photoluminescence properties of ZnS nanoparticles co-doped with Pb2+ and Cu2+. Chem. Phys. Lett. 336, 76–80 (2001).CrossRefGoogle Scholar
Ye, C., Fang, X., Li, G., and Zhang, L.: Origin of the green photoluminescence from zinc sulfide nanobelts. Appl. Phys. Lett. 85, 3035–3037 (2004).CrossRefGoogle Scholar
Acharya, S.A., Maheshwari, N., Tatikondewar, L., Kshirsagar, A., and Kulkarni, S.K.: Ethylenediamine-mediated wurtzite phase formation in ZnS. Cryst. Growth Des. 13, 1369–1376 (2013).CrossRefGoogle Scholar
Fantauzzi, M., Elsener, B., Atzei, D., Rigoldiab, A., and Rossiab, A.: Exploiting XPS for the identification of sulfides and polysulfides. RSC Adv. 5, 75953–75963 (2015).CrossRefGoogle Scholar
Hota, G., Idage, S.B., and Khilar, K.C.: Characterization of nano-sized CdS–Ag2S core-shell nanoparticles using XPS technique. Colloids Surf., A 293, 5–12 (2007).CrossRefGoogle Scholar
Pan, S., Liu, X., and Wang, X.: Preparation of Ag2S–Graphene nanocomposite from a single source precursor and its surface-enhanced Raman scattering and photoluminescent activity. Mater. Charact. 62, 1094–1101 (2011).CrossRefGoogle Scholar
Becker, W. and Bard, A.J.: Photoluminescence and photoinduced oxygen adsorption of colloidal Zinc Sulfide dispersions. J. Phys. Chem. 87, 4888–4893 (1983).CrossRefGoogle Scholar
Denzler, D., Olschewski, M., and Sattler, K.: Luminescence studies of localized gap states in colloidal ZnS nanocrystals. J. Appl. Phys. 84, 2841–2845 (1998).CrossRefGoogle Scholar
Peng, W.Q., Cong, G.W., Qu, S.C., and Wang, Z.G.: Synthesis and photoluminescence of ZnS:Cu nanoparticles. Opt. Mater. 29, 313–317 (2006).CrossRefGoogle Scholar
Xiong, Q., Chen, G., Acord, J.D., Liu, X., Zengel, J.J., Gutierrez, H.R., Redwing, J.M., Lew Yan Voon, L.C., Lassen, B., and Eklund, P.C.: Optical properties of rectangular cross-sectional ZnS nanowires. Nano Lett. 4, 1663–1668 (2004).CrossRefGoogle Scholar
Kakarndee, S., Juabrum, S., and Nanan, S.: Low temperature synthesis, characterization and photoluminescence study of plate-like ZnS. Mater. Lett. 164, 198–201 (2016).CrossRefGoogle Scholar